| Budget Amount *help |
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2020: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2019: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2018: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
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| Outline of Final Research Achievements |
We have developed a plastic crystal with the aim of developing a new molecular multiferroics. First, a stable complex of a supramolecular cation rotor constructed from m-fluoroanilinium and [18] crown-6-ether which is a condensation of two cyclohexane rings, and a ferromagnetic manganese-chromium oxalate crosslinked complex. We have established a method for synthesizing plastic crystals and succeeded in producing a single crystal that enables the expression of complex functions. In addition, by changing the type of halogen introduced into the anilinium derivative constituting the supramolecular cation, we succeeded in controlling the molecular motion in the crystal and the physical characteristics expressed. From the above results, we were able to obtain results for developing future development of molecular multiferroics.
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