Fine Control of Metal Arrangement in Transition Metal Clusters
| Project/Area Number |
18064011
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
|
| Allocation Type | Single-year Grants |
|---|
| Review Section |
Science and Engineering
|
|---|
| Research Institution | Osaka University |
|---|
Principal Investigator |
MURAHASHI Tetsuro Osaka University, 工学研究科, 准教授 (40314380)
|
|---|
| Project Period (FY) |
2006 – 2009
|
| Project Status |
Completed (Fiscal Year 2009)
|
| Budget Amount *help |
¥25,500,000 (Direct Cost: ¥25,500,000)
Fiscal Year 2009: ¥6,800,000 (Direct Cost: ¥6,800,000)
Fiscal Year 2008: ¥6,800,000 (Direct Cost: ¥6,800,000)
Fiscal Year 2007: ¥6,800,000 (Direct Cost: ¥6,800,000)
Fiscal Year 2006: ¥5,100,000 (Direct Cost: ¥5,100,000)
|
|---|
| Keywords | 金属クラスター / 構造制御 / 金属-金属間結合 / 金属錯体 / パラジウム / 共役ポリエン / 金属鎖 / クラスター / 金属核配列 / π-配位 / 精密合成 / 多環式芳香族化合物 |
|---|
| Research Abstract |
The one-dimensional metal wires or two-dimensional metal sheets are the attractive class of metal assemblies for catalysis and materials science. However, it has been difficult to construct such low-dimensional metal frameworks in a discrete molecule, because the synthetic method to build-up the low-dimensional metal assembly in a size- and shape-selective manner has not developed. In this project, we successfully developed an efficient method to construct low-dimensional metal assemblies by means of an organometallic approach.
|
Report
(6 results)
Research Products
(51 results)
