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Exploration of functions of porphyrin complex-decorated carbon nanotubes and their application to biological gas sensing

Research Project

Project/Area Number 18H01829
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 28030:Nanomaterials-related
Research InstitutionOsaka University

Principal Investigator

Katayama Mitsuhiro  大阪大学, 工学研究科, 教授 (70185817)

Co-Investigator(Kenkyū-buntansha) 田畑 博史  大阪大学, 工学研究科, 助教 (00462705)
小松 直樹  京都大学, 人間・環境学研究科, 教授 (30253008)
久保 理  大阪大学, 工学研究科, 准教授 (70370301)
森川 良忠  大阪大学, 工学研究科, 教授 (80358184)
Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2021: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2020: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2019: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2018: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Keywords半導体単層カーボンナノチューブ / 生体ガスセンサー / ガスバイオロジー / ポルフィリン錯体 / 銅環状化合物 / ナノコンポジット / 金属含有環状化合物 / ダイマー金属ポルフィリン錯体 / 金属ポルフィリン錯体 / モノマー金属ポルフィリン錯体
Outline of Final Research Achievements

Metal porphyrin complex decorated carbon nanotubes are promissing sensing materials for the detection of trace amounts of biological gases in exhaled breath, becasuse they can be made highly selective to specific gases by selecting the central metal ions. In this study, we developed sensing materials for highly sensitive and selective detection of NH3. First, SWNTs decorated with Co dimer porphyrin complex acheved a response more than four times larger than those with conventional Co monomar porphyrin. Second, SWNTs surrounded with a Cu nanorectangle, a porlphyin-like molecule, showed a high selectivity for NH3 amoung various biological gases.

Academic Significance and Societal Importance of the Research Achievements

本研究で検知対象に選んだNH3は疾患マーカーの一種であり、腎機能障害患者では呼気中のNH3濃度が増加することが知られています。本研究で作製したCoダイマーポルフィリン錯体担持SWNTセンサーおよびCu環状化合物修飾SWNTセンサーを用いれば、この呼気中のNH3成分を夾雑成分の影響を受けずに高感度に検知することができるようになると期待され、呼気診断用ガスセンサーの小型化につながるものと考えています。

Report

(5 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (46 results)

All 2022 2021 2020 2019 2018

All Journal Article (20 results) (of which Int'l Joint Research: 16 results,  Peer Reviewed: 20 results,  Open Access: 6 results) Presentation (26 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Probing the role of charged functional groups on nanoparticles grafted with polyglycerol in protein adsorption and cellular uptake2022

    • Author(s)
      Yajuan Zou,Shinji Ito,Masazumi Fujiwara,Naoki Komatsu
    • Journal Title

      Advanced Functional Materials

      Volume: na Issue: 22 Pages: 2111077-2111077

    • DOI

      10.1002/adfm.202111077

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Kagome-like structure of germanene on Al(111)2021

    • Author(s)
      Kubo Osamu、Kinoshita Seijiro、Sato Hitoshi、Miyamoto Koji、Sugahara Ryuji、Endo Satoshi、Tabata Hiroshi、Okuda Taichi、Katayama Mitsuhiro
    • Journal Title

      Physical Review B

      Volume: 104 Issue: 8 Pages: 0854041-6

    • DOI

      10.1103/physrevb.104.085404

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conjugation of Phenylboronic Acid Moiety through Multistep Organic Transformations on Nanodiamond Surface for an Anticancer Nanodrug for Boron Neutron Capture Therapy2021

    • Author(s)
      Nishikawa Masahiro、Kang Heon Gyu、Zou Yajuan、Takeuchi Hidekazu、Matsuno Naoyoshi、Suzuki Minoru、Komatsu Naoki
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 94 Issue: 9 Pages: 2302-2312

    • DOI

      10.1246/bcsj.20210200

    • NAID

      130008103567

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Adsorption of toxic gases on borophene: surface deformation links to chemisorptions2021

    • Author(s)
      Ta Luong Thi、Hamada Ikutaro、Morikawa Yoshitada、Dinh Van An
    • Journal Title

      RSC Advances

      Volume: 11 Issue: 30 Pages: 18279-18287

    • DOI

      10.1039/d1ra02738g

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Chemical stability of hydrogen boride nanosheets in water2021

    • Author(s)
      Kurt Irvin Rojas, Nguyen Thanh Cuong, Hiroaki Nishino, Ryota Ishibiki, Shin-ichi Ito, Masahiro Miyauchi, Yoshitaka Fujimoto, Satoshi Tominaka, Susumu Okada, Hideo Hosono, Nelson Jr., Arboleda, Takahiro Kondo, Yoshitada Morikawa, Ikutaro Hamada
    • Journal Title

