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Design of efficient titanium complex catalyst for evolution of new polyolefins by precise olefin polymerization

Research Project

Project/Area Number 18350055
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionNara Institute of Science and Technology

Principal Investigator

NOMURA Kotohiro  Nara Institute of Science and Technology, 物質創成科学研究科, 准教授 (20304165)

Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥17,850,000 (Direct Cost: ¥15,600,000、Indirect Cost: ¥2,250,000)
Fiscal Year 2008: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2007: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2006: ¥8,100,000 (Direct Cost: ¥8,100,000)
Keywords触媒設計・反応 / 配位子設計 / 新規ポリマー / チタン錯体触媒 / 精密重合 / 遷移金属錯体触媒 / エチレン系ポリマー / 均一系触媒 / 機構解析
Research Abstract

従来触媒では達成できない新規ポリオレフィンの精密合成を可能とする高性能分子触媒の設計・創製や合成したポリマーの構造・特性解析を主目的として課題に取り組み、期間内に以下の特筆すべき成果を得た.(1) エチレンとかさ高い置換基を有する1置換オレフィンや2置換オレフィン、環状オレフィンとの共重合体の高効率精密合成手法の確立、(2) 官能基化ポリオレフィンの精密合成新手法の提案と新規ポリマーの創製、(3) 高性能分子触媒の創製と重合機構の解明.

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (74 results)

All 2009 2008 2007 2006 Other

All Journal Article (42 results) (of which Peer Reviewed: 39 results) Presentation (26 results) Book (5 results) Remarks (1 results)

  • [Journal Article] Copolymerization of ethylene with alfa-olefins containing various substituents catalyzed by half-titanocenes2009

    • Author(s)
      K. Kakinuki, M. Fujiki, K. Nomura
    • Journal Title

      Factors affecting the monomer reactivities, Macromolecules (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Copolymerization of ethylene with tert-buytlethylene using nonbridged half-titanocene - cocatalyst systems2009

    • Author(s)
      F. Z. Khan, K. Kakinuki, K. Nomura
    • Journal Title

      Macromolecules 42

      Pages: 3767-3773

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and structural analysis of half-titanocenes containing η2-pyrazolato ligands, and their use in the catalysis for olefin polymerization2009

    • Author(s)
      I. Saeed, S. Katao, K. Nomura
    • Journal Title

      Inorganic Chemistry 48

      Pages: 5011-5020

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ethylene polymerization and ethylene/1-octene copolymerization using group 4 half-metallocenes containing aryloxo ligands2009

    • Author(s)
      K. Itagaki, S. Hasumi, M. Fujiki, K. Nomura
    • Journal Title

      Cp*MCl_2(Oar) [M=Ti, Zr, Hf ; Ar=O-2,6-R_2C_6H_3, R=^tBu, Ph] - MAO catalyst systems, J. Mol. Catal. A 303

      Pages: 102-109

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tris(pyrazolyl)borate Ti(IV) complexes containing phenoxy ligands : Effective catalyst precursors for ethylene polymerization that proceeds via cationic Ti(IV) species2009

    • Author(s)
      K. Itagaki, K. Kakinuki, S. Katao, T. Khamnaen, M. Fujiki, K. Nomura, S. Hasumi
    • Journal Title

      Organometallics 28

      Pages: 1942-1949

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and structural analysis of (cyclopentadienyl)(pyrrolide)-titanium(IV) complexes and their use in the catalysis for olefin polymerization2009

    • Author(s)
      I. Saeed, S. Katao, K. Nomura
    • Journal Title

      Organometallics 28

      Pages: 111-122

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Copolymerization of ethylene with tert-buytlethylene using nonbridged half-titanocene-cocatalyst systems2009

    • Author(s)
      Kotorhio Nomura, 他
    • Journal Title

      Macromolecules 42(ASAP)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copolymerization of ethylene with α-olefins containing various substituents catalyzed by half-titanocenes : Factors affecting the monomer reactivities2009

    • Author(s)
      Kotorhio Nomura, 他
    • Journal Title

      Macromolecules 42(accepted)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nonbridged half-titanocenes as effective catalysts for synthesis of new polyolefins by olefin copolymerization2008

