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Fine Control of Metal Arrangement in Transition Metal Clusters

Research Project

Project/Area Number 18064011
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionOsaka University

Principal Investigator

MURAHASHI Tetsuro  Osaka University, 工学研究科, 准教授 (40314380)

Project Period (FY) 2006 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥25,500,000 (Direct Cost: ¥25,500,000)
Fiscal Year 2009: ¥6,800,000 (Direct Cost: ¥6,800,000)
Fiscal Year 2008: ¥6,800,000 (Direct Cost: ¥6,800,000)
Fiscal Year 2007: ¥6,800,000 (Direct Cost: ¥6,800,000)
Fiscal Year 2006: ¥5,100,000 (Direct Cost: ¥5,100,000)
Keywords金属クラスター / 構造制御 / 金属-金属間結合 / 金属錯体 / パラジウム / 共役ポリエン / 金属鎖 / クラスター / 金属核配列 / π-配位 / 精密合成 / 多環式芳香族化合物
Research Abstract

The one-dimensional metal wires or two-dimensional metal sheets are the attractive class of metal assemblies for catalysis and materials science. However, it has been difficult to construct such low-dimensional metal frameworks in a discrete molecule, because the synthetic method to build-up the low-dimensional metal assembly in a size- and shape-selective manner has not developed. In this project, we successfully developed an efficient method to construct low-dimensional metal assemblies by means of an organometallic approach.

Report

(6 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report   Self-evaluation Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (51 results)

All 2011 2010 2009 2008 2007 2006

All Journal Article (20 results) (of which Peer Reviewed: 17 results) Presentation (31 results)

  • [Journal Article] Metallocenoids of Platinum : Syntheses and Structures of Triangular Triplatinum Sandwich Complexes of Cycloheptatrienyl2011

    • Author(s)
      T.Murahashi, K.Usui, R.Inoue, S.Ogoshi, H.Kurosawa
    • Journal Title

      Chem.Sci. 2

      Pages: 117-117

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Square Tetrapalladium Sheet Sandwich Complexes : Cyclononatetraenyl as a Versatile Face-Capping Ligand2009

    • Author(s)
      T.Murahashi, R.Inoue, K.Usui, S.Ogoshi
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 9888-9888

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Square Tetrapalladium Sheet Sandwich Complexes : Cyclononatetraenyl as a Versatile Face-Capping Ligand2009

    • Author(s)
      T.Murahashi
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 131 Pages: 9888-9889

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structures of Two Haptotropic Isomers Generated by the Sliding of 1,3,5-Triene Ligands on a Pd-Pd-Pd Chain2008

    • Author(s)
      T.Murahashi, Y.Mino, K.Chiyoda, S.Ogoshi, H.Kurosawa
    • Journal Title

      Chem.Commun.

      Pages: 4061-4063

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Stable Zerovalent Palladium Chain Enveloped by a π-Electron Sheath of Conjugated Polyene Ligands2008

    • Author(s)
      Y.Tatsumi, T.Murahashi, M.Okada, S.Ogoshi, H.Kurosawa
    • Journal Title

      Chem.Commun.

      Pages: 477-479

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Stable Zerovalent Palladium Chain Enveloped by a π-Electron Sheath of Conjugated Polyene Ligands2008

    • Author(s)
      Y. Tatsumi, T. Murahashi, M. Okada, S. Ogoshi, H. Kurosawa
    • Journal Title

      Chem. Commun.

      Pages: 477-479

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Structures of two haptotropic isomers generated by the sliding of 1,3,5-triene ligands on a Pd-Pd-Pd chain2008

    • Author(s)
      T.Murahashi
    • Journal Title

      Chem.Commun.

      Pages: 4061-4063

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Stable Zerovalent Palladium Chain Enveloped by a p-Electron Sheath of Conjugated Polyene Ligands2008

    • Author(s)
      T. Murahashi
    • Journal Title

      Chem. Commun.