      Communications Materials 2 (2021) 81. (8 pages)

      Volume: 2 Issue: 1 Pages: 1-8

    • DOI

      10.1038/s43246-021-00184-5

    • NAID

      120007185343

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Visible-Light-Activated Response Originating from Carrier-Mobility Modulation of NO2 Gas Sensors Based on MoS2 Monolayers2021

    • Author(s)
      Hiroshi Tabata, Hiroaki Matsuyama, Taishi Goto, Osamu Kubo, Mitsuhiro Katayama
    • Journal Title

      ACS Nano

      Volume: 15 Issue: 2 Pages: 2542-2553

    • DOI

      10.1021/acsnano.0c06996

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidative etching mechanism of diamond (100) surface2021

    • Author(s)
      J. I. Enriquez, F. Muttaqien, M. Michiuchi, K. Inagaki, M. Geshi, I. Hamada, Y. Morikawa
    • Journal Title

      Carbon

      Volume: 174 Pages: 36-51

    • DOI

      10.1016/j.carbon.2020.11.057

    • NAID

      120006952200

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Polyglycerol Grafting Shields Nanoparticles from Protein Corona Formation to Avoid Macrophage Uptake2020

    • Author(s)
      Zou Yajuan、Ito Shinji、Yoshino Fumi、Suzuki Yuta、Zhao Li、Komatsu Naoki
    • Journal Title

      ACS Nano

      Volume: 14 Issue: 6 Pages: 7216-7226

    • DOI

      10.1021/acsnano.0c02289

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Quantitative investigation of the interaction between proteins and charged functional groups on the polyglycerol-grafted nanodiamond surface2020

    • Author(s)
      Yajuan Zou,Naoki Komatsu*
    • Journal Title

      Carbon

      Volume: 164 Pages: 395-401

    • DOI

      10.1016/j.carbon.2020.02.089

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Geometric and electronic structure correlation at a metal-organic interface2020

    • Author(s)
      H. Koshida, Y. Takahashi, H. Okuyama, S. Hatta, T. Aruga, Y. Hamamoto, I. Hamada, Y. Morikawa
    • Journal Title

      J. Phys. Chem. C.

      Volume: 124 Issue: 32 Pages: 17696-17701

    • DOI

      10.1021/acs.jpcc.0c04678

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Insight into Trimeric Formation of Nitric Oxide on Cu(111): A Density Functional Theory Study2020

    • Author(s)
      Pham Thanh Ngoc、Hamamoto Yuji、Inagaki Kouji、Son Do Ngoc、Hamada Ikutaro、Morikawa Yoshitada
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 124 Issue: 5 Pages: 2968-2977

    • DOI

      10.1021/acs.jpcc.9b08569

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Chemical functionalization of nanodiamonds: opportunities and challenges ahead2019

    • Author(s)
      G. Reina, L. Zhao, A. Bianco,* N. Komatsu
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 58 Pages: 17918-17929

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Preferential Tumor Accumulation of Polyglycerol Functionalized Nanodiamond Conjugated with Cyanine Dye Leading to Near‐Infrared Fluorescence In Vivo Tumor Imaging2019

    • Author(s)
      Yoshino Fumi、Amano Tsukuru、Zou Yajuan、Xu Jian、Kimura Fuminori、Furusho Yoshio、Chano Tokuhiro、Murakami Takashi、Zhao Li、Komatsu Naoki
    • Journal Title

      Small

      Volume: 15 Issue: 48 Pages: 1901930-1901930

    • DOI

      10.1002/smll.201901930

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Vibration-driven reaction of CO2 on Cu surfaces via Eley?Rideal-type mechanism2019

    • Author(s)
      Quan Jiamei、Muttaqien Fahdzi、Kondo Takahiro、Kozarashi Taijun、Mogi Tomoyasu、Imabayashi Takumi、Hamamoto Yuji、Inagaki Kouji、Hamada Ikutaro、Morikawa Yoshitada、Nakamura Junji
    • Journal Title

      Nature Chemistry

      Volume: 11 Issue: 8 Pages: 722-729

    • DOI

      10.1038/s41557-019-0282-1

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structural Analysis of Self-Assembled Platinum-Silicide Nanostructures on Si(001) Using Ion Scattering Spectroscopy2018

    • Author(s)
      Hiroyuki Kagitani, Seijiro Kinoshita, Osamu Kubo, Kazuki Takahashi, Hiroshi Tabata, Mitsuhiro Katayama
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 16 Issue: 0 Pages: 66-71