    • Author(s)
      K. Nomura, J. Liu, B. Kitiyanan
    • Journal Title

      Current Topics in Catalysis 7

      Pages: 1-20

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Recent progress in precise synthesis of polyolefins containing polar functionalities by transition metal catalysis2008

    • Author(s)
      K. Nomura, B. Kitiyanan
    • Journal Title

      Cur. Org. Synth. 5

      Pages: 217-226

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct precise functional group introduction into polyolefins : Efficient incorporation of vinyltrialkylsilanes in ethylene copolymerizations by nonbridged half-titanocenes2008

    • Author(s)
      K. Nomura, K. Kakinuki, M. Fujiki, K. Itagaki
    • Journal Title

      Macromolecules 41

      Pages: 8974-8976

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Efficient functional group introduction into polyolefins by copolymerization of ethylene with allyltrialkylsilane using nonbridged half-titanocenes2008

    • Author(s)
      J. Liu, K. Nomura
    • Journal Title

      Macromolecules 41

      Pages: 1070-1072

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Factors affecting product distributions in ethylene/styrene copolymerization by (aryloxo)(cyclopentadienyl)- titanium complexes - MAO catalyst systems2008

    • Author(s)
      K. Nomura, H. Zhang, D.-J. Byun
    • Journal Title

      J.Polym. Sci. PartA : Polym. Chem. 46

      Pages: 4162-4174

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nonbridged half-titanocenes containing anionic ancillary donor ligands : Promising new catalysts for precise synthesis of cyclic olefin copolymers (COCs)2008

    • Author(s)
      K. Nomura
    • Journal Title

      Chin. J. Polym. Sci. 26

      Pages: 513-523

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct functional group introduction into polyolefins : Efficient incorporation of vinyltrialkylsilanes in ethylene copolymerizations by nonbridged half-titanocenes2008

    • Author(s)
      Kotorhio Nomura, 他
    • Journal Title

      Macromolecules 41

      Pages: 8974-8976

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nonbridged half-titanocenes as effective catalysts for synthesis of new polyolefins by olefin copolymerization"2008

    • Author(s)
      Kotorhio Nomura, 他
    • Journal Title

      Current Topics in Catalysis, Research Trends(Feature Article) 7

      Pages: 1-20

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 新規ポリオレフィンの創製を可能とする高性能遷移金属錯体触媒の設計・創製2008

    • Author(s)
      野村琴広, 他
    • Journal Title

      (社)日本ゴム協会誌 81

      Pages: 400-407

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高性能ハーフチタノセン錯体触媒による新規ポリマーの精密合成 : 極性官能基化ポリオレフィンの環境調和型の精密合成新手法2008

    • Author(s)
      野村琴広, 他
    • Journal Title

      「次世代ポリオレフィン総合研究」, 郷 茂夫, 寺 野稔(編) 1

      Pages: 400-407

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高性能チタン錯体触媒の配位子設計と新規ポリマーの創製2008

    • Author(s)
      野村琴広, 他
    • Journal Title

      「次世代ポリオレフィン総合研究」, 郷 茂夫, 寺野 稔(編) 2

      Pages: 74-79

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nonbridged half-titanocenes containing anionic ancillary donor ligands: Promising new catalysts for precise synthesis of cyclic olefin copolymers(COCs)2008

    • Author(s)
      Kotohiro Nomura, 他
    • Journal Title

      Chinese Journal of Polymer Science(Feature Article) (accepted)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Factors affecting product distributions in ethylene/styrene copolymerization by(aryloxo)(cyclopentadienyl)titanium complexes-MAO catalyst systems2008

    • Author(s)
      Kotohiro Nomura, 他
    • Journal Title

      Journal of Polymer Science PartA: Polymer Chemistry (in press)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recent progress in precise synthesis of polyolefins containing polar functionalities by transition metal catalysis2008

    • Author(s)
      Kotohiro Nomura, 他
    • Journal Title

      Current Organic Synthesis(Review) (in press)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高機能ポリオレフィンの創製を指向した高性能分子触媒-新しいエチレン系ポリマーの創製を可能とした研究例-触媒技術の動向と展望20072007