      Pages: 477-479

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rearrangement of a Pd4 Skeleton from a 1D Chain to a 2D Sheet on the Face of Perylene or Fluoranthene Ligand Caused by Exchange of the Binder Molecule2007

    • Author(s)
      T.Murahashi, N.Kato, T.Uemura, H.Kurosawa
    • Journal Title

      Angew.Chem.Int.Ed. 46

      Pages: 3509-3512

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rearrangement of a Pd4 Skeleton from a 1D Chain to a 2D Sheet on the Face of Perylene or Fluoranthene Ligand Caused by Exchange of the Binder Molecule2007

    • Author(s)
      T. Murahashi, N. Kato, T. Uemura, H. Kurosawa
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 3509-3512

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Rearrangement of a Pd4 Skeleton from a 1D Chain to a 2D Sheet on the Face of Perylene or Fluoranthene Ligand Caused by Exchange of the Binder Molecule2007

    • Author(s)
      T. Murahashi
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 3579-3582

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dinuclear Addition of the Pd-Pd Moieties to 1,3-Dienes、2006

    • Author(s)
      T.Murahashi, T.Nagai, H.Nakashima, T.Tomiyasu, H.Kurosawa
    • Journal Title

      Chem.Lett.

      Pages: 754-755

    • NAID

      10017604452

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sandwich Complexes Containing Bent Palladium Chains2006

    • Author(s)
      Y.Tatsumi, K.Shirato, T.Murahashi, S.Ogoshi, H.Kurosawa
    • Journal Title

      Angew.Chem.Int.Ed.Engl. 45

      Pages: 5799-5803

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Discrete Sandwich Compounds of Monolayer Palladium Sheets2006

    • Author(s)
      T.Murahashi, M.Fujimoto, M.Oka, Y.Hashimoto, T.Uemura, Y.Tatsumi, Y.Nakao, A.Ikeda, S.Sakaki, H.Kurosawa
    • Journal Title

      Science 313

      Pages: 1104-1107

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Discrete Sandwich Compounds of Monolayer Palladium Sheets2006

    • Author(s)
      Hashimoto, T. Uemura, Y. Tatsumi, Y. Nakao, A. Ikeda, S. Sakaki, H. Kurosawa
    • Journal Title

      Science 313

      Pages: 1104-1107

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Sandwich Complexes Containing Bent Palladium Chains2006

    • Author(s)
      Y. Tatsumi, K. Shirato, T. Murahashi, S. Ogoshi, H. Kurosawa
    • Journal Title

      Angew. Chem. Int. Ed. Engl. 45

      Pages: 5799-5803

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Dinuclear Addition of the Pd-Pd Moieties to 1,3-Dienes2006

    • Author(s)
      T. Murahashi, T. Nagai, H. Nakashima, T. Tomiyasu, H. Kurosawa
    • Journal Title

      Chem. Lett.

      Pages: 754-755

    • NAID

      10017604452

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Discrete Sandwich Compounds of Monlayer Palladium Sheets2006

    • Author(s)
      Tetsuro Murahashi et al.
    • Journal Title

      Science 313

      Pages: 1104-1104

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Sandwich Complexes Containing Bent Palladium Chains2006

    • Author(s)
      Tetsuro Murahashi et al.
    • Journal Title

      Angew. Chem. Int. Ed. 45

      Pages: 5799-5799

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Dinuclear Addition of the Pd-Pd Moieties to 1,3-Dienes2006

    • Author(s)
      Tetsuro Murahashi et al.
    • Journal Title

      Chem. Lett.

      Pages: 754-754

    • NAID

      10017604452

    • Related Report
      2006 Annual Research Report
  • [Presentation] アリール配位子を持つシクロヘプタトリエニル白金3核サンドイッチ錯体の合成と構造2010

    • Author(s)
      臼井謙太郎、村橋哲郎、生越専介
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-26
    • Related Report
      2009 Final Research Report
  • [Presentation] アリール配位子を持つシクロヘプタトリエニル白金3核サンドイッチ錯体の合成と構造2010

    • Author(s)
      臼井謙太郎、村橋哲郎、生越専介
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] Square Tetrapalladium Sheet Sandwich Complexes、特定領域研究「元素相乗系化合物の化学」2010

    • Author(s)
      Tetsuro Murahashi, Ryou Inoue, Kentaro Usui, Sensuke Ogoshi
    • Organizer
      第5回公開シンポジウム
    • Place of Presentation
      札幌
    • Year and Date
      2010-03-08
    • Related Report
      2009 Final Research Report
  • [Presentation] Square Tetrapalladium Sheet Sandwich Complexes2009

    • Author(s)
      Tetsuro Murahashi, Ryou Inoue, Kentaro Usui, Sensuke Ogoshi
    • Organizer
      9th Tateshina Conference on Organic Chemistry
    • Place of Presentation
      蓼科
    • Year and Date
      2009-11-14
    • Related Report
      2009 Final Research Report
  • [Presentation] Square Tetrapalladium Sheet Sandwich Complexes2009

