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High-Pressure Magnetic Study of a Quasi Two-Dimensional pi-d Molecular Conductor

Research Project

Project/Area Number 18K03526
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 13030:Magnetism, superconductivity and strongly correlated systems-related
Research InstitutionShibaura Institute of Technology

Principal Investigator

Ishii Yasuyuki  芝浦工業大学, 工学部, 教授 (90391854)

Co-Investigator(Kenkyū-buntansha) 開 康一  福島県立医科大学, 医学部, 教授 (00306523)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2020: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2019: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2018: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords有機伝導体 / 金属絶縁体転移 / 磁性 / 圧力効果 / 分子性導体 / 圧力 / 超伝導
Outline of Final Research Achievements

Magnetic measurements were carried out under high-pressure up to 0.15 GPa on the molecular pi-d system, lambda-BETS2FeCl4. Below 0.04 GPa, antiferromagnetic transition temperature decreased with increasing pressure. On the other hand, above 0.04 GPa, antiferromagnetic transition temperature is almost unchanged. Assuming that most of the magnetism observed in this experiment is contributed from the d-electrons of iron, it is considered that the contribution of pi-electrons is dominant below 0.04 GPa, while the antiferromagnetic state coming from d-electrons still remains above 0.04 GPa.

Academic Significance and Societal Importance of the Research Achievements

本研究成果はπ電子とd電子が共存する強相関電子系物質において,これまでわかっていなかった金属絶縁体転移と磁気転移の機構を解明するための鍵となる成果である。社会的意義としては,金属絶縁体転移を磁場と圧力でコントロールしていることから,次世代のスイッチ素子としての応用の鍵となる可能性も内在している。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (1 results)

All 2019

All Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results)

  • [Journal Article] Magnetic Study of the Lower Critical Field of Organic Superconductor λ-(BETS)2GaCl42019

    • Author(s)
      Dita Puspita Sari*, Koichi Hiraki, Takehito Nakano, Masayuki Hagiwara, Yasuo Nozue, Takumi Kusakawa, Akiko Hori, Ayako Yamamoto, Isao Watanabe, Yasuyuki Ishii
    • Journal Title

      Materials Science Forum

      Volume: 966 Pages: 296-301

    • DOI

      10.4028/www.scientific.net/msf.966.296

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

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