    • Author(s)
      野村琴広, 板垣浩司
    • Journal Title

      触媒学会(編)

      Pages: 40-52

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 遷移金属触媒重合による環状オレフィン系ポリマーの精密合成2007

    • Author(s)
      野村琴広
    • Journal Title

      光学用透明樹脂における材料設計と応用技術, 技術情報協会(編)

      Pages: 104-116

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of half-titanocenes containing phenoxy-imine ligands and their use as catalysts for olefin polymerization2007

    • Author(s)
      H. Zhang, S. Katao, K. Nomura, J. Huang
    • Journal Title

      Organometallics 26

      Pages: 5967-5977

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] uning the active species from syndiospecific styrene polymerisation to ethylene/styrene copolymerisation by (aryloxo)(cyclopentadienyl)titanium complexes-MAO catalysts2007

    • Author(s)
      H. Zhang, D.-J. Byun, K. Nomura
    • Journal Title

      Dalton Trans.

      Pages: 1802-1806

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of ketimide ligand for ethylene polymerization and ethylene/norbornene copolymerization catalyzed by (cyclopentadienyl)(ketimide)titanium complexes - MAO catalyst systems. Structural analysis for Cp*TiCl_2(N=CPh_2)2007

    • Author(s)
      K. Nomura, J. Yamada, W. Wang, J. Liu
    • Journal Title

      J.Organomet. Chem. 692

      Pages: 4675-4682

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Facile , efficient functionalization of polyolefins via controlled incorporation of terminal olefins by repeated 1, 7-octadiene insertion2007

    • Author(s)
      K. Nomura, J. Liu, M. Fujiki, A. Takemoto
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 14170-14171

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and structure of titanatranes containing tetradentate trianionic donor ligands of the type, [(O_2, 4-R_2C_6H_2-6-CH_2)_2(OCH_2CH_2)]N^<3->, and their use in catalysis for ethylene polymerization2007

    • Author(s)
      S. Padmanabhan, S. Katao, K. Nomura
    • Journal Title

      OrganometallicsOrganometallics 26

      Pages: 1616-1626

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of titanatranes containing bis(aryloxo)(alkoxo)amines and their use in catalysis for ethylene polymerization2007

    • Author(s)
      S. Padmanabhan, W. Wang, S. Katao, K. Nomura
    • Journal Title

      Macromol. Symp. 260

      Pages: 133-139

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly efficient ethylene/cyclopentene copolymerization with exclusive 1, 2-cyclopentene incorporation by (cyclopentadienyl)(ketimide)titanium(IV) complexes - MAO catalysts2007

    • Author(s)
      J. Liu, K. Nomura
    • Journal Title

      Adv. Synth. Catal. 349

      Pages: 2235-2240

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nonbridged half-metallocenes containing anionic ancillary donor ligands : New promising candidates as catalysts for precise olefin polymerization2007

    • Author(s)
      K. Nomura, J. Liu, S. Padmanabhan, B. Kitiyanan
    • Journal Title

      J. Mol.Catal. A. 267

      Pages: 1-29

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of cyclopentadienyl and anionic donor ligands on monomer reactivities in copolymerization of ethylene with 2-methyl-1-pentene by nonbridged half-titanocenes-cocatalyst systems2007

    • Author(s)
      K. Itagaki, M. Fujiki, K. Nomura
    • Journal Title

      Macromolecules 40

      Pages: 6489-6499

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of ketimide ligand for ethylene polymerization and ethylene/norbornene copolymerization catalyzed by(cyclopentadienyl)(ketimide)titanium complexes-MAO catalyst systems. Structural analysis for Cp^*TiCl_2(N=CPh_2)2007

    • Author(s)
      Kotohiro Nomura, 他
    • Journal Title

      Journal of Organometallic Chemistry 692

      Pages: 4675-4682

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of titanatranes containing bis(aryloxo)(alkoxo)amines and their use in catalysis for ethylene polymerization2007