    • Author(s)
      Tetsuro Murahashi, Ryou Inoue, Kentaro Usui, Sensuke Ogoshi
    • Organizer
      5th Spanish-Portuguese-Japanese Organic Chemistry Symposium
    • Place of Presentation
      大阪
    • Year and Date
      2009-11-07
    • Related Report
      2009 Final Research Report
  • [Presentation] シクロノナテトラエニル配位子を有するパラジウムクラスターの合成と構造2009

    • Author(s)
      臼井謙太郎・井上亮・村橋哲郎・生越専介
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Chemistry of Metal Sheet Sandwich Complexes2009

    • Author(s)
      Tetsuro Murahashi
    • Organizer
      4th International Workshop on Molecular Technology of the Future
    • Place of Presentation
      Delft, Netherland
    • Year and Date
      2009-09-15
    • Related Report
      2009 Final Research Report
  • [Presentation] Chemistry of Metal Sheet Sandwich Complexes2009

    • Author(s)
      T.Murahashi
    • Organizer
      4th International Workshop on Molecular Technology of the Future
    • Place of Presentation
      オランダ・デルフト
    • Year and Date
      2009-09-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] シクロヘプタトリエニル白金3核サンドイッチ錯体の合成と構造2009

    • Author(s)
      臼井謙太郎・井上亮・村橋哲郎・生越専介・黒澤英夫
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      田辺
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Discrete Multinuclear Sandwich Complexes of Palladium and Platinum2009

    • Author(s)
      Tetsuro Murahashi
    • Organizer
      Japan-Canada Coordination Space Symposium 2009
    • Place of Presentation
      Banff, Canada
    • Year and Date
      2009-07-09
    • Related Report
      2009 Final Research Report
  • [Presentation] Discrete Multinuclear Sandwich Complexes of Palladium and Platinum2009

    • Author(s)
      T.Murahashi
    • Organizer
      Japan-Canada Coordination Space Symposium 2009
    • Place of Presentation
      カナダ・バンフ
    • Year and Date
      2009-07-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] シクロヘプタトリエニルを配位子とするサンドイッチ型白金3核錯体の合成と構造2009

    • Author(s)
      臼井謙太郎・井上亮・村橋哲郎・生越専介・黒澤英夫
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-30
    • Related Report
      2009 Final Research Report
  • [Presentation] 2つのパラジウム2核ユニットを持つサンドイッチ型錯体の合成2009

    • Author(s)
      福島あづさ・松谷晃男・白戸克典・村橋哲郎・生越専介・黒澤英夫
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-28
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 2 つのパラジウム2 核ユニットを持つサンドイッチ型錯体の合成2009

    • Author(s)
      福島あづさ・松谷晃男・白戸克典・村橋哲郎・生越専介・黒澤英夫
    • Organizer
      日本化学会第89 春季年会
    • Place of Presentation
      船橋
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] Assembling and Shaping of Multiple Metal Atoms by Unsaturated Hydrocarbons2008

    • Author(s)
      T.Murahashi
    • Organizer
      Japan-China Joint Symposium on Functional Supramolecular Architectures
    • Place of Presentation
      北京
    • Year and Date
      2008-12-20
    • Related Report
      2009 Final Research Report 2008 Self-evaluation Report
  • [Presentation] サンドイッチ型トリエンパラジウム3核鎖錯体の構造-分子間相互作用の影響2008

    • Author(s)
      美野裕香里・千代田幸治・福島あづさ・村橋哲郎・生越専介・黒沢英夫
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢
    • Year and Date
      2008-09-21
    • Related Report
      2009 Final Research Report 2008 Annual Research Report 2008 Self-evaluation Report 2007 Annual Research Report
  • [Presentation] Multinuclear Sandwich Complexes of Palladium2008

    • Author(s)
      T.Murahashi
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      Rennes
    • Year and Date
      2008-07-14
    • Related Report
      2009 Final Research Report
  • [Presentation] Multinuclear Sandwich Complexes of Palladium2008

    • Author(s)
      T.Murahashi
    • Organizer
      23^<rd> International Conference on Organometallic Chemistry (ICOMC2008)
    • Place of Presentation
      フランス、レンヌ
    • Year and Date
      2008-07-14
    • Related Report
      2008 Annual Research Report
  • [Presentation] Organometallic Sandwich Clusters Containing Triangular Tripalladium Cores2008

