| Project/Area Number |
18066003
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | The University of Tokyo |
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Principal Investigator |
NISHIBAYASHI Yoshiaki The University of Tokyo, 大学院・工学系研究科, 准教授 (40282579)
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| Co-Investigator(Kenkyū-buntansha) |
SAKATA Ken 星薬科大学, 薬学部, 准教授 (90328922)
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| Co-Investigator(Renkei-kenkyūsha) |
SAKATA Ken 星薬科大学, 薬学部, 准教授 (90328922)
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| Project Period (FY) |
2006 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥19,900,000 (Direct Cost: ¥19,900,000)
Fiscal Year 2009: ¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2008: ¥5,900,000 (Direct Cost: ¥5,900,000)
Fiscal Year 2007: ¥5,900,000 (Direct Cost: ¥5,900,000)
Fiscal Year 2006: ¥4,500,000 (Direct Cost: ¥4,500,000)
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| Keywords | 新規触媒反応 / 不斉合成 / 分子理論 / 反応機構 / ルテニウム / 理論計算 / プロパルギルアルコール / 複核錯体 / 硫黄架橋 / アレニリデン錯体 / 銅 / 結合開裂 / 共役エンイン / プロパルギル位置換反応 / 硫黄 / 光学活性配位子 |
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| Research Abstract |
Our recent studies on catalytic reactions via ruthenium-allenylidene complexes are summarized here. Thiolate-bridged diruthenium complexes work as efficient catalysts to promote a variety of novel organic transformations [1,2], especially propargylic substituion reactions and their asymmetric versions, via allenylidene complexes as key and common reactive intermediates.
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