    • Author(s)
      Kotohiro Nomura, 他
    • Journal Title

      Macromolecular Symposia 260

      Pages: 133-139

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of half-titanocenes containing phenoxy-imine ligand and their use in catalysts for olefin polymerization2007

    • Author(s)
      Kotohiro Nomura, 他
    • Journal Title

      Organometallics 26

      Pages: 5967-5977

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile efficient functionalization of polyolefins via controlled incorporation of terminal olefins by repeated 1, 7-octadiene insertion2007

    • Author(s)
      Kotohiro Nomura, 他
    • Journal Title

      Journal of American Chemical Society 129

      Pages: 14170-14171

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, structure of titanatranes containing tetradentate trianionic donor ligands of the type, [(O-2,4-R_2C_6H_2-6-CH_2)_2(OCH_2CH_2)]N^<3->, and their use in catalysis for ethylene polymerization2007

    • Author(s)
      Kotorhio Nomura 他
    • Journal Title

      Organometallics 26

      Pages: 1616-1626

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Tuning the active species from syndiospecific styrene polymerisation to ethylene/styrene copolymerisation by (aryloxo)(cyclopentadienyl)titanium complexes - MAO catalysts2007

    • Author(s)
      Kotorhio Nomura 他
    • Journal Title

      Dalton Transactions (Inside Cover Articleに採択) (in press)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Living copolymerization of ethylene with styrene catalyzed by (cyclopentadienyl)(ketimide)- titanium(IV) complex - MAO catalyst system : Effect of anionic ancillary donor ligand2006

    • Author(s)
      H. Zang, K. Nomura
    • Journal Title

      Macromolecules 39

      Pages: 5266-5274

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Living copolymerization of ethylene with styrene catalyzed by (cyclopentadienyl)(ketimide)titanium(IV) complex - MAO catalyst system : Effect of anionic ancillary donor ligand2006

    • Author(s)
      Kotorhio Nomura 他
    • Journal Title

      Macromolecules 39

      Pages: 5266-5274

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 環状オレフィン系樹脂の精密重合

    • Author(s)
      野村琴広
    • Journal Title

      Material Stage 8

      Pages: 1-5

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Presentation] フェノキシ配位子を有する第4族ハーフメタロセン錯体の合成とオレフィン重合2008

    • Author(s)
      野村琴広, 他
    • Organizer
      石油学会関西支部第17回研究発表会
    • Place of Presentation
      京都大学
    • Year and Date
      2008-12-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] 非架橋ハーフチタノセン錯体触媒を用いるエチレン系共重合体の精密合成2008

    • Author(s)
      野村琴広, 他
    • Organizer
      第38回石油・石油化学討論会
    • Place of Presentation
      国立オリンピック記念青少年総合センター
    • Year and Date
      2008-11-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] Efficient, precise synthesis of new polyolefins catalyzed by nonbridgedhalf-titanocenes2008

    • Author(s)
      Kotorhio Nomura
    • Organizer
      5th International Symposium on High-Tech Polymer Materials (HTPM-V)
    • Place of Presentation
      Beijing, China
    • Year and Date
      2008-10-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Efficient, precise synthesis of new polyolefins catalyzed by nonbridgedhalf-titanocenes2008

    • Author(s)
      Kotorhio Nomura
    • Organizer
      102nd Korean Chemical Society National Meeting
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2008-10-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] 新しいオレフィン系ポリマーの創製を目指したポストメタロセン触媒の創製一高機能化ポリオレフィンのための触媒設計2008

    • Author(s)
      野村琴広
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2008-09-26
    • Related Report
      2008 Annual Research Report
  • [Presentation] 高活性を発現する高性能チタン錯体触媒の配位子設計と新規ポリマーの創製2008

    • Author(s)
      野村琴広
    • Organizer
      第3回次世代型ポリオレフィン総合研究会
    • Place of Presentation
      キャンパスイノベーションセンター, 東京
    • Year and Date
      2008-07-31
    • Related Report
      2008 Annual Research Report
  • [Presentation] Precise, efficient copolymerization of ethylene with sterically encumbereda-olefins catalyzed by nonbridged half-titanocenes-cocatalyst systems2008

