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Development of Repeatable pH Indicator Utilizing Natural Pigment Derivatives

Research Project

Project/Area Number 18K02983
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 09080:Science education-related
Research InstitutionUniversity of Miyazaki

Principal Investigator

Arii Hidekazu  宮崎大学, 教育学部, 准教授 (80384733)

Co-Investigator(Kenkyū-buntansha) 中林 健一  宮崎大学, 教育学部, 教授 (60201670)
Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2020: ¥260,000 (Direct Cost: ¥200,000、Indirect Cost: ¥60,000)
Fiscal Year 2019: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2018: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsアントシアニン系色素 / 繰り返し利用 / pH試験剤 / フラビリウムイオン / 吸着剤
Outline of Final Research Achievements

We aimed to develop a repeatable pH indicator which is utilized readily in a laboratory for the acid-neutral-base solution of elementary and junior high school science. We synthesized the flavylium ions known as a chromophore of anthocyanin pigments in widely common plants, and investigated the inorganic materials adsorbed them. As a result of the various combination between them, the proton-form mordenite adsorbed the flavylium ion maintained the pH-dependent color change through 30 times, and few flavylium ions were liberated when the mordenite kept in solution. Consequently, we achieved the preparation of pH indicator which measures samples repeatedly and utilizes in solution.

Academic Significance and Societal Importance of the Research Achievements

繰り返し利用できるpH試験剤は、複数のサンプルを何回でも測定することが可能になる。実験は複数回実施できる方が理想的で、その過程で思考が整理され理解が深まることが期待される。本研究で開発したものはサンプルに常時浸すこともできるので、時間経過によるpH変化や容器の局所的なpH変化も観察することができ、実験の幅を広げることができる。また、開発したpH試験剤は作成過程が比較的簡便であるので、適切な指導のもとで児童・生徒が作成すれば、化学物質の特性に関心を持つ機会になることも期待している。

Report

(5 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (11 results)

All 2022 2020 2019 2018

All Journal Article (4 results) (of which Peer Reviewed: 2 results,  Open Access: 2 results) Presentation (7 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results)

  • [Journal Article] フラビリウムイオンをゼオライトに吸着させた繰り返し利用可能なpH試験剤の調製2022

    • Author(s)
      黒木千絵、有井秀和
    • Journal Title

      九州地区国立大学教育系・文系研究論文集

      Volume: 8

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 青色フラビリウムイオンの合成と無機固体材料への吸着による繰り返し利用可能なpH 試験剤への利用2022

    • Author(s)
      田中友子、黒木千絵、有井秀和
    • Journal Title

      宮崎大学教育学部紀要

      Volume: 98 Pages: 102-111

    • Related Report
      2021 Annual Research Report
  • [Journal Article] Synthesis of 1-Silabenzo[d,e]isochromanes via Electrophilic Aromatic Substitution of Aldehydes Activated by Silylium Ion2022

    • Author(s)
      Hidekazu Arii, Kenichi Nakao, Hideki Masuda, Takayuki Kawashima
    • Journal Title

      ACS Omega

      Volume: 7 Issue: 6 Pages: 5166-5175

    • DOI

      10.1021/acsomega.1c06228

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] フラビリウムイオン誘導体を無機固体材料に吸着させたpH 試験剤の合成とその性質2020

    • Author(s)
      田中友子、有井秀和
    • Journal Title

      宮崎大学教育学部紀要

      Volume: 94 Pages: 160-169

    • NAID

      120007120381

    • Related Report
      2019 Research-status Report
  • [Presentation] アントシアニン系色素を用いた複数の領域を検出する繰り返し利 用可能なpH 試験剤2020

    • Author(s)
      黒木千絵、田中友子、有井秀和
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Synthesis of Germacyclic Compounds by Intra- and Intermolecular Reactions Using In-situ Generated Germyl Cations2019

    • Author(s)
      T. Kawashima, H. Arii, Y. Iwanami, K. Mochida
    • Organizer
      International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] シリルカチオンによるアルキンの活性化を活用した含ケイ素環状化合物の合成(2): 4-ジイソプロピルシリル-1-メチル-1H-インドールを用いた反応2019

    • Author(s)
      川島隆幸、有井秀和
    • Organizer
      第46回有機典型元素化学討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] Synthesis of Silacyclic Compounds Induced by Addition of In-situ Generated Silyl Cations to Multiple Bonds2019

    • Author(s)
      T. Kawashima, H. Arii
    • Organizer
      Chemistry 2019 2nd Edition EuroSciCon Conference on Chemistry
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of Silacyclic Compounds Utilizing Cumulated Double-Bond Compounds Activated by In-situ Generated Silyl Cations2018

    • Author(s)
      T. Kawashima, H. Arii
    • Organizer
      the 15th International Symposium on Inorganic Ring Systems
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Silacyclic Compounds Utilizing Aldehydes Activated by Silyl Cations2018

    • Author(s)
      T. Kawashima, H. Arii
    • Organizer
      9th European Silicon Days
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 系中で発生させたゲルミルカチオンを用いる含ゲルマニウム環状化合物の合成2018

    • Author(s)
      川島隆幸、有井秀和、岩波彌生子、持田邦夫
    • Organizer
      第45回有機典型元素化学討論会
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2023-01-30  

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