    • Author(s)
      T.Murahashi, M.Fujimoto, Y.Hashimoto, R.Inoue, K.Chiyoda, T.Uemura, Y.Kawabata, S.Ogoshi, H.Kurosawa
    • Organizer
      第88春季年会アジア国際シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2008-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Organometallic Sandwich Clusters Containing Triangular Tripalladium Cores2008

    • Author(s)
      T. Murahashi, M. Fujimoto, Y. Hashimoto, R. Inoue, K. Chiyoda, T. Uemura, Y. Kawabata, S. Ogoshi, H. Kurosawa
    • Organizer
      第88 春季年会アジア国際シンポジウム
    • Place of Presentation
      東京
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] Multinuclear Sandwich Complexes of Palladium2008

    • Author(s)
      T. Murahashi
    • Organizer
      23^<rd> International Conference on Organometallic Chemistry (ICOMC2008)
    • Place of Presentation
      Rennes
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] μ4シクロオクタテトラエン配位子を有する菱形4核パラジウム錯体の合成と構造2007

    • Author(s)
      井上亮・加藤尚弘・上村朋史・辰巳泰基・村橋哲郎・生越専介・黒澤英夫
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-10-27
    • Related Report
      2009 Final Research Report
  • [Presentation] 不飽和炭化水素配位子上での4核パラジウムの1D鎖から2Dシートへの形状変換2007

    • Author(s)
      村橋哲郎・加藤尚弘・上村朋史・井上亮・辰己泰基・生越専介・黒沢英夫
    • Organizer
      第54回有機金属化学討論会
    • Place of Presentation
      広島
    • Year and Date
      2007-10-27
    • Related Report
      2009 Final Research Report
  • [Presentation] Rearrangement of a Pd_4 Skeleton from a 1D Chain to a 2D Sheet on the Face of Unsaturated Hydrocarbon Ligands2007

    • Author(s)
      T. Murahashi
    • Organizer
      第56回有機金属討論会
    • Place of Presentation
      東広島
    • Year and Date
      2007-10-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] o-フェニレンを含有する共役ポリエン系配位子を用いたパラジウム複核錯体の合成と構造2007

    • Author(s)
      白戸克典・辰巳泰基・村橋哲郎・生越専介・黒澤英夫
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-26
    • Related Report
      2009 Final Research Report
  • [Presentation] μ_4-シクロオクタテトラエン配位子を有する菱形4核パラジウム錯体の合成と構造2007

    • Author(s)
      井上 亮
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-26
    • Related Report
      2007 Annual Research Report
  • [Presentation] 1,2-ビス(4-フェニル-1,3-ブタジエニル)ベンゼンパラジウム四核鎖サンドイッチ錯体の異性化反応2007

    • Author(s)
      白戸克典・辰巳泰基・村橋哲郎・黒沢英夫
    • Organizer
      第87春季年会
    • Place of Presentation
      吹田
    • Year and Date
      2007-03-25
    • Related Report
      2009 Final Research Report
  • [Presentation] 1,2-ビス(4-フェニル-1,3-ブタジエニル)ベンゼンパラジウム四核鎖サンドイッチ錯体の異性化反応2007

    • Author(s)
      白戸克典・辰巳泰基・村橋哲郎・黒沢英夫
    • Organizer
      第87 春季年会
    • Place of Presentation
      吹田
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] 不飽和炭化水素配位子上での4核パラジウムの1D鎖から2Dシートへの形状変換2007

    • Author(s)
      村橋哲郎・加藤尚弘・上村朋史・井上亮・辰己泰基・生越専介・黒沢英夫
    • Organizer
      第54 回有機金属化学討論会
    • Place of Presentation
      広島
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] o-フェニレンを含有する共役ポリエン系配位子を用いたパラジウム複核錯体の合成と構造2007

    • Author(s)
      白戸克典・辰巳泰基・村橋哲郎・生越専介・黒澤英夫
    • Organizer
      第57 回錯体化学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] μ_4-シクロオクタテトラエン配位子を有する菱形4核パラジウム錯体の合成と構造2007

    • Author(s)
      井上亮・加藤尚弘・上村朋史・辰巳泰基・村橋哲郎・生越専介・黒澤英夫
    • Organizer
      第57 回錯体化学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Self-evaluation Report

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Published: 2006-04-01   Modified: 2018-03-28  

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