    • Author(s)
      Kotorhio Nomura, 他
    • Organizer
      Pre-Symposium of 14th International Congress on Catalysis (ICC 14)
    • Place of Presentation
      京都時計台記念会館
    • Year and Date
      2008-07-09
    • Related Report
      2008 Annual Research Report
  • [Presentation] Efficient introduction of reactive functionalities into polyolefins by ethylene copolymerizations using nonbridged half-titanocenes2008

    • Author(s)
      Kotorhio Nomura
    • Organizer
      International Workshop on Olefin Polymerization Kinetics
    • Place of Presentation
      キャンパスイノベーションセンター, 東京
    • Year and Date
      2008-04-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] Design of efficient molecular catalysts for precise olefin polymerization2008

    • Author(s)
      K. Nomura
    • Organizer
      5th International Symposium on High-Tech Polymer Materials
    • Place of Presentation
      Beijing, China
    • Related Report
      2008 Final Research Report
  • [Presentation] Efficient, precise synthesis of new polyolefins catalyzed by nonbridged half-titanocenes2008

    • Author(s)
      K. Nomura
    • Organizer
      102nd Korean Chemical Society National Meeting
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] 新しいオレフィン系ポリマーの創製を目指したポストメタロセン触媒の創製-高機能化ポリオレフィンのための触媒設計2008

    • Author(s)
      野村琴広
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋大学
    • Related Report
      2008 Final Research Report
  • [Presentation] 新規ポリオレフィンの創製を可能とする多機能分子触媒-配位子による協奏機能の精密制御2008

    • Author(s)
      野村琴広
    • Organizer
      特定領域研究「協奏機能触媒」ミニシンポジウム 協奏機能触媒と高分子化学
    • Place of Presentation
      東京工業大学
    • Related Report
      2008 Final Research Report
  • [Presentation] 高活性を発現する高性能チタン錯体触媒の配位子設計と新規ポリマーの創製2008

    • Author(s)
      野村琴広
    • Organizer
      第3回次世代型ポリオレフィン総合研究会
    • Place of Presentation
      東京
    • Related Report
      2008 Final Research Report
  • [Presentation] Efficient introduction of reactive functionalities into polyolefins by ethylene copolymerizations using nonbridged half-titanocenes2008

    • Author(s)
      K. Nomura
    • Organizer
      International Workshop on Olefin Polymerization Kinetics
    • Place of Presentation
      東京
    • Related Report
      2008 Final Research Report
  • [Presentation] Precise, efficient copolymerization of ethylene with a-olefins containing bulkysubstituents catalyzed by nonbridged half-titanocenes-cocatalyst systems2008

    • Author(s)
      Kotorhio Nomura, 他
    • Organizer
      14th International Congress on Catalysis (ICC 14)
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2008 Annual Research Report
  • [Presentation] Design of nonbridged half-titanocenes for precise synthesis of new polyolefins2007

    • Author(s)
      Kotohiro Nomura, 他
    • Organizer
      Asian Polyolefin Workshop 2007(APO2007)
    • Place of Presentation
      Zhejiang University, China
    • Year and Date
      2007-11-02
    • Related Report
      2007 Annual Research Report
  • [Presentation] キレート多座配位チタン錯体の合成とオレフィン重合触媒への適用2007

    • Author(s)
      Kotohiro Nomura, 他
    • Organizer
      第37回石油・石油化学討論会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2007-10-25
    • Related Report
      2007 Annual Research Report
  • [Presentation] ハーフメタロセン型チタン錯体触媒によるスチレンの立体特異性重合とエチレンとの共重合における触媒活性種2007

    • Author(s)
      Kotohiro Nomura, 他
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2007-09-18
    • Related Report
      2007 Annual Research Report
  • [Presentation] 新規ポリマーの創製を指向した高性能ハーフチタノセン錯体触媒の設計・創製2007

    • Author(s)
      Kotohiro Nomura, 他
    • Organizer
      第二回次世代ポリオレフィン総合研究会
    • Place of Presentation
      東京大学
    • Year and Date
      2007-08-09
    • Related Report
      2007 Annual Research Report
  • [Presentation] Ethylene polymerization catalyzed by thermally robust titanatranes containing tetradentate trianionic donor ligands of the type,[(O-2, 4-R_2C_6H_2-6-CH_2)_2(OCH_2CH_2)]N^<3->2007

