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Attempt to estimate the source mine of vermilion excavated from archaeological sites using an ultra-trace sulfur isotope analyzer

Research Project

Project/Area Number 18K01094
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 03060:Cultural assets study-related
Research InstitutionKindai University

Principal Investigator

Minami Takeshi  近畿大学, 理工学部, 非常勤講師 (00295784)

Co-Investigator(Kenkyū-buntansha) 高橋 和也  国立研究開発法人理化学研究所, 仁科加速器科学研究センター, 特別嘱託研究員 (70221356)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords産地推定 / 遺跡 / 朱 / 硫黄同位体分析 / 超微量硫黄同位体比分析 / 超微量分析 / 遺跡出土朱 / 墳墓
Outline of Final Research Achievements

We have developed an ultra-trace sulphur isotope analyzing system and attempted to estimate the source mine of vermillion excavated from sites before Kofun period using this system. Sampling is completed by lightly pressing a piece of sulphur-free adhesive tape onto the vermillion-bearing artefact, and the red part was cut out with scissors together with the adhesive tape, and sulfur isotope analysis was performed. This means that It does not cause any visible damage to precious crafts and can be analyzed even with a small amount of vermilion. In addition, even if vermilion from different production areas was mixed and used in one archaeological site, it is possible to check whether the vermilion was collected from several production areas by analyzing vermilion from several points at a single site. Using this analysis method, we have received many requests for analysis from cultural property institutions, and have obtained interesting results.

Academic Significance and Societal Importance of the Research Achievements

1粒の朱で硫黄同位体比を測定できる超微量分析法を開発できたことで、貴重な文化財遺物を傷つけることなく、また微量しか用いられていない場合も朱の産地推定が行えるようになった。このことで、様々な文化財関係者から分析依頼を受けて朱の産地推定を行っており、その中には弥生時代の中国産朱の伝来と西日本各地への流通や、古代大和王権と国産朱の使用など、学術的にも、社会的にも貴重な結果が得られた。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (29 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (4 results) Journal Article (18 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 7 results,  Open Access: 5 results) Presentation (7 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Int'l Joint Research] Universitat de Bercelona(スペイン)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] バルセロナ大学(スペイン)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] 中国科学院地質及地球物理研究所/中国地質博物館(中国)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] バルセロナ大学(スペイン)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Identification of source mine using sulfur, mercury, and lead isotope analyses of vermilion used in three representative tombs from Kofun period in Japan2021

    • Author(s)
      Minami Takeshi、Takeuchi Akinori、Imazu Setsuo、Okuyama Masayoshi、Higashikage Yu、Mizuno Toshinori、Okabayashi Kosaku、Takahashi Kazuya
    • Journal Title

      Journal of Archaeological Science: Reports

      Volume: 37 Pages: 102970-102970

    • DOI

      10.1016/j.jasrep.2021.102970

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Sulfur Isotope Analysis to Examine the Provenance of Cinnabar Used in Wall Paintings in the Roman domus Aviny? (Barcelona)2020

    • Author(s)
      Tsantini Evanthia、Minami Takeshi、Cau Ontiveros Miguel ?ngel、Takahashi Kazuya、Melgarejo Joan Carles
    • Journal Title

      Minerals

      Volume: 11 Issue: 1 Pages: 6-6

    • DOI

      10.3390/min11010006

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 硫黄同位体分析による兵庫県の遺跡出土朱の産地推定2020

    • Author(s)
      南 武志、高橋和也、藤田淳、池田征弘
    • Journal Title

      兵庫県立考古博物館研究紀要

      Volume: 13 Pages: 53-58

    • NAID

      40022269561

    • Related Report
      2020 Annual Research Report
  • [Journal Article] 島の山古墳出土朱の産地推定2020

    • Author(s)
      今津節生、南 武志
    • Journal Title

      奈良県文化財調査報告書

      Volume: 183 Pages: 125-127

    • Related Report
      2020 Annual Research Report
  • [Journal Article] 清水風遺跡の朱2020

    • Author(s)
      南 武志、高橋和也
    • Journal Title

      唐古・鍵考古学ミュージアム 展示図録

      Volume: 27 Pages: 11-14

    • Related Report
      2020 Annual Research Report
  • [Journal Article] 与呂木古墳から出土した頭蓋骨付着朱の硫黄同位体分析2020

    • Author(s)
      南 武志、高橋和也
    • Journal Title

      三木市文化研究資料

      Volume: 35 Pages: 35-39

    • Related Report
      2020 Annual Research Report
  • [Journal Article] A method of collecting trace amounts of vermilion from artifacts for source estimation by sulfur isotope (δ34S) analysis: use of sulfur-free adhesive tape to minimize damage to the artifact body during sampling2019

    • Author(s)
      Takeshi Minami, Kousuke Hatanaka, Yuko Motizuki, Yoichi Nakai, and Kazuya Takahashi
    • Journal Title

      Journal of Archaeological Science

      Volume: 28 Pages: 102027-102027

    • DOI

      10.1016/j.jasrep.2019.102027

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] 伯耆国分寺古墳出土朱の産地推定2019

    • Author(s)
      南 武志
    • Journal Title

      伯耆国分寺古墳の研究-島根大学考古学研究室調査報告書

      Volume: 18 Pages: 71-74

    • Related Report
      2019 Research-status Report 2018 Research-status Report
  • [Journal Article] 朱の硫黄同位体分析2019

    • Author(s)
      河野摩耶、南 武志
    • Journal Title

      須玖岡本遺跡6-岡本地区20次調査の報告-

      Volume: 79 Pages: 53-54

    • Related Report
      2019 Research-status Report
  • [Journal Article] 京田遺跡4区出土遺物付着水銀朱の硫黄同位体分析2019

    • Author(s)
      南 武志、高橋和也
    • Journal Title

      京田遺跡4区 出雲市の文化財報告

      Volume: 39 Pages: 165-168

    • Related Report
      2019 Research-status Report
  • [Journal Article] 糸島地方における弥生~古墳時代の赤色顔料 墳墓における朱の使い分けを中心に2019

    • Author(s)
      河野摩耶、南 武志、岡部裕俊
    • Journal Title

      伊都国歴史博物館紀要

      Volume: 14 Pages: 1-16

    • Related Report
      2019 Research-status Report
  • [Journal Article] 小竹1号墳の赤色顔料について2019

    • Author(s)
      河野摩耶、南 武志
    • Journal Title

      遺跡

      Volume: 52 Pages: 123-125

    • Related Report
      2019 Research-status Report
  • [Journal Article] 朱の硫黄同位体分析2019

    • Author(s)
      河野摩耶、南 武志
    • Journal Title

      春日市文化財調査報告書

      Volume: 79 Pages: 53-54

    • Related Report
      2018 Research-status Report
  • [Journal Article] Analysis of sulphur isotopes to identify the origin of cinnabar in the Roman wall paintings from Badalona (Spain)2018

    • Author(s)
      Evanthia Tsantini, Takeshi Minami, Kazuya Takahashi and Miguel Ángel Cau Ontiveros
    • Journal Title

      Journal of Archaeological Science

      Volume: 18 Pages: 300-307

    • DOI

      10.1016/j.jasrep.2018.01.032

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 福岡県安徳台遺跡群における朱の使い分けについて2018

    • Author(s)
      河野摩耶・高橋和也・今津節生・南 武志
    • Journal Title

      古代

      Volume: 142 Pages: 97-103

    • NAID

      40021645824

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] 中国および朝鮮半島における古代の朱産地2018

    • Author(s)
      南 武志
    • Journal Title

      文化財科学

      Volume: 77 Pages: 47-55

    • NAID

      40021746695

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] 黒塚古墳出土朱の産地推定2018

    • Author(s)
      今津節生、南 武志
    • Journal Title

      黒塚古墳の研究

      Volume: 1 Pages: 354-355

    • Related Report
      2018 Research-status Report
  • [Journal Article] High‐sensitivity sulfur isotopic measurements for Antarctic ice core analyses2018

    • Author(s)
      Kazuya Takahashi Yoichi Nakai Yuko Motizuki Toshiyuki Ino Shigeru Ito Satoru B. Ohkubo Takeshi Minami Yuichi Takaku Yoshitaka Yamaguchi Miho Tanaka Hideaki Motoyama
    • Journal Title

      Rapid Communications in Mass Spectrometry

      Volume: 32 Issue: 23 Pages: 1991-1998

    • DOI

      10.1002/rcm.8275

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] イオウ同位体比分析による列島産アスファルトの原産地推定2020

    • Author(s)
      上條信彦、高橋和也、南 武志
    • Organizer
      第37回日本文化財科学会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 遺跡から出土する水銀朱に対する極微量硫黄同位体比分析と産地同定の試み2019

    • Author(s)
      高橋 和也、南 武志、幡中 光輔
    • Organizer
      第79回分析化学討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 超微量硫黄同位体分析法を用いた弥生時代遺跡出土土器付着朱 の産地推定2019

    • Author(s)
      南 武志、高橋和也
    • Organizer
      第36回日本文化財科学会
    • Related Report
      2019 Research-status Report
  • [Presentation] イオウ同位体比分析による出土アスファルトの原産地推定2019

    • Author(s)
      上條信彦、南武志、高橋和也
    • Organizer
      第36回日本文化財科学会
    • Related Report
      2019 Research-status Report
  • [Presentation] Development of ultra-trace sulfur isotope analysis and its application to mural painting vermilion2019

    • Author(s)
      Takeshi Minami, Kazuo Takahashi, Evanthia Tsantini, Miguel Ángel Cau Ontiveros
    • Organizer
      the Colloquium Spectroscopicum Internationale XLI (CSIXLI)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 超微量硫黄同位体分析法の開発と考古学資料分析への応用2018

    • Author(s)
      南 武志、高橋和也
    • Organizer
      日本文化財科学会第35回大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 伯耆国分寺古墳の赤色顔料2018

    • Author(s)
      上山晶子、南武志
    • Organizer
      シンポジウム 伯耆国分寺古墳とその時代
    • Related Report
      2018 Research-status Report
    • Invited

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Published: 2018-04-23   Modified: 2022-01-27  

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