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Molecula recognition of a layered silicate, magadiite, having intralayer flexible micropores

Research Project

Project/Area Number 18H02064
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 36010:Inorganic compounds and inorganic materials chemistry-related
Research InstitutionNational Institute for Materials Science

Principal Investigator

IDE Yusuke  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主幹研究員 (40449327)

Co-Investigator(Kenkyū-buntansha) 冨中 悟史  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主任研究員 (90468869)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2020: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2019: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2018: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Keywords層状ケイ酸塩 / ゼオライト / 吸着分離 / 光触媒 / マガディアイト / ミクロ多孔体 / ナノシート / 剥離 / 分子認識 / 化成品合成
Outline of Final Research Achievements

Development of microporous materials, like zeolites and metal-organic frameworks (MOFs), with unique and better properties, is crucially important, while yet challenging, for many energy, environment, and healthcare applications. In this study, we report some applications of magadiite (a kind magadiite with a structure diversity) which are chemically and thermally stable like zeolites while flexible like MOFs.

Academic Significance and Societal Importance of the Research Achievements

ゼオライトや層状粘土鉱物は、水道水を軟水化(Caイオンの分離除去)し洗剤の泡立ちを良くしたり、お茶からカフェイン成分のみを除去したりといった目的で吸着材として実用化されているが、それはその安定性とミクロ細孔構造に由来する。こういった細孔をもつ多孔体の開発は世界中で盛んに研究されているものの、安定で、優れた性能を示し、生体親和性に優れ、さらには低コストな材料の開発は困難である。本研究で得られた知見は、天然にも産出する粘土系多孔体が、例えば、世界中で使用が禁止されつつある酸化チタンに代わる紫外線吸収材へ応用できることを示したなど、産業界への波及効果が大きい。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (16 results)

All 2021 2020 2019 2018

All Journal Article (4 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (11 results) (of which Int'l Joint Research: 9 results,  Invited: 11 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] In Situ Blue Titania via Band Shape Engineering for Exceptional Solar H2 Production in Rutile TiO22021

    • Author(s)
      Esmail Doustkhah, M. Hussein N.Assadi, Kenji Komaguchi, NaoTsunoji, Mohamed Esmat, Naoki Fukata, Osamu Tomita, Ryu Abe, Bunsho Ohtani, Yusuke Ide
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: - Pages: 120380-120380

    • DOI

      10.1016/j.apcatb.2021.120380

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Microporous layered silicates: old but new microporous materials2020

    • Author(s)
      Doustkhah Esmail、Ide Yusuke
    • Journal Title

      New Journal of Chemistry

      Volume: 44 Issue: 24 Pages: 9957-9968

    • DOI

      10.1039/c9nj06222j

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bursting Exfoliation of a Microporous Layered Silicate to Three-Dimensionally Meso-Microporous Nanosheets for Improved Molecular Recognition2019

    • Author(s)
      Doustkhah Esmail、Ide Yusuke
    • Journal Title

      ACS Applied Nano Materials

      Volume: 2 Issue: 12 Pages: 7513-7520

    • DOI

      10.1021/acsanm.9b01508

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Zeolitic intralayer microchannels of magadiite, a natural layered silicate, to boost green organic synthesis2018

    • Author(s)
      Ide Yusuke、Tominaka Satoshi、Kono Hiroyuki、Ram Rahul、Machida Akihiko、Tsunoji Nao
    • Journal Title

      Chemical Science

      Volume: 9 Issue: 46 Pages: 8637-8643

    • DOI

      10.1039/c8sc03712d

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Frontiers in Porous Materials Design of Layered Inorganic Solids2019

    • Author(s)
      井出裕介
    • Organizer
      MANA-i-MATE Joint Symposium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Smart Utilization of Nanoporous Silicas for Photocatalytic Reactions2019

    • Author(s)
      井出裕介
    • Organizer
      019 International Conference on Nanospace Nanomaterials
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontiers in Porous Materials Design of Layered Inorganic Solids2019

    • Author(s)
      井出裕介
    • Organizer
      8th Asian Conference on Colloid and Interface Science (ACCIS 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Smart Uses of Nanoporous Silicas for Photocatalytic Synthetic Reactions2019

    • Author(s)
      井出裕介
    • Organizer
      5th International Symposium of Advanced Inorganic Materials
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Recent Developments in Material Design of Layered Alkali Silicates2018

    • Author(s)
      井出裕介
    • Organizer
      XII Meeting of the International Mineralogical Association
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 層状アルカリケイ酸塩,チタン酸塩ならではの材料設計2018

    • Author(s)
      井出裕介
    • Organizer
      第62回粘土科学討論会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Frontier of TiO2 Functionalization-From Materials Design to Operating Environment Control2018

    • Author(s)
      井出裕介
    • Organizer
      International Congress on Pure and Applied Chemistry Langkawi 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontier of Materials Design of Layered Silicates2018

    • Author(s)
      井出裕介
    • Organizer
      The 9th International Workshop on Advanced Materials Science and Nanotechnology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontiers in Material Design of Layered Alkali Silicates2018

    • Author(s)
      井出裕介
    • Organizer
      France-Japan Workshop 2018 on Functional Nanomaterials and Soft Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Zeolitic Intralayer Microchannels of Magadiite, a Natural Layered Silicate, to Boost Organic Synthetic Reactions2018

    • Author(s)
      井出裕介
    • Organizer
      Thai-Kyutech Mini Workshop on Nanomaterials 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 天然層状ケイ酸塩マガディアイトの層内細孔2018

    • Author(s)
      井出裕介
    • Organizer
      第5回島根大学-信州大学学合同セミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Patent(Industrial Property Rights)] 紫外線遮蔽材、その製造方法、それを用いた化粧料、および、保護シート2020

    • Inventor(s)
      井出裕介
    • Industrial Property Rights Holder
      物質・材料研究機構
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2020-137234
    • Filing Date
      2020
    • Related Report
      2020 Annual Research Report

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Published: 2018-04-23   Modified: 2024-01-30  

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