    • DOI

      10.1380/ejssnt.2018.66

    • NAID

      130006655057

    • ISSN
      1348-0391
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Bias- and Gate-Tunable Gas Sensor Response Originating from Modulation in the Schottky Barrier Height of a Graphene/MoS2 van der Waals Heterojunction2018

    • Author(s)
      Hiroshi Tabata, Yuta Sato, Kouhei Oi, Osamu Kubo, Mitsuhiro Katayama
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 44 Pages: 38387-38393

    • DOI

      10.1021/acsami.8b14667

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Flexible Nanotweezers with Various Metals and their Application in Carbon Nanotube Extraction2018

    • Author(s)
      Yuya Miyake, Alejandro Lopez-Moreno, Jian Yang, Hai-Jun Xu, Nicolas Desbois, Claude P. Gros, Naoki Komatsu
    • Journal Title

      New Journal of Chemistry

      Volume: 42 Issue: 10 Pages: 7592-7594

    • DOI

      10.1039/c8nj00147b

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dendritic cell-mediated delivery of doxorubicin-polyglycerol-nanodiamond composites elicits enhanced anti-cancer immune response in glioblastoma2018

    • Author(s)
      T.-F. Li, K. Li, Q. Zhang, C. Wang, Y. Yue, Z. Chen, S.-J. Yuan, X. Liu, Y. Wen, M. Han, N. Komatsu, Y.-H. Xu, L. Zhao,* X. Chen*
    • Journal Title

      Biomaterials

      Volume: 181 Pages: 35-52

    • DOI

      10.1016/j.biomaterials.2018.07.035

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Hydrogen Bond-Induced Nitric Oxide Dissociation on Cu(110)2018

    • Author(s)
      Pham Thanh Ngoc、Sugiyama Masahiro、Muttaqien Fahdzi、Putra Septia Eka Marsha、Inagaki Kouji、Son Do Ngoc、Hamamoto Yuji、Hamada Ikutaro、Morikawa Yoshitada
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 22 Pages: 11814-11824

    • DOI

      10.1021/acs.jpcc.8b01208

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Enhancement of CO2 adsorption on oxygen-functionalized epitaxial graphene surface under near-ambient conditions2018

    • Author(s)
      Yamamoto Susumu、Takeuchi Kaori、Hamamoto Yuji、Liu Ro-Ya、Shiozawa Yuichiro、Koitaya Takanori、Someya Takashi、Tashima Keiichiro、Fukidome Hirokazu、Mukai Kozo、Yoshimoto Shinya、Suemitsu Maki、Morikawa Yoshitada、Yoshinobu Jun、Matsuda Iwao
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 29 Pages: 19532-19538

    • DOI

      10.1039/c8cp03251c

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Ag(111)上ヒ素単層膜の構造および物性の評価2022

    • Author(s)
      梯 雄一郎,  久保 理, 田畑 博史, 片山 光浩
    • Organizer
      第69回応用物理学会春季学術講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ゲルマナン薄膜トランジスタの電極界面における伝導メカニズム2021

    • Author(s)
      鈴木 雄大, 松浦 直毅, 古沢 侑也, 久保 理, 田畑 博史, 片山 光浩
    • Organizer
      第82回応用物理学会秋季学術講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] イオン交換樹脂を用いたゲルマナン作製と評価2021

    • Author(s)
      松浦 直毅、鈴木 雄大、久保 理、田畑 博史、片山 光浩
    • Organizer
      第82回応用物理学会秋季学術講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Structural analysis of VO2 thin films prepared on r-plane sapphire substrates by mist CVD2021

    • Author(s)
      H. Maeda, E. Nakayama, O. Kubo, Y. Matamura, M. Kimura, T. Ikenoue, H. Tabata and M. Katayama
    • Organizer
      The 9 International Symposium on Surface Science (ISSS-9)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoactivated Gas Response of Gas Sensor Based on MoS2 Monolayers to Various Biogas Species2021

    • Author(s)
      Taishi Goto, Ryota Inao, Hiroshi Tabata, Osamu Kubo, Mitsuhiro Katayama
    • Organizer
      International Conference on the Science and Application of Nanotubes and Low-Dimensional Materials (NT21)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoenhanced Response of Gas Sensor Based on MoS2 Monolayers to Various Biogas Species”2021

    • Author(s)
      T. Goto, R. Inao, H. Tabata, O. Kubo, and M. Katayama
    • Organizer
      第61回フラーレン・ナノチューブ・グラフェン総合シンポジウム(FNTG61)
    • Related Report
      2021 Annual Research Report
  • [Presentation] 架橋構造によるMoS2光活性化ガスセンサの電流特性の改善2021

