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Development of in-situ measurements and mass transfer analysis of electrode slurries during drying

Research Project

Project/Area Number 18K13702
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 19020:Thermal engineering-related
Research InstitutionOsaka University

Principal Investigator

Suzuki Takahiro  大阪大学, 工学研究科, 助教 (90711630)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2020: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2019: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2018: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords固体高分子形燃料電池 / 電極スラリー / 乾燥過程 / 物質輸送 / その場計測 / 多孔質 / 多孔質電極 / 乾燥プロセス / 粒子輸送
Outline of Final Research Achievements

In-situ measurement techniques have been developed and investigated mass transfer of materials in an electrode slurry during drying by a combination with a numerical simulation. The in-situ measurements using both a microelectrode chip and a laser measurement to find particle agglomeration and surface displacement during drying of the electrode slurry found the formation of material distribution in thickness direction during the process. Also, the numerical simulation showed the formation of material distribution which contained a high concentration of the material on the drying surface induced by solvent evaporation and a high concentration of the material on a substrate at the same time. This material distribution was strongly affected by the effective density of the material.

Academic Significance and Societal Importance of the Research Achievements

本研究では,従来ブラックボックスとして扱われてきた電極スラリーの乾燥過程における材料輸送挙動を実験と数値解析から評価することで,形成される電極の多孔質構造を推定するための技術開発を進めた.開発した方法論に基づき多孔質電極の形成プロセスの解析を進めることで,形成過程の材料輸送現象と形成される多孔質構造の関係を解明し,高性能な多孔質電極の作製条件について科学的知見に基づいて設定して形成することが可能になると期待される.

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (21 results)

All 2021 2020 2019 2018

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 3 results) Presentation (16 results) (of which Int'l Joint Research: 6 results,  Invited: 2 results)

  • [Journal Article] Simultaneous in situ measurements and numerical analysis of mass transfer in polymer electrolyte fuel cell electrode slurries during drying2021

    • Author(s)
      Takahiro Suzuki, Tatsuaki Nagai, Shohji Tsushima
    • Journal Title

      Journal of Thermal Science and Technology

      Volume: 16 Issue: 1 Pages: JTST0012-JTST0012

    • DOI

      10.1299/jtst.2021jtst0012

    • NAID

      130007965468

    • ISSN
      1880-5566
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Investigation of gas transport properties of PEMFC catalyst layers using a microfluidic device2020

    • Author(s)
      T. Suzuki, Y. Nakata, F. Tsutsui, S. Tsushima
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 167 Issue: 12 Pages: 124519-124519

    • DOI

      10.1149/1945-7111/abaf28

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Measurement and analysis of gas transport properties in catalyst layers of polymer electrolyte fuel cells with different ionomer to carbon ratio2020

    • Author(s)
      Fumiaki Tsutsui, Takahiro Suzuki, Shohji Tsushima
    • Journal Title

      ECS Transactions

      Volume: 98 Issue: 9 Pages: 49-54

    • DOI

      10.1149/09809.0049ecst

    • NAID

      130008003725

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 電池デバイスにおける究極の電極構造を目指して:固体高分子形燃料電池とレドックスフロー電池への取り組み2020

    • Author(s)
      津島将司,鈴木崇弘
    • Journal Title

      伝熱

      Volume: 59 Pages: 33-39

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of agglomeration and sedimentation of PEFC electrode slurries by a laminated microfluidic device2020

    • Author(s)
      鈴木崇弘,土井瑞樹,清水祐樹,蓼沼知秀,津島将司
    • Journal Title

      Transactions of the JSME (in Japanese)

      Volume: 86 Issue: 883 Pages: 19-00364-19-00364

    • DOI

      10.1299/transjsme.19-00364

    • NAID

      130007815916

    • ISSN
      2187-9761
    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 並行マイクロ流路間酸素透過測定と多孔質構造評価によるPEFC触媒層内ガス輸送解析2020

    • Author(s)
      筒井史朗,鈴木崇弘,津島将司
    • Organizer
      第57回日本伝熱シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] PEFC電極スラリー乾燥過程の軟X線顕微観察2020

    • Author(s)
      宮澤直之,鈴木崇弘,津島将司
    • Organizer
      第57回日本伝熱シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] アイオノマー対カーボン比の異なる固体高分子形燃料電池触媒層のガス輸送計測と解析2020

    • Author(s)
      筒井史朗,鈴木崇弘,津島将司
    • Organizer
      日本機械学会2020年度年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Rheological and impedance measurements and analysis of catalyst ink prepared by different mixing processes2020

    • Author(s)
      Takahiro Suzuki, Sakiko Kitamura, Shohji Tsushima
    • Organizer
      PRiME2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Measurement and analysis of gas transport properties in catalyst layers of polymer electrolyte fuel cell with different ionomer to carbon ratio2020

    • Author(s)
      Fumiaki Tsutsui, Takahiro Suzuki, Shohji Tsushima
    • Organizer
      PRiME2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 異なる炭素材料を含むPEFC触媒インクの乾燥過程における多孔質構造形成挙動解析2019

    • Author(s)
      鈴木崇弘,永井辰昌,津島将司
    • Organizer
      第56回日本伝熱シンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] フィルム積層型マイクロ流体デバイスを用いたPEFC電極スラリーの凝集・沈降評価2019

    • Author(s)
      鈴木崇弘,清水祐樹,土井瑞樹,津島将司
    • Organizer
      第24回動力・エネルギー技術シンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] 燃料電池電極スラリー乾燥過程の計測と解析2019

    • Author(s)
      鈴木崇弘
    • Organizer
      混相流学会若手研究者夏季セミナー2019
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] A study on rheological and dielectric properties of carbon/ionomer dispersions prepared by different mixing processes2019

    • Author(s)
      Sakiko Kitamura, Takahiro Suzuki, Shohji Tsushima
    • Organizer
      The Fifth International Symposium on Innovative Materials and Processes in Energy Systems (IMPRES2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] In-Situ Measurements and Analysis of Mass Transfer in Polymer Electrolyte Fuel Cell Electrode Slurries during Drying Process2019

    • Author(s)
      Takahiro Suzuki, Tatsuaki Nagai, Shohji Tsushima
    • Organizer
      The 2nd Pacific Rim Thermal Engineering Conference (PRTEC2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 微細加工技術を応用した燃料電池のシステムと材料に関する研究2018

    • Author(s)
      鈴木崇弘
    • Organizer
      微細加工とその応用研究シンポ
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 電気抵抗と液面変位の計測によるPEFC触媒インク乾燥挙動解析2018

    • Author(s)
      永井辰昌,鈴木崇弘,津島将司
    • Organizer
      第55回日本伝熱シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] Particle transfer and structure formation in catalyst ink during drying process2018

    • Author(s)
      Takahiro Suzuki, Shohji Tsushima
    • Organizer
      16th International Heat Transfer Conference
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Characterization of Catalyst Inks by Rheology and Microscopic Particle Properties2018

    • Author(s)
      Takahiro Suzuki, Shinya Okada, Shohji Tsushima
    • Organizer
      234th ECS Meeting
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] パルスインジェクションと乾燥雰囲気制御によるPEFC触媒層内アイオノマー分布形成2018

    • Author(s)
      入川祥伍,鈴木崇弘,津島将司
    • Organizer
      熱工学コンファレンス2018
    • Related Report
      2018 Research-status Report
  • [Presentation] 電気抵抗と液面変位の計測によるナノ粒子混合電解液の乾燥過程内部状態モニタリング2018

    • Author(s)
      永井辰昌,鈴木崇弘,津島将司
    • Organizer
      熱工学コンファレンス2018
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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