Photoinduced large magnetodielectric effect in perovskite magnetic nanogranular

• Project/Area Number: 17K19019
• Research Category: Grant-in-Aid for Challenging Research (Exploratory)
• Allocation Type: Multi-year Fund
• Research Field: Nano/Micro science and related fields
• Research Institution: Hokkaido University
• Principal Investigator: Kaiju Hideo 北海道大学, 電子科学研究所, 准教授 (70396323)
• Co-Investigator(Kenkyū-buntansha): 西井 準治 北海道大学, 電子科学研究所, 教授 (60357697) ; 芥川 智行 東北大学, 多元物質科学研究所, 教授 (60271631)
• Project Period (FY): 2017-06-30 – 2019-03-31
• Project Status: Completed (Fiscal Year 2018)
• Budget Amount: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000); Fiscal Year 2018: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000); Fiscal Year 2017: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
• Keywords: スピントロニクス / 磁気ナノ構造 / 誘電体 / 光電流 / トンネル効果

Outline of Final Research Achievements

In this study, we explore the possibility of photo-induced large magnetodielectric effect in photo-magnetic nanogranular (p-MNG), in which magnetic nanoparticles are dispersed in perovskite solar cell (PSC). As a result, we have successfully observed magnetodielectric effect in magnetic nanogranular, in which Fe magnetic nanoparticles are dispersed in MgF2 insulating matrix, and the experimental data can be well explained by theoretical calculation based on Debye-Frolich model. Moreover, we have successfully observed photodielectric effect in CH3NH3PbI3 PSC. As we carried out the calculation of photo-induced magnetodielectric effect in p-MNG, based on these experimental and calculation results, we found that a large magnetodielectric effect could be observed.

Academic Significance and Societal Importance of the Research Achievements

本研究課題の推進により、ペロブスカイト太陽電池に磁気ナノ粒子を分散させた新しいタイプの光磁気ナノグラニュラーにおいて、光誘起型巨大磁気誘電効果の発現が期待できることが理論的に明らかになった。今後は、当該研究を更に推進させることで、光学(特に太陽電池研究分野)と磁性(特にスピントロニクス)、そして、誘電性が互いに融合した新たな学際領域の創出が期待できるとともに、次世代超高性能磁気センサ・メモリ、インピーダンスチューナブル素子の実現に向けた新たな設計指針を導けるものと考えられる。

Research Products

• [Int'l Joint Research] ブラウン大学(米国)
• [Int'l Joint Research] ブラウン大学(米国)
• [Journal Article] Ferroelectric Alkylamide Substituted Helicene Derivative with 2D Hydrogen-Bonding Lamellar Phase (2019)
  • Author(s): Hayato Anetai, Takashi Takeda, Norihisa Hoshino, Higashi Kobayashi, Nozomi Saito, Masanori Shigeno, Masahiko Yamaguchi, and Tomoyuki Akutagawa
  • Journal Title: J. Am. Chem. Soc. Volume: 141 Pages: 2391-2397
  • Peer Reviewed
• [Journal Article] A trinuclear iron(III) complex of a triple non-innocent ligand toward spin-structured molecular conductors (2019)
  • Author(s): Norihisa Hoshino and Tomoyuki Akutagawa
  • Journal Title: Chem. Eur. J. Volume: 24 Issue: 72 Pages: 19323-19331
  • DOI: 10.1002/chem.201804280
  • Peer Reviewed
• [Journal Article] Dynamic Motion of Organic Ligands in Polar Layered Cobalt Phosphonates (2018)
  • Author(s): Cai Zhong-Sheng、Hoshino Norihisa、Bao Song-Song、Jia Jiage、Akutagawa Tomoyuki、Zheng Li-Min
  • Journal Title: Chemistry - A European Journal Volume: 24 Issue: 51 Pages: 13495-13503
  • DOI: 10.1002/chem.201801301
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Robustness of Voltage-induced Magnetocapacitance (2018)
  • Author(s): H. Kaiju, T. Misawa, T. Nagahama, T. Komine, O. Kitakami, M. Fujioka, J. Nishii, and G. Xiao
  • Journal Title: Scientific Reports Volume: 8 Issue: 1
  • DOI: 10.1038/s41598-018-33065-y
  • NAID: 120006536950
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] ESIPT fluorescent chromism and conformational change of 2-(2-hydroxyphenyl-5'-sulfonic acid)benzothiazole by amine sorption (2018)
  • Author(s): Y. Nakane, T. Takeda, N. Hoshino, K. Sakai, and T. Akutagawa
  • Journal Title: J. Phys. Chem. C Volume: 122 Issue: 28 Pages: 16249-16255
  • DOI: 10.1021/acs.jpcc.8b03248
  • Peer Reviewed
• [Journal Article] Magnetic Response of Random Lasing Modes in a ZnO nanoparticle film deposited on a NiFe thin film (2018)
  • Author(s): Hideki Fujiwara, Hideo Kaiju, Junji Nishii, Keiji Sasaki
  • Journal Title: Applied Physics Letters Volume: 113 Issue: 13 Pages: 131108-131108
  • DOI: 10.1063/1.5040720
  • NAID: 120006725825
  • Peer Reviewed
• [Journal Article] Dynamic Molecular Assemblies Toward a New Frontier in Materials Chemistry (2018)
  • Author(s): Tomoyuki Akutagawa
  • Journal Title: Mater. Chem. Front. Volume: 2 Issue: 6 Pages: 1064-1073
  • DOI: 10.1039/c7qm00603a
  • Peer Reviewed
• [Presentation] Tunnel Magnetocapacitance in Single-layered Fe/MgF2 Granular Films (2018)
  • Author(s): R. Msiska, S. Honjo, Y. Asai, M. Arita, A. T. Fukuchi, Y. Takahashi, N. Hoshino, T. Akutagawa, O. Kitakami, M. Fujioka, J. Nishii and H. Kaiju
  • Organizer: 第79回応用物理学会秋季学術講演会
• [Presentation] ボウル状トリチアスマネン誘導体の強誘電性 (2018)
  • Author(s): Wu JianYun、武田 貴志、星野 哲久、甲山 雅也、古川 俊輔、斎藤 雅一、芥川 智行
  • Organizer: 第12回分子科学討論会2018
• [Presentation] Tunnel Magnetocapacitance in Fe/MgF2 Magnetic Nanogranular Films (2018)
  • Author(s): R. Msiska, S. Honjo, Y. Asai, M. Arita, A. T. Fukuchi, Y. Takahashi, N. Hoshino, T. Akutagawa, O. Kitakami, M. Fujioka, J. Nishii and H. Kaiju
  • Organizer: 平成30年度物質・デバイス領域共同研究拠点 展開共同研究B「新機能創出に向けたスピンダイナミクスに関する研究」研究会
• [Presentation] ジアルキルテレフタルアミド誘導体の強誘電性 (2018)
  • Author(s): 川名 萌枝子、武田 貴志、星野 哲久、芥川 智行
  • Organizer: 第12回分子科学討論会2018
• [Presentation] Study on Tunnel Magnetocapacitance in Fe/MgF2 Nanogranular Films (2018)
  • Author(s): R. Msiska, S. Honjo, Y. Asai, M. Arita, A. T. Fukuchi, Y. Takahashi, N. Hoshino, T. Akutagawa, O. Kitakami, M. Fujioka, J. Nishii and H. Kaiju
  • Organizer: 日本材料科学会第4回マテリアルズ・インフォマティクス基礎研究会
• [Presentation] 分子性材料の基礎と将来 (2018)
  • Author(s): 芥川智行
  • Organizer: 第２２８回フォトポリマー懇話会
  • Invited
• [Presentation] Magnetocapacitance effect in magnetic tunnel junctions (2018)
  • Author(s): H. Kaiju, T. Nagahama, O. Kitakami, J. Nishii, and G. Xiao
  • Organizer: 14th Hokkaido University-Nanjing University-NIMS/MANA Joint Symposium
  • Int'l Joint Research / Invited
• [Presentation] 力で形を変える結晶～有機強弾性 (2018)
  • Author(s): 芥川智行
  • Organizer: 第８回CSJフェスタ
  • Invited
• [Presentation] Tunnel Magnetocapacitance in Single-layered Fe/MgF2 Magnetic Granular Films (2018)
  • Author(s): R. Msiska, S. Honjo, Y. Asai, M. Arita, A. T. Fukuchi, Y. Takahashi, N. Hoshino, T. Akutagawa, O. Kitakami, M. Fujioka, J. Nishii and H. Kaiju
  • Organizer: The 19th RIES-Hokudai International Symposium
  • Int'l Joint Research
• [Presentation] Ferroelectricity of Alkylamide-Substituted Helicene Derivatives (2018)
  • Author(s): Hayato Anetai, Takashi Takeda, Norihisa Hoshino, Higashi Kobayashi, Nozomi Saito, Masanori Shigeno, Masahiko Yamaguchi, and Tomoyuki Akutagawa
  • Organizer: The International Conference on Science and Technology of Synthetic Metals 2018
  • Int'l Joint Research
• [Presentation] Ferroelectric Non pi-planar Helicene Derivatives bearing Alkylamide-Chains (2018)
  • Author(s): H. Anetai, T. Takeda, N. Hoshino, H. Kobayashi, N. Saito, M. Shigeno, M. Yamaguchi, T. Akutagawa
  • Organizer: The 43rd International Conference on Coordination Chemistry
  • Int'l Joint Research
• [Presentation] Ferroelectric Bowl-to-Bowl Inversion System Based on Trithiasumanene Derivative (2018)
  • Author(s): Tomoyuki Akutagawa, Jianyun Wu, Shunsuke Furukawa, Masaichi Saito
  • Organizer: π-EJ 2018 π-System Figuration European-Japanese Workshop 2018
  • Int'l Joint Research / Invited
• [Presentation] Ferroelectricity and Bowl-to-Bowl Inversion of Trithiasumanene Derivative (2018)
  • Author(s): Tomoyuki Akutagawa, Jianyun Wu, Shunsuke Furukawa, Masaichi Saito
  • Organizer: The 8th TOYOTA RIKEN International Workshop: Organic Semiconductors, Conductors, and Electronics
  • Int'l Joint Research / Invited
• [Presentation] スピンデバイスにおける磁気誘電効果の理論とその実証 (2018)
  • Author(s): 海住英生、長浜太郎、北上修、西井準治、Xiao Gang
  • Organizer: 第2回マテリアルズ・インフォマティクス基礎研究会
  • Invited
• [Presentation] Fe/AlOx/Fe3O4磁気トンネル接合における逆磁気キャパシタンス効果 (2018)
  • Author(s): 海住英生、長浜太郎、佐々木駿、島田敏宏、北上修、三澤貴浩、西井準治、Xiao Gang
  • Organizer: 日本物理学会第73回年次大会
• [Presentation] 磁気トンネル接合における逆磁気キャパシタンス効果 (2017)
  • Author(s): 海住英生、長浜太郎、北上修、西井準治、Gang Xiao
  • Organizer: 第22回スピン工学の基礎と応用
  • Invited
• [Presentation] Inverse Tunnel Magnetocapacitance in Fe/Al-oxide/Fe3O4 (2017)
  • Author(s): H. Kaiju, T. Nagahama, S. Sasaki, T. Shimada, O. Kitakami, T. Misawa, M. Fujioka, J. Nishii and G. Xiao
  • Organizer: 62nd Annual Conference on Magnetism and Magnetic Materials
  • Int'l Joint Research
• [Presentation] Study of Ni78Fe22/Alq3/Ni78Fe22 nanoscale junction devices utilizing thin-film edges (2017)
  • Author(s): Y. Sasaki, T. Misawa, R. Msiska, S. Mori, T. Komine, N. Hoshino, T. Akutagawa, M. Fujioka, J. Nishii, H. Kaiju
  • Organizer: The 18th RIES-Hokudai International Symposium
  • Int'l Joint Research
• [Presentation] キラルアンモニウムを用いた層状ハロゲン化金属ペロブスカイトの結晶構造と誘電応答 (2017)
  • Author(s): 高橋正樹、星野哲久、武田貴志、芥川智行
  • Organizer: 第11回分子科学討論会
• [Presentation] Phase Transition, Crystal Structure, and Dielectric Response of Two-Dimensional Perovskites Including Chiral Ammonium (2017)
  • Author(s): M. Takahashi, N. Hoshino, T. Takeda, and T. Akutagawa
  • Organizer: The 6th Asian Conference on Coordination Chemistry (ACCC6)
  • Int'l Joint Research
• [Remarks] 研究室ホームページ
  • URL: http://nanostructure.es.hokudai.ac.jp/