• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Charge/ Hydrogen -Transport and -Storage through the Exchanging Reactions in Redox Polymers

Research Project

Project/Area Number 18H03921
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Review Section Medium-sized Section 35:Polymers, organic materials, and related fields
Research InstitutionWaseda University

Principal Investigator

NISHIDE Hiroyuki  早稲田大学, 理工学術院, 名誉教授 (90120930)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥41,210,000 (Direct Cost: ¥31,700,000、Indirect Cost: ¥9,510,000)
Fiscal Year 2020: ¥13,260,000 (Direct Cost: ¥10,200,000、Indirect Cost: ¥3,060,000)
Fiscal Year 2019: ¥13,260,000 (Direct Cost: ¥10,200,000、Indirect Cost: ¥3,060,000)
Fiscal Year 2018: ¥14,690,000 (Direct Cost: ¥11,300,000、Indirect Cost: ¥3,390,000)
Keywords機能性高分子 / 機能性有機材料 / 高分子合成 / レドックス反応 / 電荷貯蔵 / グリーンマテリアル / 二次電池 / 水素キャリア / 高分子物性
Outline of Final Research Achievements

Redox polymers are organic polymers that reversibly undergo redox or electron-releasing and -gaining reactions. Very efficient transport and storage of charge (electron and counter ion) or hydrogen molecule (proton) in the redox polymers were experimentally characterized with the rapid exchanging-reactions and concentration-gradient-driven diffusion among the densely populated redox-active sites. Employing the redox polymers in rechargeable batteries, a hydrogen carrier, an oxygen-barrier film, etc. were demonstrated in the perspective of the functional polymers for use in sustainable energy-related technologies.

Academic Significance and Societal Importance of the Research Achievements

電池のように電荷(すなわち電気)を貯蔵し放出できる材料の多くは金属・金属酸化物など無機物によっている。また水素の化学的な貯蔵でも同じである。これらエネルギーの貯蔵作用を、レドックス能もち軽量・成形性ある有機高分子材料で発現できる可能性を提示した研究である。無機材料には無い特性として、数秒でのフル充電、サロンパス様電池、水素運搬プラスチック、酸素バリアフィルムなどを例示し、資源制約少なく環境適合・安全な機能材料としてアピールした。

Report

(4 results)
  • 2021 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (35 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (1 results) Journal Article (22 results) (of which Int'l Joint Research: 10 results,  Peer Reviewed: 22 results,  Open Access: 8 results) Presentation (10 results) (of which Int'l Joint Research: 10 results,  Invited: 10 results) Patent(Industrial Property Rights) (2 results)

  • [Int'l Joint Research] Monash University(オーストラリア)

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Hydrophilic Anthraquinone-Substituted Polymer: Its Environmentally Friendly Preparation and Efficient Charge/Proton-Storage Capability for Polymer?Air Secondary Batteries2021

    • Author(s)
      Oka Kouki、Murao Saki、Kataoka Miho、Nishide Hiroyuki、Oyaizu Kenichi
    • Journal Title

      Macromolecules

      Volume: 54 Issue: 10 Pages: 4854-4859

    • DOI

      10.1021/acs.macromol.1c00865

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis of vinyl polymers substituted with 2-propanol and acetone and investigation of their reversible hydrogen storage capabilities2021

    • Author(s)
      Oka Kouki、Tobita Yuka、Kataoka Miho、Murao Saki、Kobayashi Kazuki、Furukawa Shuhei、Nishide Hiroyuki、Oyaizu Kenichi
    • Journal Title

      Polymer Journal

      Volume: - Issue: 7 Pages: 799-804

    • DOI

      10.1038/s41428-021-00475-1

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copolymer of Phenylene and Thiophene toward a Visible‐Light‐Driven Photocatalytic Oxygen Reduction to Hydrogen Peroxide2021

    • Author(s)
      Oka Kouki、Nishide Hiroyuki、Winther‐Jensen Bjorn
    • Journal Title