    • Author(s)
      稲生亮太、後藤大志、久保理、田畑博史、片山光浩
    • Organizer
      応用物理学会関西支部 2021年度第2回講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] r面サファイア基板上にミストCVD法で作製したVO2薄膜の表面構造解析に関する研究2021

    • Author(s)
      前田 青輝、中山 瑛太、田畑 博史、久保 理、片山 光浩、木村 信、股村 雄 也、池之上 卓己
    • Organizer
      第61回 応用物理学会春季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 光活性化されたMoS2ガスセンサのNO2に対する移動度変調応答2020

    • Author(s)
      田畑 博史、松山 弘明、後藤 大志、雛本 樹生、杉本 泰、久保 理、藤井 稔、 片山 光浩
    • Organizer
      第81回 応用物理学会秋季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 単層MoS2ガスセンサの可視光照射下での応答活性化2020

    • Author(s)
      後藤 大志、松山 弘明、田畑 博史、久保 理、片山 光浩
    • Organizer
      第81回 応用物理学会秋季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Coダイマーポルフィリン錯体担持半導体単層カーボンナノチューブによるNH3分子の高感度検知2019

    • Author(s)
      藤本 一輝、栗本 悠司、田畑 博史、久保 理、Claude Gros、小松 直樹、片山 光浩
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] グラフェン/Siヘテロ構造光起電力型ガスセンサのガス応答特性の改善2019

    • Author(s)
      杉山 裕一、田畑 博史、久保 理、片山 光浩
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 単層MoS2ガスセンサの可視光照射下での応答活性化2019

    • Author(s)
      松山 弘明、田畑 博史、久保 理、片山 光浩
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] FET特性に向けた大面積ゲルマナン薄膜の堆積法の検討2019

    • Author(s)
      古沢 侑也、山本 陸、久保 理、田畑 博史、片山 光浩
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 単層 MoS2の光活性化ガス応答の評価2019

    • Author(s)
      田畑 博史、松山 弘明、久保 理、片山 光浩
    • Organizer
      2019 年日本表面真空学会学術講演
    • Related Report
      2019 Annual Research Report
  • [Presentation] Ion Scattering Spectroscopy of α-Ga2O3 Grown on r-plane Sapphire by Mist Chemical Vapor Deposition2019

    • Author(s)
      Osamu Kubo, Daiki Tamba, Shun Osaka, Masaya Oda, Hiroshi Tabata and Mitsuhiro Katayama
    • Organizer
      32th International Microprocesses and Nanotechnology Conference (MNC 2019)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Al(111)3×3超周期ゲルマネンの角度分解光電子分光計測2019

    • Author(s)
      久保 理、木下 盛治朗、佐藤 仁、宮本 幸治、遠藤 聡、菅原 隆志、田畑 博史、奥田太一、片山 光浩
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] MoS2/Siヘテロ接合の光起電力ガス応答のメカニズム2019

    • Author(s)
      鵜篭 直也、田畑 博史、松山 弘明、久保 理、片山 光浩
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Al(111)√7×√7周期ゲルマネンの電子バンド構造2018

    • Author(s)
      久保 理、遠藤 聡、佐藤 仁、宮本 幸治、木下 盛治郎、菅原 隆志、田畑 博史、奥田太一、片山 光浩
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ボロフェンの低温電子物性測定2018

    • Author(s)
      新宮 勇,細川 晋平,遠藤 聡,田畑 博史,久保 理,片山 光浩
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 酸化グラフェン-カーボンナノチューブ複合薄膜を用いた揮発性有機化合物センシング2018

    • Author(s)
      田畑 博史、杉浦 知樹、久保 理、片山 光浩
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Structural Analysis of Germanene on Al(111) by Ion Scattering Spectroscopy2018

    • Author(s)
      Seijiro Kinoshita, Osamu Kubo, Hiroyuki Kagitani, Ryuji Sugahara, Hiroshi Tabata, Mitsuhiro Katayama
    • Organizer
      31st International Microprocesses and Nanotechnology Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] グラフェン/Siヘテロ接合の光起電力ガス応答のメカニズム2018

    • Author(s)
      杉山 裕一、田畑 博史、鵜篭 直也、麻下 卓嗣、久保 理、片山 光浩
    • Organizer
      2018年日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 低速イオン散乱分光法によるAl(111)ゲルマネンの構造解析2018

    • Author(s)
      菅原 隆志、木下 盛治朗、久保 理、鍵谷 浩行、田畑 博史、片山 光浩
    • Organizer
      2018年日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 走査トンネル顕微鏡によるボロフェンの低温電子物性測定2018

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Published: 2018-04-23   Modified: 2023-01-30  

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