• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Study of charge-discharge mechanism in phosphate-type cathode material with defect control

Research Project

Project/Area Number 17K14920
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionTohoku University (2018)
Tokyo University of Agriculture and Technology (2017)

Principal Investigator

Kisu Kazuaki  東北大学, 材料科学高等研究所, 助教 (80755645)

Project Period (FY) 2017-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2018: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsリチウムイオン二次電池 / リン酸鉄リチウム / リン酸鉄コバルトリチウム / 欠陥・結晶化度 / 結晶化度・欠陥
Outline of Final Research Achievements

This study aims at elucidation the influence of vacancies and crystallinity on phosphate type cathode electrode to obtain the guideline for improvement the cycleability and power density of cathode material operating high voltage. The vacancies in M2 sites in phosphate type cathode material are responsible for the Li+ diffusivity enhancement within the crystals and thus for the improvements of rate capability. The findings may offer new approaches to stabilize the structure of phosphate type cathode material and other high-voltage positive electrodes for use in Li-ion batteries operating high voltage.

Academic Significance and Societal Importance of the Research Achievements

電気自動車や小型モバイルなど幅広い分野における需要の高まりを背景として、蓄電デバイスの安全性、エネルギー密度、高速充放電、サイクル特性などさまざまな観点からの高性能化が要求されている。こうした高い要求の実現に向けて、現行のリチウムイオン電池の性能を凌駕する革新的な蓄電デバイスが強く望まれており、その達成に向けた新規の正極・負極電極材料や電解液などの創出が必須となっている。本研究では、電極材料における結晶内欠陥および粒子表面コーティング層が電池寿命や充放電速度に与える影響を明らかにすることで、電極材料の高性能化および新規創出に向けて指針を提案した。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • Research Products

    (20 results)

All 2018 2017 Other

All Int'l Joint Research (2 results) Journal Article (6 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 4 results) Presentation (11 results) (of which Int'l Joint Research: 8 results,  Invited: 1 results) Book (1 results)

  • [Int'l Joint Research] Universite Paul Sabatier/Universite de Nantes(フランス)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Universite Paul Sabatier/Universite de Nantes(フランス)

    • Related Report
      2017 Research-status Report
  • [Journal Article] Development of New Generation Capacitors for Renewable Energy Utilization2018

    • Author(s)
      岩間 悦郎、木須 一彰、直井 和子、直井 勝彦
    • Journal Title

      Nihon Enerugii Gakkai Kikanshi Enermix

      Volume: 97 Issue: 4 Pages: 328-334

    • DOI

      10.20550/jieenermix.97.4_328

    • NAID

      130007428424

    • ISSN
      2432-3586, 2432-3594
    • Year and Date
      2018-07-20
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stabilizing the Structure of LiCoPO4 Nanocrystals via Addition of Fe3+: Formation of Fe3+ Surface Layer, Creation of Diffusion-Enhancing Vacancies, and Enabling High-Voltage Battery Operation2018

    • Author(s)
      Okita Naohisa、Kisu Kazuaki、Iwama Etsuro、Sakai Yuki、Lim Yiyo、Takami Yusuke、Sougrati Moulay Tahar、Brousse Thierry、Rozier Patrick、Simon Patrice、Naoi Wako、Naoi Katsuhiko
    • Journal Title

      Chemistry of Materials

      Volume: 30 Issue: 19 Pages: 6675-6683

    • DOI

      10.1021/acs.chemmater.8b01965

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Internal resistance mapping preparation to optimize electrode thickness and density using symmetric cell for high-performance lithium-ion batteries and capacitors2018

    • Author(s)
      Kisu Kazuaki、Aoyagi Shintaro、Nagatomo Haruka、Iwama Etsuro、Reid McMahon Thomas Homer、Naoi Wako、Naoi Katsuhiko
    • Journal Title

      Journal of Power Sources

      Volume: 396 Pages: 207-212

    • DOI

      10.1016/j.jpowsour.2018.05.083

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Cation-Disordered Li3VO4: Reversible Li Insertion/Deinsertion Mechanism for Quasi Li-Rich Layered Li1+x[V1/2Li1/2]O2 (x = 0-1)2018

    • Author(s)
      Patrick Rozier, Etsuro Iwama, Nagare Nishio, Kazuhisa Baba, Keisuke Matsumura, Kazuaki Kisu, Junichi Miyamoto, Wako Naoi, Yuki Orikasa, Patrice Simon, Katsuhiko Naoi
    • Journal Title

      Chemistry of Materials

      Volume: 30 Issue: 15 Pages: 4926-4934

    • DOI

      10.1021/acs.chemmater.8b00721

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 2.超遠心ナノハイブリッド技術による次世代ハイブリッドキャパシタ電極材料の研究開発2017

    • Author(s)
      直井 勝彦, 岩間 悦郎, 木須 一彰
    • Journal Title

      Electrochemistry

      Volume: 85 Issue: 11 Pages: 740-745

    • DOI

      10.5796/electrochemistry.85.740

    • NAID

      130007342851

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2017 Research-status Report
  • [Journal Article] Enhanced Hybrid Supercapacitors Utilizing Nanostructured Metal Oxides2017

    • Author(s)
      Etsuro Iwama, Kazuaki Kisu, Patrice Simon, Katsuhiko Naoi
    • Journal Title

      Metal Oxides in Supercapacitors

      Volume: - Pages: 247-247

    • DOI

      10.1016/b978-0-12-810464-4.00010-3

    • ISBN
      9780128111697
    • Related Report
      2017 Research-status Report
  • [Presentation] Intercalation Host Using Defective FePO4-Carbon Composite for Magnesium Rechargeable Battery Cathode2018

    • Author(s)
      Yuki Orikasa, Kazuaki Kisu, Etsuro Iwama, Wako Naoi, Yusuke Yamaguchi, Toshiyuki Munesada, Masashi Hattori, Kentaro Yamamoto, Patrick Rozier, Patrice Simon, Katsuhiko Naoi
    • Organizer
      AiMES 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Magnesium Intercalation Host of Defective FePO4-Carbon Composite2018

    • Author(s)
      Yusuke Yamaguchi, Yuki Orikasa, Kazuaki Kisu, Etsuro Iwama, Wako Naoi , Toshiyuki Munesada, Masashi Hattori, Kentaro Yamamoto, Patrick Rozier, Patrice Simon, Katsuhiko Naoi
    • Organizer
      The 19th International Meeting on Lithium Batteries
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] FePO4-Carbon Composite Electrode for Calcium Rechargeable Battery Cathode2018

    • Author(s)
      Yoshitomo Yamaguchi, Yuki Orikasa, Kazuaki Kisu, Etsuro Iwama, Wako Naoi, Patrick Rozier, Patrice Simon, Katsuhiko Naoi
    • Organizer
      The 19th International Meeting on Lithium Batteries
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pseudo-Capacitive Behavior of Nanostructure LiFePO4/Graphitic Carbon Composite for Hybrid Capacitor2017

    • Author(s)
      Kazuaki Kisu, Etsuro Iwama, Yuki Orikasa, Wako Naoi, Philippe Leone, Nicolas Dupre, Thierry Brousse, Patrick Rozier, Patrice Simon, Katsuhiko Naoi
    • Organizer
      232nd ECS MEETING
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Ultrafast Carbon-Nested LiFePO4 Core-Shell Structured Nanomaterial for Hybrid EES2017

    • Author(s)
      Kazuaki Kisu, Etsuro Iwama, Yuki Orikasa, Wako Naoi, Philippe Leone, Nicolas Dupre, Thierry Brousse, Patrick Rozier, Patrice Simon, Katsuhiko Naoi
    • Organizer
      5th International Symposium on Enhanced Electrochemical Capacitors
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Lithium-ion Insertion/Deinsertion Reaction Kinetics in a Carbon-Nested Ultrafast Nano-LiFePO42017

    • Author(s)
      Kazuaki Kisu, Etsuro Iwama, Yuki Orikasa, Wako Naoi, Philippe Leone, Nicolas Dupre, Thierry Brousse, Patrick Rozier, Patrice Simon, Katsuhiko Naoi
    • Organizer
      The 58th Battery Symposium Japan (International Session)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] LiCo0.8Fe0.2PO4/Multi-Walled Carbon Nanotubes Nanocomposites for 5-Volts Class Lithium Ion Batteries2017

    • Author(s)
      Naohisa Okita, Kazuaki Kisu, Yuki Sakai, Yiyo Lim, Yusuke Takami, Brousse Thierry, Rozier Patrick, Simon Patrice, Wako Naoi, Katsuhiko Naoi
    • Organizer
      The 58th Battery Symposium Japan (International Session)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Nanocrystalline LiCo0.8Fe0.2PO4/Multi- Walled Carbon Nanotubes Positive Electrode for 5-Volts Class Lithium Ion Batteries2017

    • Author(s)
      Naohisa Okita, Kazuaki Kisu, Yuki Sakai, Yiyo Lim, Yusuke Takami, T. Brousse, P. Rozier, P. Simon, Wako Naoi, Katsuhiko Naoi
    • Organizer
      232nd ECS MEETING
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] ハイブリッドキャパシタ用正極材料に向けたナノLiFePO4/カーボン三層コアシェル複合体の作製と電気化学評価2017

    • Author(s)
      木須一彰, 岩間悦郎, 酒井祐輝, 折笠有基, 直井和子, 直井勝彦
    • Organizer
      電気化学会第84回大会
    • Related Report
      2017 Research-status Report
  • [Presentation] LiCo0.8Fe0.2PO4/多層カーボンナノチューブ複合体のリチウムイオン二次電池正極特性2017

    • Author(s)
      高見祐介, 木須一彰, 沖田尚久, 酒井祐輝, 林怡瑤, 直井和子, 直井勝彦
    • Organizer
      第58回電池討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] LiCo0.8Fe0.2PO4/多層カーボンナノチューブ複合体のサイクル特性向上のメカニズム解析2017

    • Author(s)
      林怡瑤, 木須一彰, 沖田尚久, 酒井祐輝, 高見祐介, 直井和子, 直井勝彦
    • Organizer
      第58回電池討論会
    • Related Report
      2017 Research-status Report
  • [Book] 電気化学・インピーダンス測定のデータ解析手法と事例集, 第5節 高エネルギー・高パワー密度化に向けたリチウムイオン二次電池/キャパシタ用多孔質電極の内部抵抗解析2018

    • Author(s)
      木須一彰, 岩間悦郎, 直井勝彦
    • Total Pages
      10
    • Publisher
      技術情報協会
    • Related Report
      2018 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2020-03-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi