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Design and fabrication of rare-earth-free ZnO-based white phosphor films

Research Project

Project/Area Number 17K14806
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

Kawashima Tomoyuki  東北大学, 工学研究科, 講師 (40708450)

Project Period (FY) 2017-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2018: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords蛍光体 / 薄膜 / 紫外光励起 / 酸化亜鉛 / タングステン / バナジウム / 青色 / スパッタリング / ナノ材料 / 機能性セラミックス材料
Outline of Final Research Achievements

Fabrication process of rare-earth-free ZnO-based phosphor films and their stacked structure was investigated. W-Zn-O blue phosphor films (hereafter 'WZO') exhibited high quantum efficiency when it is mostly consisted of zinc tungstate but not tungsten oxide. Higher quantum efficiency was exhibited in stacked film of WZO and zinc vanadate when thermally oxidized layer-by-layer despite of stacked order.

Academic Significance and Societal Importance of the Research Achievements

これまで蛍光体波長変換型白色LEDの多くは封止樹脂中に粉体状の蛍光体を分散固定していた。この樹脂はLEDの熱によって劣化・変性し、変色や光取り出し効率の低下を招いている。本研究成果は蛍光体自身と多色混合に固定材料を要しないだけでなく、急速熱酸化処理に基づく高速薄膜形成プロセスを採用しており、蛍光体の生産プロセスを短縮化し、省エネルギー化にも資するものである。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • Research Products

    (8 results)

All 2019 2018 2017

All Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Presentation] WZO/VZO積層蛍光薄膜の発光特性2019

    • Author(s)
      岡本 諒, 岡田 健, 川島 知之, 鷲尾 勝由
    • Organizer
      第66回 応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Optical Property of Stacked Yellow/Blue Phosphor Films on Quartz Substrate2018

    • Author(s)
      R. Okamoto, A. Kimura, T. Kawashima and K. Washio
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures (ACSIN-14)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Formation and properties of luminescent oxide films on SiO22018

    • Author(s)
      Tomoyuki Kawashima, Katsuyoshi Washio
    • Organizer
      11th International WorkShop on New Group IV Semiconductor Nanoelectronics
    • Related Report
      2018 Annual Research Report 2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] W-Zn-O青色蛍光体薄膜中の金属組成と発光特性の関係2018

    • Author(s)
      木村 惇志, 川島 知之, 鷲尾 勝由
    • Organizer
      第65回 応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] W-Zn-O青色蛍光体薄膜結晶成長に及ぼす金属組成の影響2018

    • Author(s)
      川島 知之, 木村 惇志, 鷲尾 勝由
    • Organizer
      第65回 応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] W-Zn-O青色蛍光体薄膜中の金属組成と発光特性の関係2018

    • Author(s)
      木村 惇志, 川島 知之, 鷲尾 勝由
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] W-Zn-O青色蛍光体薄膜結晶成長に及ぼす金属組成の影響2018

    • Author(s)
      川島 知之, 木村 惇志, 鷲尾 勝由
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] 急速加熱処理によるW-Zn-O青色蛍光体薄膜の形成2017

    • Author(s)
      川島 知之, 鷲尾 勝由
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2020-03-30  

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