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Low temperature ammonia synthesis by heterogeneous catalysts enhancing electron-donating power

Research Project

Project/Area Number 18H05251
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Review Section Broad Section D
Research InstitutionTokyo Institute of Technology

Principal Investigator

Hara Michikazu  東京工業大学, 科学技術創成研究院, 教授 (70272713)

Co-Investigator(Kenkyū-buntansha) Chandra Debraj  東京工業大学, 科学技術創成研究院, 特任准教授 (20802309)
Project Period (FY) 2018-06-11 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥190,580,000 (Direct Cost: ¥146,600,000、Indirect Cost: ¥43,980,000)
Fiscal Year 2022: ¥32,110,000 (Direct Cost: ¥24,700,000、Indirect Cost: ¥7,410,000)
Fiscal Year 2021: ¥34,190,000 (Direct Cost: ¥26,300,000、Indirect Cost: ¥7,890,000)
Fiscal Year 2020: ¥34,190,000 (Direct Cost: ¥26,300,000、Indirect Cost: ¥7,890,000)
Fiscal Year 2019: ¥35,490,000 (Direct Cost: ¥27,300,000、Indirect Cost: ¥8,190,000)
Fiscal Year 2018: ¥54,600,000 (Direct Cost: ¥42,000,000、Indirect Cost: ¥12,600,000)
Keywords不均一系触媒 / アンモニア / ハーバー・ボッシュ法 / 鉄 / レアメタル / 電子供与体 / アンモニア合成 / アルカリ土類金属水素化物 / ルテニウム / ヒドリド欠陥 / 水素化フッ化カルシウム / 固溶体 / 酸化バリウム / 水素化バリウム
Outline of Final Research Achievements

BaO-BaH2 mixture loaded with Ru nanoparticles (Ru/BaO-BaH2) exhibited high catalytic performance for ammonia synthesis; the catalytic activity is comparable to that of a catalyst that has the highest catalytic activity for the reaction. In addition, it was found that Ru nanoparticles-deposited CaFH solid solution (Ru/CaFH) acts as a catalyst to synthesize ammonia even at 50 degrees Celsius. This catalyst exhibited much higher catalytic performance for ammonia synthesis than Ru/BaO-BaH2. Furthermore, metallic iron particles loaded with BaO-BaH2 (BaO-BaH2/Fe) was found to act as the first iron based catalyst that can synthesize ammonia below 100 degrees Celsius.

Academic Significance and Societal Importance of the Research Achievements

Fe触媒はNH3大量製造を初めて可能にしたが、近年Ru、Co、Niといった貴金属やレアメタルの触媒研究が進むにつれて、それは性能の低い時代遅れの触媒と考えられるようになってきた。このような背景の下、低温で作動する強い電子供与体を適切にFeと複合させれば、Fe触媒は上記遷移金属触媒の数百倍以上のNH3合成活性を発現することを本研究は明らかにした。更に、地域偏在性のない豊富で安価なFeを原料とする当該触媒は100年以上30%台であったハーバー・ボッシュ法のNH3収率を大幅に押し上げる道を開いた。これは少ないエネルギーで安価なNH3が製造できることを意味する。

Assessment Rating
Ex-post Assessment Comments (Rating)

A+: In light of the aim of introducing the research area into the research categories, more research outcomes have been produced than expected.

Assessment Rating
Interim Assessment Comments (Rating)

A+: In light of the aim of introducing the research area into the research categories, more progress has been made in research than expected.

Report

(11 results)
  • 2023 Ex-post Assessment (Comments) ( PDF )
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Abstract (Interim Assessment) ( PDF )   Annual Research Report   Interim Assessment (Comments) ( PDF )
  • 2019 Annual Research Report
  • 2018 Abstract ( PDF )   Comments on the Screening Results ( PDF )   Annual Research Report
  • Research Products

    (78 results)

All 2023 2022 2021 2020 2019 2018 Other

All Journal Article (23 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 23 results,  Open Access: 5 results) Presentation (48 results) (of which Int'l Joint Research: 5 results,  Invited: 14 results) Remarks (5 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Low-Temperature Ammonia Synthesis on Iron Catalyst with an Electron Donor2023

    • Author(s)
      Masashi Hattori, Natsuo Okuyama, Hiyori Kurosawa, and Michikazu Hara
    • Journal Title

      Journal of the American Chemical Society

      Volume: 145 Issue: 14 Pages: 7888-7897

    • DOI

      10.1021/jacs.2c13015

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] β-MnO2 nanoparticles as heterogenous catalysts for aerobic oxidative transformation of alcohols to carbonyl compounds, nitriles, and amides2022

    • Author(s)
      Keigo Kamata, Nanami Kinoshita, Maki Koutani, Ryusei Aono, Eri Hayashi, Michikazu Hara
    • Journal Title

      Catalysis Science & Technology

      Volume: 12 Issue: 20 Pages: 6219-6230

    • DOI

      10.1039/d2cy01476a

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heterogeneous Low-valent Mn Catalysts for α-Alkylation of Ketones with Alcohols through Borrowing Hydrogen Methodology2022

    • Author(s)
      Yusuke Kita, Midori Kuwabara, Keigo Kamata, Michikazu Hara
    • Journal Title

      ACS Catalysis

      Volume: 12 Issue: 19 Pages: 11767-11775

    • DOI

      10.1021/acscatal.2c03085

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Primary Amine Synthesis by Hydrogen-involving Reactions over Heterogeneous Cobalt Catalysts2022

    • Author(s)
      Kahoko Kato, Dian Deng, Yusuke Kita, Keigo Kamata, Michikazu Hara
    • Journal Title

      Catalysis Science & Technology

      Volume: 12 Issue: 17 Pages: 5425-5434

    • DOI

      10.1039/d2cy00870j

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Aerobic Oxidation Catalysis of Mesoporous Todorokite-type Manganese Oxides Nanoparticles by Crystallization of Precursors2022

    • Author(s)
      Maki Koutani, Eri Hayashi, Keigo Kamata, Michikazu Hara
    • Journal Title

      Journal of the American Chemical Society

      Volume: 144 Issue: 31 Pages: 14090-14100

    • DOI

      10.1021/jacs.2c02308

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stability enhancement of iron-based perovskite catalysts by A-site substituion for oxidative transposition of α-bromostyrene to phenacyl bromide2022

    • Author(s)
      Satomi Shibata, Keigo Kamata, Michikazu Hara
    • Journal Title

      ChemCatChem

      Volume: 14 Issue: 18

    • DOI

      10.1002/cctc.202200395

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Heterogeneous Cobalt Catalyst for C-C Bond Formation by Borrowing Hydrogen Strategy2022

    • Author(s)
      Endah Suarsih, Yusuke Kita, Keigo Kamata, Michikazu Hara
    • Journal Title

      Catalysis Science & Technology

      Volume: 12 Issue: 13 Pages: 4113-4117

    • DOI

      10.1039/d2cy00724j

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synergistic Effects of Earth-Abundant Metal-Metal Oxide Enable Reductive Amination of Carbonyls at 50 °C2022

    • Author(s)
      Bhunia Manas K.、Chandra Debraj、Abe Hitoshi、Niwa Yasuhiro、Hara Michikazu
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 14 Issue: 3 Pages: 4144-4154

    • DOI

      10.1021/acsami.1c21157

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Base-Assisted Aerobic C-H Oxidation of Alkylarenes with a Murdochite-Type Oxide Mg6MnO8 Nanoparticle Catalyst2022

    • Author(s)
      Hayashi Eri、Tamura Takatoshi、Aihara Takeshi、Kamata Keigo、Hara Michikazu
    • Journal Title

      ACS Applied Materials and Interfaces

      Volume: 14 Issue: 5 Pages: 6528-6537

    • DOI

      10.1021/acsami.1c20080

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Novel Tetradentate Phosphonate Ligand Based Bioinspired Co-Metal Organic Frameworks: Robust Electrocatalyst for the Hydrogen Evolution Reaction in Different Mediums2021

    • Author(s)
      Chakraborty Debabrata、Chowdhury Avik、Chandra Moumita、Jana Rajkumar、Shyamal Sanjib、Bhunia Manas K.、Chandra Debraj、Hara Michikazu、Pradhan Debabrata、Datta Ayan、Bhaumik Asim
    • Journal Title

      Crystal Growth & Design

      Volume: 21 Issue: 5 Pages: 2614-2623

    • DOI

      10.1021/acs.cgd.0c01275

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Iron phosphate nanoparticle catalyst for direct oxidation of methane into formaldehyde: effect of surface redox and acid base properties2021

    • Author(s)
      Matsuda Aoi、Tateno Haruka、Kamata Keigo、Hara Michikazu
    • Journal Title

      Catalysis Science and Technology

      Volume: 11 Issue: 21 Pages: 6987-6998

    • DOI

      10.1039/d1cy01265g

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Aerobic oxidative C=C bond cleavage of aromatic alkenes by a high valency iron-containing perovskite catalyst2021

    • Author(s)
      Satomi Shibata, Keigo Kamata and Michikazu Hara
    • Journal Title

      Catalysis Science & Technology

      Volume: 11 Issue: 7 Pages: 2369-2373

    • DOI

      10.1039/d1cy00245g

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electronic Effect in a Ruthenium Catalyst Designed in Nanoporous N-Functionalized Carbon for Efficient Hydrogenation of Heteroarenes2020

    • Author(s)
      Debraj Chandra, Shikha Saini, Saswata Bhattacharya, Asim Bhaumik, Keigo Kamata, and Michikazu Hara
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 12 Issue: 47 Pages: 668-677

    • DOI

      10.1021/acsami.0c15407

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effects of ruthenium hydride species on primary amine synthesis by direct amination of alcohols over a heterogeneous Ru catalyst2020

    • Author(s)
      Yusuke Kita, Midori Kuwabara, Satoshi Yamadera, Keigo Kamata and Michikazu Hara
    • Journal Title

      Chemical Science

      Volume: 11 Issue: 36 Pages: 9884-9890

    • DOI

      10.1039/d0sc03858j

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solid solution for catalytic ammonia synthesis from nitrogen and hydrogen gases at 50 °C2020

    • Author(s)
      Hattori Masashi、Iijima Shinya、Nakao Takuya、Hosono Hideo、Hara Michikazu
    • Journal Title

      Nature Communications

      Volume: 11 Issue: 1 Pages: 1-8

    • DOI

      10.1038/s41467-020-15868-8

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] One-pot Aerobic Oxidative Sulfonamidation of Aromatic Thiols with Ammonia by a Dual-functional β-MnO2 Nanocatalyst2020

    • Author(s)
      Eri Hayashi, Yui Yamaguchi, Yusuke Kita, Keigo Kamata, Michikazu Hara
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 14 Pages: 2095-2098

    • DOI

      10.1039/c9cc09411c

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Benzylic C‐H Fluorination over Supported Silver Catalyst2019

    • Author(s)
      Yusuke Kita, Shunsuke Shigetani, Keigo Kamata, Michikazu Hara
    • Journal Title

      Molecular Catalysis

      Volume: 475 Pages: 110463-110463

    • DOI

      10.1016/j.mcat.2019.110463

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of MnO2 Crystal Structure on Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid2019

    • Author(s)
      Eri Hayashi, Yui Yamaguchi, Keigo Kamata, Naoki Tsunoda, Yu Kumagai, Fumiyasu Oba, Michikazu Hara
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Issue: 2 Pages: 890-900

    • DOI

      10.1021/jacs.8b09917

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct Activation of Cobalt Catalyst by 12CaO7Al2O3 Electride for Ammonia Synthesis2019

    • Author(s)
      Yasunori Inoue, Masaaki Kitano, Mai Tokunari, Teppei Taniguchi, Kayato Ooya, Hitoshi Abe, Yasuhiro Niwa, Masato Sasase, Michikazu Hara,* Hideo Hosono
    • Journal Title

      ACS Catalysis

      Volume: 9 Issue: 3 Pages: 1670-1679

    • DOI

      10.1021/acscatal.8b03650

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Low-temperature Reductive Amination of Carbonyl Compounds over Ru-deposited on Nb2O5nH2O2019

    • Author(s)
      Dian Deng, Yusuke Kita, Keigo Kamata, Michikazu Hara
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 7 Issue: 5 Pages: 4692-4698

    • DOI

      10.1021/acssuschemeng.8b04324

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Catalytic Ammonia Synthesis with Transformed BaO2018

    • Author(s)
      Masashi Hattori, Taiyo Mori, Tomohiro Arai, Yasunori Inoue, Masato Sasase, Tomofumi Tada, Masaaki Kitano, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono
    • Journal Title

      ACS Catalysis

      Volume: 8 Issue: 12 Pages: 10977-10984

    • DOI

      10.1021/acscatal.8b02839

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High Performance Catalyst of Shape-specific Ruthenium Nanoparticles for Production of Primary Amines by Reductive Amination of Carbonyl Compounds2018

    • Author(s)
      Debraj Chandra, Yasunori Inoue, Masato Sasase, Masaaki Kitano, Asim Bhaumik, Keigo Kamata, Hideo Hosono, Michikazu Hara
    • Journal Title

      Chemical Science

      Volume: 9 Issue: 27 Pages: 5949-5956

    • DOI

      10.1039/c8sc01197d

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Heterogeneously Catalyzed Aerobic Oxidation of Sulfides with a BaRuO3 Nanoperovskite2018

    • Author(s)
      Keigo Kamata, Kosei Sugahara, Yuuki Kato, Satoshi Muratsugu, Yu Kumagai, Fumiyasu Oba, Michikazu Hara
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 28 Pages: 23792-23801

    • DOI

      10.1021/acsami.8b05343

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] 50℃で水素と窒素からアンモニアを合成する新触媒『CO2排出ゼロ』のアンモニア生産へブレークスルー2022

    • Author(s)
      原 亨和
    • Organizer
      都立高校生のための先端科学・技術フォーラム
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] 低温アンモニア合成触媒の開発:50℃でアンモニアを合成する不均一系触媒2022

    • Author(s)
      原 亨和
    • Organizer
      第67回 国立大学附置研究所・センター会議第1部会シンポジウム
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] 低温アンモニア合成触媒の開発:50℃でアンモニアを合成する不均一系触媒2022

    • Author(s)
      原 亨和
    • Organizer
      第4回GXIセミナー
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] FeとY種を組み合わせた触媒によるアンモニア合成2022

    • Author(s)
      浴 歩輝
    • Organizer
      第12回 CSJ化学フェスタ2022
    • Related Report
      2022 Annual Research Report
  • [Presentation] バリウムハイドライドと複合化した鉄による低温アンモニア合成2022

    • Author(s)
      黑沢 ひより
    • Organizer
      第12回 CSJ化学フェスタ2022
    • Related Report
      2022 Annual Research Report
  • [Presentation] アルミニウム種促進鉄触媒によるアンモニア合成2022

    • Author(s)
      宮下 健人
    • Organizer
      第12回 CSJ化学フェスタ2022
    • Related Report
      2022 Annual Research Report
  • [Presentation] シリカ担持コバルト触媒によるニトリル水素化を用いた選択的一級アミン合成2022

    • Author(s)
      加藤 可百子
    • Organizer
      日本化学会第102春季年会(2022)
    • Related Report
      2021 Annual Research Report
  • [Presentation] Borrowing Hydrogen法によるアルコール変換を可能とする不均一系マンガン触媒の開発2022

    • Author(s)
      喜多 祐介
    • Organizer
      日本化学会第102春季年会(2022)
    • Related Report
      2021 Annual Research Report
  • [Presentation] 新技術で工場排熱(200℃以下)によるアンモニア生産の可能性と、アンモニアを使ったCO2削減2021

    • Author(s)
      原 亨和
    • Organizer
      第347回科学技術展望懇談会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Development of Metallic Cobalt Catalysts for Reductive Amination at Low Temperature and Hydrogen Pressure2021

    • Author(s)
      Dian Deng
    • Organizer
      The 12th International Conference on the Science and Technology for Advanced Ceramics (STAC-12)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イッテルビウム種を添加した鉄触媒によるアンモニア合成2021

    • Author(s)
      森實 泰貴
    • Organizer
      第128回触媒討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Y種を担持した鉄触媒による高活性なアンモニア合成触媒の開発2021

    • Author(s)
      浴 歩輝
    • Organizer
      第128回触媒討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ヒドロシランを用いた液相還元法による大気安定性Ni触媒の調製2021

    • Author(s)
      竹内 舜
    • Organizer
      第128回触媒討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 担持鉄触媒を用いたカルボニル化合物の還元的アミノ化反応による一級アミン合成2021

    • Author(s)
      新井 麻友
    • Organizer
      第128回触媒討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Borrowing Hydrogen法を用いた変換反応を可能とする不均一系マンガン触媒の開発2021

    • Author(s)
      桑原 翠
    • Organizer
      第128回触媒討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Co/SiO2触媒を用いたニトリルの水素化による一級アミン合成2021

    • Author(s)
      加藤 可百子
    • Organizer
      第128回触媒討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Advanced nonoarchitectures of Ru-based metal catalysts towards production of value-added chemicals2021

    • Author(s)
      Debraj Chandra
    • Organizer
      Pacifichem 2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] 炭素系固体ブレンステッド酸の触媒作用と応用展開2021

    • Author(s)
      原 亨和
    • Organizer
      炭素材料学会1月セミナー
    • Related Report
      2020 Annual Research Report
  • [Presentation] コバルト・バリウム複合系と水素化カルシウムの混合触媒によるアンモニア合成2021

    • Author(s)
      森實泰貴、服部真史、鎌田慶吾、原 亨和
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Heterogeneous Co catalyst for α-alkylation fo ketones with primary alcohols through borrowing hydrogen strategy2021

    • Author(s)
      Endah Suarsih、喜多祐介、鎌田慶吾、原 亨和
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 担持コバルト触媒を用いたニトリル水素化による一級アミン合成2021

    • Author(s)
      加藤可百子、喜多祐介、鎌田慶吾、原 亨和
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ルテニウム触媒によるアルコール類の直接アミノ化におけるMgOの効果2021

    • Author(s)
      喜多祐介、桑原翠、鎌田慶吾、原 亨和
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] バイオマスを利用した環境にやさしい化学プロセスの創出2020

    • Author(s)
      原 亨和
    • Organizer
      9th JACI/GSC Symposium 2020
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Sugar conversion to a monomer for high-performance polyamides2020

    • Author(s)
      Michikazu Hara
    • Organizer
      2020 Tokyo tech Reseach Showcase
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 未利用バイオマスからの戦略化学資源の生産2020

    • Author(s)
      原 亨和
    • Organizer
      第10回CSJ化学フェスタ
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] バイオマスからプラスチック原料を製造する固体触媒2020

    • Author(s)
      原 亨和
    • Organizer
      時代を刷新する会 月例会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] コバルト・バリウム複合系と水素化カルシウムの混合触媒によるアンモニア合成2020

    • Author(s)
      森實泰貴、服部真史、原 亨和
    • Organizer
      第10回CSJ化学フェスタ
    • Related Report
      2020 Annual Research Report
  • [Presentation] 不均一系Ru触媒を用いたアルコールの直接アミノ化反応2020

    • Author(s)
      桑原翠、喜多祐介、鎌田慶吾、原 亨和
    • Organizer
      第10回CSJ化学フェスタ
    • Related Report
      2020 Annual Research Report
  • [Presentation] 低水素圧下で還元的アミノ化反応を可能とするコバルト触媒の開発2020

    • Author(s)
      加藤可百子、DENG Dian、喜多祐介、鎌田慶吾、原 亨和
    • Organizer
      第10回CSJ化学フェスタ
    • Related Report
      2020 Annual Research Report
  • [Presentation] Ru-MgO/TiO2を用いたアルコールの直接アミノ化反応2020

    • Author(s)
      桑原翠、喜多祐介、鎌田慶吾、原 亨和
    • Organizer
      9th JACI/GSC Symposium 2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] Co/SiO2触媒による還元的アミノ化反応2020

    • Author(s)
      加藤可百子、喜多祐介、鎌田慶吾、原 亨和
    • Organizer
      9th JACI/GSC Symposium 2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] Co/SiO2触媒による低水素圧還元的アミノ化反応2020

    • Author(s)
      加藤可百子、喜多祐介、鎌田慶吾、原 亨和
    • Organizer
      第126回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Ru触媒を用いたアルコールの直接アミノ化反応による2.5-ビスアミノメチルフラン合成2020

    • Author(s)
      桑原翠、喜多祐介、鎌田慶吾、原 亨和
    • Organizer
      第126回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 水素化カルシウムを用いた鉄触媒系によるアンモニア合成2020

    • Author(s)
      奥山夏生、服部真史、原 亨和
    • Organizer
      第10回CSJ化学フェスタ
    • Related Report
      2020 Annual Research Report
  • [Presentation] 水素化カルシウム担持ルテニウム触媒を用いたアンモニア合成の低温化2020

    • Author(s)
      飯嶋慎也、服部真史、原亨和
    • Organizer
      第125回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] コバルト-水素化カルシウム混合系触媒を用いたアンモニア合成2020

    • Author(s)
      池田奈央、服部真史、原亨和
    • Organizer
      第125回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 環境低負荷触媒プロセスの構築2019

    • Author(s)
      原 亨和
    • Organizer
      第14回四大学連合文化講演会 東京医科歯科大学
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Advanced nanoarchitectures as efficient catalysts towards production of value-added chemicals and fuel2019

    • Author(s)
      Debraj Chandra
    • Organizer
      31th American Advanced Materials Congress
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] HMF conversion into polymer monomers2019

    • Author(s)
      Michikazu Hara
    • Organizer
      International Symposium on Heterogeneous Catalysis for Sustainable Energy and Chemical Production
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Glucose Conversion into Biobased Monomers by Heterogeneous Catalysts2019

    • Author(s)
      Michikazu Hara
    • Organizer
      4th International Conference on Biopolymers & Polymer Chemistry
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Ni/NiOのOne-pot還元的アミノ化反応への応用2019

    • Author(s)
      甲斐彩、喜多祐介、鎌田慶吾、原亨和
    • Organizer
      第78回有機合成化学協会関東支部シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 担持銀触媒によるベンジル位炭素-水素結合の直接フッ素化反応2019

    • Author(s)
      喜多祐介、重谷俊輔、鎌田慶吾、原亨和
    • Organizer
      第78回有機合成化学協会関東支部シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] Bao添加CaH2担持Ruによる効率的アンモニア合成2019

    • Author(s)
      服部真史、新井智尋、多田朋史、北野政明、原亨和、細野秀雄
    • Organizer
      第123回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Baoを添加したRu担持CaH2による効率的アンモニア合成2019

    • Author(s)
      服部真史、新井智尋、多田朋史、北野政明、原亨和、細野秀雄
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Nanoarchitectures as heterogeneous catalytic system towards production of value-added chemicals and solar-fuel2018

    • Author(s)
      Debraj Chandra
    • Organizer
      International Conference on Nanomaterials & Nanotechnology(ICNANO)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ammonia synthesis by electride catalysts2018

    • Author(s)
      Michikazu Hara
    • Organizer
      6th International Conference on Advanced Materials Science and Technology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Direct formation of 5-(hydroxymethyl)furfural from glucose with photoassist-phosphorylated TiO2 catalyst2018

    • Author(s)
      Masashi Hattori
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] バリウム水素化物担持Ru触媒によるアンモニア合成2018

    • Author(s)
      新井智尋、服部真史、原亨和
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Remarks] 50 ℃で水素と窒素からアンモニアを合成する新触媒

    • URL

      https://www.titech.ac.jp/news/2020/046682

    • Related Report
      2022 Annual Research Report
  • [Remarks] 鉄はレアメタルより強し 100 ℃の低温でアンモニアを合成する鉄触媒の開発に成功

    • URL

      https://www.titech.ac.jp/news/2023/066470

    • Related Report
      2022 Annual Research Report
  • [Remarks] Synthesizing ammonia using less energy

    • URL

      https://www.eurekalert.org/pub_releases/2020-04/tiot-ftw042420.php

    • Related Report
      2020 Annual Research Report
  • [Remarks] 50 ℃で水素と窒素からアンモニアを合成する新触媒

    • URL

      https://www.titech.ac.jp/news/2020/046682.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] Fuelling the World Sustainably

    • URL

      https://www.titech.ac.jp/english/news/2020/046753.html

    • Related Report
      2020 Annual Research Report
  • [Patent(Industrial Property Rights)] 含水素アルミニウムと鉄を組み合わせたアンモニア合成触媒2022

    • Inventor(s)
      原 亨和
    • Industrial Property Rights Holder
      原 亨和
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2022-101842
    • Filing Date
      2022
    • Related Report
      2022 Annual Research Report
  • [Patent(Industrial Property Rights)] アンモニア合成触媒2020

    • Inventor(s)
      原 亨和
    • Industrial Property Rights Holder
      原 亨和
    • Industrial Property Rights Type
      特許
    • Filing Date
      2020
    • Related Report
      2020 Annual Research Report

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Published: 2018-06-12   Modified: 2024-03-28  

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