    • Author(s)
      Kotohiro Nomura, 他
    • Organizer
      14th Internationl Symposium on Organometallic Chemistry directed towards Organic Chemistry(OMCOS 14)
    • Place of Presentation
      奈良市100年会館
    • Year and Date
      2007-08-05
    • Related Report
      2007 Annual Research Report
  • [Presentation] Design of nonbridged half-titanocenes for precise synthesis of new polyolefins2007

    • Author(s)
      K. Nomura, J. Liu, and A. Takemoto
    • Organizer
      Asian Polyolefin Workshop 2007
    • Place of Presentation
      Hangzhou, China
    • Related Report
      2008 Final Research Report
  • [Presentation] 新規ポリマーの創製を指向した高性能ハーフチタノセン錯体触媒の設計・創製2007

    • Author(s)
      野村琴広
    • Organizer
      第2回次世代ポリオレフィン総合研究会
    • Place of Presentation
      東京大学
    • Related Report
      2008 Final Research Report
  • [Presentation] オレフィンの精密重合を可能とする高性能遷移金属錯体触媒 : 配位重合やメタセシス重合による新しいオレフィン系高分子機能材料の創製2007

    • Author(s)
      野村琴広
    • Organizer
      石油学会石油化学分科会
    • Place of Presentation
      石油学会
    • Related Report
      2008 Final Research Report
  • [Presentation] Design, synthesis of efficient early transition metal catalysts for precise olefin polymerization2006

    • Author(s)
      K. Nomura
    • Organizer
      Xiangshan Science Conferences ofChina 香山科学会議
    • Place of Presentation
      Beijing, China
    • Related Report
      2008 Final Research Report
  • [Presentation] 高機能ポリオレフィンの環境調和型の精密合成新プロセスの提案2006

    • Author(s)
      野村琴広, 長谷川喜一
    • Organizer
      環境資源工学会第116回例会
    • Place of Presentation
      京都
    • Related Report
      2008 Final Research Report
  • [Presentation] Precise olefin copolymerization catalyzed by nonbridged half-titanocenes2006

    • Author(s)
      K. Nomura
    • Organizer
      国際高分子化学学求討論会
    • Place of Presentation
      Dalian, China
    • Related Report
      2008 Final Research Report
  • [Book] 次世代ポリオレフィン総合研究2008

    • Author(s)
      野村琴広
    • Publisher
      次世代ポリオレフィン総合研究会(編)
    • Related Report
      2008 Final Research Report
  • [Book] (社)日本ゴム協会誌2008

    • Author(s)
      野村琴広
    • Related Report
      2008 Final Research Report
  • [Book] 光学樹脂 : 遷移金属触媒重合による環状オレフィン系ポリマーの精密合成2007

    • Author(s)
      野村琴広(著者分担)
    • Publisher
      技術情報協会(in press)
    • Related Report
      2006 Annual Research Report
  • [Book] 触媒技術の動向と展望 : 高機能ポリオレフィンの創製を指向した高性能分子触媒-新しいエチレン系ポリマーの創製を可能とした研究例-2007

    • Author(s)
      野村琴広, 板垣浩司(著者分担)
    • Publisher
      触媒学会(in press)
    • Related Report
      2006 Annual Research Report
  • [Book] 月間マテリアル(技術情報協会)

    • Author(s)
      野村琴広
    • Publisher
      遷移金属触媒重合による環状オレフィン系ポリマーの精密合成(in press)
    • Related Report
      2007 Annual Research Report
  • [Remarks] 平成20年8月23日に、「ひらめき☆ときめきサイエンス~ようこそ大学の研究室へ」を開催し、科学研究費の課題の目的と成果の概要を紹介した.

    • URL

      http://www.aist-nara.ac.jp/~nomurak/nomura/kotohironomuratoppage.htm

    • Related Report
      2008 Final Research Report

URL: 

Published: 2006-04-01   Modified: 2016-04-21  

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