      Advanced Science

      Volume: 8 Issue: 5 Pages: 2003077-2003077

    • DOI

      10.1002/advs.202003077

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Completely Solar-Driven Photoelectrochemical Water Splitting Using a Neat Polythiophene Film2021

    • Author(s)
      Oka Kouki、Nishide Hiroyuki、Winther-Jensen Bjorn
    • Journal Title

      Cell Reports Physical Science

      Volume: 2 Issue: 1 Pages: 100306-100306

    • DOI

      10.1016/j.xcrp.2020.100306

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Organic π‐Conjugated Polymers as Photocathode Materials for Visible‐Light‐Enhanced Hydrogen and Hydrogen Peroxide Production from Water2021

    • Author(s)
      Oka Kouki、Winther‐Jensen Bjorn、Nishide Hiroyuki
    • Journal Title

      Advanced Energy Materials

      Volume: 11 Issue: 43 Pages: 2003724-2003724

    • DOI

      10.1002/aenm.202003724

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrophilic isopropanol/acetone‐substituted polymers for safe hydrogen storage2021

    • Author(s)
      Oka Kouki、Tobita Yuka、Kataoka Miho、Kobayashi Kazuki、Kaiwa Yusuke、Nishide Hiroyuki、Oyaizu Kenichi
    • Journal Title

      Polymer International

      Volume: 71 Issue: 3 Pages: 348-351

    • DOI

      10.1002/pi.6337

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile reversible hydrogenation of a poly(6‐vinyl‐2,3‐dimethyl‐1,2,3,4‐tetrahydroquinoxaline) gel‐like solid2020

    • Author(s)
      Kaiwa Yusuke、Oka Kouki、Nishide Hiroyuki、Oyaizu Kenichi
    • Journal Title

      Polymers for Advanced Technologies

      Volume: 32 Issue: 3 Pages: 1162-1167

    • DOI

      10.1002/pat.5163

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Poly(dihydroxybenzoquinone): its high-density and robust charge storage capability in rechargeable acidic polymer?air batteries2020

    • Author(s)
      Oka Kouki、Furukawa Shuhei、Murao Saki、Oka Tatsuya、Nishide Hiroyuki、Oyaizu Kenichi
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 29 Pages: 4055-4058

    • DOI

      10.1039/d0cc00660b

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tuning Conformational H-Bonding Arrays in Aromatic/Alicyclic Polythiourea Toward High Energy-Storable Dielectric Material2019

    • Author(s)
      Yang Feng, Yui Hasegawa, Takeo Suga, Hiroyuki Nishide, Liuqing Yang, George Chen, Shengtao Li
    • Journal Title

      Macromolecules

      Volume: 52 Issue: 33 Pages: 8781-8787

    • DOI

      10.1039/d0py00091d

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Characterization of PEDOT-Quinone conducting redox polymers in water-in-salt electrolytes for safe and high-energy Li-ion batteries2019

    • Author(s)
      Oka Kouki、Strietzel Christian、Emanuelsson Rikard、Nishide Hiroyuki、Oyaizu Kenichi、Str?mme Maria、Sj?din Martin
    • Journal Title

      Electrochemistry Communications

      Volume: 105 Pages: 106489-106489

    • DOI

      10.1016/j.elecom.2019.106489

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Oxygen Scavenging and Oxygen Barrier Poly (1, 2‐butadiene) Films Containing an Iron‐Complex Catalyst2019

    • Author(s)
      Yu Wang, Motoharu Shoda, Ayako Hisama, Kenichi Oyaizu, Hiroyuki Nishide
    • Journal Title

      Macromol. Chem. Phys.

