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Precise synthesis of one-dimensional coordination polymers based on sequential axial coordination of dirhodium complexes

Research Project

Project/Area Number 18K05219
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 35010:Polymer chemistry-related
Research InstitutionKyushu University

Principal Investigator

Morikawa Masa-aki  九州大学, 工学研究院, 助教 (10363384)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords一次元配位高分子 / ロジウム二核錯体 / 光異性化 / 刺激応答性 / 大環状錯体 / 精密合成 / シーケンス制御 / リビング重合 / 配位高分子
Outline of Final Research Achievements

In this study, supramolecular polymers composed of dirhodium complexes and ditopic axial ligands were synthesized, into which various functional groups were introduced. Control on the monomer sequence, molecular weight, and multi-stimuli response of the coordination polymers was investigated. As a result, we succeeded in synthesizing ABAC-type one-dimensional coordination polymers that were alternately cross-linked with different axial ligands, and succeeded in constructing organized structures according to the monomer sequence. Furthermore, when ring-opening polymerization of a cyclic complex composed of dirhodium complex and ditopic ligand having an azobenzene group was attempted, a structural change from cis-cyclic 1:1 complex to trans-cyclic 2:2 complex was observed. In addition, using a dirhodium complex with oligoether side chains, we succeeded in optical control of LCST behavior, heat-set gelation, and dielectric properties of the drop cast film.

Academic Significance and Societal Importance of the Research Achievements

本研究により、一次元配位高分子における有機配位子の交互配列の方法論が確立され、その一次構造に基づいた組織構造が形成されることを明らかにした。また、環状錯体モノマーの合成と光による環構造の変化を達成したが、開環重合させるためにはより大きな配位エンタルピーが必要であることなど、分子設計指針が示された。さらに、柔軟なオリゴエーテル鎖を導入することにより、水中および固体状態において光・熱・電場など複数の刺激に応答する機能性一次元配位高分子が得られることを明らかにした。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (21 results)

All 2021 2020 2019 2018

All Journal Article (9 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 9 results,  Open Access: 1 results) Presentation (12 results)

  • [Journal Article] Photon upconverting bioplastics with high efficiency and in-air durability2021

    • Author(s)
      Bharmoria Pankaj、Hisamitsu Shota、Sasaki Yoichi、Kang Tejwant Singh、Morikawa Masa-aki、Joarder Biplab、Moth-Poulsen Kasper、Bildirir Hakan、M?rtensson Anders、Yanai Nobuhiro、Kimizuka Nobuo
    • Journal Title

      Journal of Materials Chemistry C

      Volume: Advance Article Issue: 35 Pages: 11655-11661

    • DOI

      10.1039/d1tc00287b

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Light‐Triggered, Non‐Centrosymmetric Self‐Assembly of Aqueous Arylazopyrazoles at the Air?Water Interface and Switching of Second‐Harmonic Generation2021

    • Author(s)
      Nagai Yuki、Ishiba Keita、Yamamoto Ryosuke、Yamada Teppei、Morikawa Masa‐aki、Kimizuka Nobuo
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 60 Issue: 12 Pages: 6333-6338

    • DOI

      10.1002/anie.202013650

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Liquid Arylazopyrazole Derivative as Molecular Solar Thermal Fuel with Long-term Thermal Stability2020

    • Author(s)
      Morikawa Masa-aki、Yang Hanyu、Ishiba Keita、Masutani Kouta、Hui Joseph K.-H.、Kimizuka Nobuo
    • Journal Title

      Chemistry Letters

      Volume: 49 Issue: 6 Pages: 736-740

    • DOI

      10.1246/cl.200171

    • NAID

      130007852082

    • ISSN
      0366-7022, 1348-0715
    • Year and Date
      2020-06-05
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Liquid crystalline microspheres of azobenzene amphiphiles formed by thermally induced pH changes in binary water?hydrolytic ionic liquid media2019

    • Author(s)
      Kang Tejwant Singh、Morikawa Masa-aki、Kimizuka Nobuo
    • Journal Title

      Chemical Communications

      Volume: 55 Issue: 38 Pages: 5459-5462

    • DOI

      10.1039/c9cc01731c

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Demonstration of an azobenzene derivative based solar thermal energy storage system2019

    • Author(s)
      Wang Zhihang、Losantos Raul、Sampedro Diego、Morikawa Masa-aki、Borjesson Karl、Kimizuka Nobuo、Moth-Poulsen Kasper
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 7 Issue: 25 Pages: 15042-15047

    • DOI

      10.1039/c9ta04905c

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Enhanced Electric Polarization and Polar Switching of Dipolar Aromatic Liquids Confined in Supramolecular Gel Networks2019

    • Author(s)
      Yamamoto Ryosuke、Minami Yusuke、Hui Joseph K.-H.、Morikawa Masa-aki、Kimizuka Nobuo
    • Journal Title

      Journal of the American Chemical Society

      Volume: 142 Issue: 3 Pages: 1424-1432

    • DOI

      10.1021/jacs.9b11276

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hierarchical Hybrid Metal-Organic Frameworks: Tuning the Visible/Near-Infrared Optical Properties by a Combination of Porphyrin and Its Isomer Units2019

    • Author(s)
      Y. Yang, M. Ishida, Y. Yasutake, S. Fukatsu, C. Fukakusa, M-a. Morikawa, T. Yamada, N. Kimizuka, H. Furuta
    • Journal Title

      Inorg. Chem.

      Volume: 58 Issue: 7 Pages: 4647-4656

    • DOI

      10.1021/acs.inorgchem.9b00251

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Simple and Versatile Platform for Air-Tolerant Photon Upconverting Hydrogels by Biopolymer-Surfactant-Chromophore Co-assembly2018

    • Author(s)
      P. Bharmoria, S. Hisamitsu,H. Nagatomi, T. Ogawa, M-a. Morikawa, N. Yanai, N. Kimizuka
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 140 Issue: 34 Pages: 10848-10588

    • DOI

      10.1021/jacs.8b05821

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Selective Ionic Conduction in Choline Iodide/Triiodide Solid Electrolyte and Its Application to Thermocells2018

    • Author(s)
      Shimono Tomoya、Matsuki Masaya、Yamada Teppei、Morikawa Masaaki、Yasuda Nobuhiro、Fujigaya Tsuyohiko、Kimizuka Nobuo
    • Journal Title

      Chem. Lett.

      Volume: 47 Issue: 3 Pages: 261-264

    • DOI

      10.1246/cl.171069

    • NAID

      130006434025

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 光応答性一次元ロジウム二核錯体の合成と可逆的な重合特性2021

    • Author(s)
      石原ひかり、坂田萌音、森川全章、君塚信夫
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 近赤外-可視フォトン・アップコンバージョンを示すソフトマテリアルの開発2020

    • Author(s)
      田中健太郎、佐々木陽一、森川全章、楊井伸浩、君塚信夫
    • Organizer
      第69回高分子年次学会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Crystal and electronic structures of chiral-lipid-packaged 1D halogen-bridged Pt complexes2019

    • Author(s)
      永井邑樹、松木昌也、森川全章、山田鉄兵、君塚信夫
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 水溶性ロジウム(II)二核錯体の自己組織化に基づくLSCT特性とその光制御2019

    • Author(s)
      坂田萌音、小林徹朗、森川全章、君塚信夫
    • Organizer
      第56回化学関連支部合同九州大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 光および熱応答性を示す一次元ロジウム(II)二核錯体の自己組織化と溶液特性2019

    • Author(s)
      坂田萌音、小林徹朗、森川全章、君塚信夫
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] 光異性化能を有する環状二核ロジウム(II)錯体の形成と構造制御2019

    • Author(s)
      小林徹朗、内野慎也、森川全章、君塚信夫
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] アゾベンゼン基を含む脂溶性ロジウム(II)二核錯体による環状錯体の形成と光構造制御2019

    • Author(s)
      小林徹朗,内野慎也,森川全章,君塚信夫
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Research-status Report
  • [Presentation] 光および熱刺激応答性を示す水溶性ロジウム(II)二核錯体の合成と自己集合特性2019

    • Author(s)
      坂田萌音, 小林徹朗, 森川全章, 君塚信夫
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Research-status Report
  • [Presentation] キラル脂質―MX型白金錯体複合体における一次元錯体鎖のアシンメトリ誘起と新しい電子状態の発現2019

    • Author(s)
      永井邑樹、松木昌也、森川全章、山田鉄兵、君塚信夫
    • Organizer
      第68回高分子学会年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] アゾベンゼン基を含む環状二核ロジウム(II)錯体の合成と光異性化特性2018

    • Author(s)
      小林徹朗,内野慎也,森川全章,君塚信夫
    • Organizer
      第55回化学関連支部合同九州大会
    • Related Report
      2018 Research-status Report
  • [Presentation] キラル脂質―MX型一次元白金錯体複合体における錯体鎖のアシンメトリ誘起と超分子バンドギャップ制御2018

    • Author(s)
      永井邑樹, 松木昌也, 森川全章, 山田鉄兵, 君塚信夫
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Modulation of Colloidal Behavior of Azo-Surfactants using Ionic Liquids in Aqueous Medium2018

    • Author(s)
      Tejwant Singh KANG, Masa-Aki MORIKAWA, Nobuo KIMIZUKA
    • Organizer
      第69回コロイドおよび界面化学討論会
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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