      Volume: 220 Issue: 19 Pages: 1900294-1900294

    • DOI

      10.1002/macp.201900294

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Hydrogen Releasing and Fixing with Poly(Vinylfluorenol) through a Mild Ir‐Catalyzed Dehydrogenation and Electrochemical Hydrogenation2019

    • Author(s)
      Kato Ryo、Oka Kouki、Yoshimasa Keisuke、Nakajima Masataka、Nishide Hiroyuki、Oyaizu Kenichi
    • Journal Title

      Macromolecular Rapid Communications

      Volume: 40 Issue: 16 Pages: 1900139-1900139

    • DOI

      10.1002/marc.201900139

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nonconjugated Redox-Active Polymer Mediators for Rapid Electrocatalytic Charging of Lithium Metal Oxides2019

    • Author(s)
      Hatakeyama-Sato Kan、Masui Tomomi、Serikawa Takuma、Sasaki Yusuke、Choi Wonsung、Doo Seok-Gwang、Nishide Hiroyuki、Oyaizu Kenichi
    • Journal Title

      ACS Applied Energy Materials

      Volume: 2 Issue: 9 Pages: 6375-6382

    • DOI

      10.1021/acsaem.9b01007

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] n-Type Redox-active Benzoylpyridinium-substituted Supramolecular Gel for an Organogel-based Rechargeable Device2019

    • Author(s)
      K. Hatakeyama-Sato, R. Ichinoi, Y. Sasada, Y. Sasaki, K. Oyaizu, H. Nishide
    • Journal Title

      Chem. Lett.

      Volume: 48 Issue: 6 Pages: 555-557

    • DOI

      10.1246/cl.190085

    • NAID

      130007659793

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultra-thin and Stretchable Rechargeable Devices with Organic Polymer Nanosheets Conformable to Skin Surface2019

    • Author(s)
      Hatakeyama-Sato, K., Wakamatsu, H., Yamagishi, K., Fujie, T., Takeoka, S., Oyaizu, K., Hiroyuki, N.
    • Journal Title

      Small

      Volume: 15 Issue: 13 Pages: 1805209-1805209

    • DOI

      10.1002/smll.201805296

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Poly (1, 4‐di (2‐thienyl)) benzene Facilitating Complete Light‐Driven Water Splitting under Visible Light at High pH2019

    • Author(s)
      Kouki Oka, Kanako Noguchi, Takeo Suga, Hiroyuki Nishide, Bjorn Winther-Jensen
    • Journal Title

      Advanced Energy Materials

      Volume: 9 Issue: 6 Pages: 1803286-1803286

    • DOI

      10.1002/aenm.201803286

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] How to Install TEMPO in Dielectric Polymers-Their Rational Design toward Energy‐Storable Materials2019

    • Author(s)
      Yang Feng, Takeo Suga, Hiroyuki Nishide, Yoshimichi Ohki, George Chen, Shengtao Li
    • Journal Title

      Macromolecular rapid communications

      Volume: 40 Issue: 4 Pages: 18007-18007

    • DOI

      10.1002/marc.201800734

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Long-lived water clusters in hydrophobic solvents investigated by standard NMR techniques2019

    • Author(s)
      Kouki Oka, Toshimichi Shibue, Natsuhiko Sugimura, Yuki Watabe, Bjorn Winther-Jensen, Hiroyuki Nishide
    • Journal Title

      Scientific Reports

      Volume: 9 Issue: 1 Pages: 223-223

    • DOI

      10.1038/s41598-018-36787-1

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrophilic Organic Redox-active Polymer Nanoparticles for Higher Energy Density Flow Batteries2019

    • Author(s)
      K. Hatakeyama-Sato, T. Nagano, S. Noguchi, Y. Sugai, J. Du, H. Nishide, K. Oyaizu
    • Journal Title

      ACS Applied Polym. Mater.

      Volume: 1 Issue: 2 Pages: 188-196

    • DOI

      10.1021/acsapm.8b00074

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Poly(vinyldibenzothiophenesulfone): Its Redox Capability at Very Negative Potential Toward an All‐Organic Rechargeable Device with High‐Energy Density2018

    • Author(s)
      Oka Kouki、Kato Ryo、Oyaizu Kenichi、Nishide Hiroyuki
    • Journal Title

      Advanced Functional Materials

      Volume: 28 Issue: 50 Pages: 1805858-1805858

    • DOI

      10.1002/adfm.201805858

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Ultrahigh Output Rechargeable Electrode of a Hydrophilic Radical Polymer/Nanocarbon Hybrid with an Exceptionally Large Current Density beyond 1 A cm?22018

    • Author(s)
      Hatakeyama-Sato Kan、Wakamatsu Hisato、Katagiri Ryu、Oyaizu Kenichi、Nishide Hiroyuki
    • Journal Title

      Advanced Materials

      Volume: 30 Issue: 26 Pages: 1800900-1800900

    • DOI

      10.1002/adma.201800900

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Light-assisted electrochemical water-splitting at verylow bias voltage using metal-free polythiophene as photocathode at high pH in a full-cell setup2018

    • Author(s)
      Kouki Oka, Orie Tsujimura, Takeo Suga, Hiroyuki Nishide and Bjorn Winther-Jensen
    • Journal Title

      Energy Environ. Sci.

      Volume: - Issue: 5 Pages: 1335-1342

    • DOI

      10.1039/c7ee03669h

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Allylic polymers as an Ultrahigh Oxygen-scavenging and Active Packaging Film2021

    • Author(s)
      H. Nishide
    • Organizer
      7th Congress of Federation of Asian Polymer Societies
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] “Solar-Driven Water Splitting with a Specialty Polymer”2019

    • Author(s)
      H. Nishide
    • Organizer
      8th Int Symp on Specialty Polymers
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] “Macromolecular Complexes as an Advanced Functional Polymer”2019

    • Author(s)
      H. Nishide
    • Organizer
      18th IUPAC Int Symp on Macromolecule-Matal Complexes
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] “Radical Polymers as an Organic Charge-transport and Energy-storage Material”2019

    • Author(s)
      H. Nishide
    • Organizer
      Organic Battery Days 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] “Polythiophenes for Solar-Driven Water Splitting”2019

    • Author(s)
      H. Nishide
    • Organizer
      6th FAPS Polymer Congress
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] “Polythiophenes for Solar-Driven Water Splitting”2019

    • Author(s)
      H. Nishide
    • Organizer
      12nd East Asian Symp on Polymer for Advanced Technologies
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Radical Polymer/ Nanocarbon Hybrid as an Ultrahigh Output Rechargeable Electrode2018

    • Author(s)
      H. Nishide
    • Organizer
      8th Int. Symp. Polymer Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ultrathin and Flexible Rechargeable Deavies with Organic Polymer Nanosheets2018

    • Author(s)
      H. Nishide
    • Organizer
      5th Int. Biomaterials Symp.
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Materials Informatics for Enegy-related Functional Polmers2018

    • Author(s)
      H. Nishide
    • Organizer
      Polymer Soc. Korea, Fall Meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Redox- active Polymers as an Organic Charge- Trangat and Energy- Storage Material2018

    • Author(s)
      H. Nishide
    • Organizer
      12th Inter. Polymer Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Patent(Industrial Property Rights)] 水素の製造方法2020

    • Inventor(s)
      西出宏之、岡弘樹、ビヨーン ウインザー ジェンセン
    • Industrial Property Rights Holder
      西出宏之、岡弘樹、ビヨーン ウインザー ジェンセン
    • Industrial Property Rights Type
      特許
    • Filing Date
      2020
    • Acquisition Date
      2020
    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] 過酸化水素の製造法2019

    • Inventor(s)
      西出宏之、岡弘樹、ビヨーン ウインザー ジェンセン
    • Industrial Property Rights Holder
      西出宏之、岡弘樹、ビヨーン ウインザー ジェンセン
    • Industrial Property Rights Type
      特許
    • Filing Date
      2019
    • Acquisition Date
      2019
    • Related Report
      2019 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2023-01-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi