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The development of high performance carbon electrocatalyst by controlling the hierachical porous structure

Research Project

Project/Area Number 18K14047
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 27020:Chemical reaction and process system engineering-related
Research InstitutionHokkaido University

Principal Investigator

ZHU Chunyu  北海道大学, 工学研究院, 特任助教 (30749255)

Project Period (FY) 2018-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2019: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2018: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords電極触媒 / 多孔質炭素 / 酸素還元反応 / 炭素 / 多孔質 / 階層構造
Outline of Final Research Achievements

The development of low-cost and abundant carbon-based electrode materials which have high oxygen reduction electrocatalytic activity, to substitute precious metals such as platium, has received great attentions. Hierarchical porous carbon is one of the most promising candidates because of the unique structure. This study is to explore a new process for synthesize hierarchical porous carbon for electrocatalyst. In detail, an exothermic reaction that occures between the metal nitrate oxidant and organic reductant is used for the exfoliation and pyrolysis of biomass cellulose to hierarchical porous carbon.

Academic Significance and Societal Importance of the Research Achievements

本研究は再生可能なバイオマスセルロースを原料とした新規な合成手法により、安価かつ簡便で高性能な階層的多孔質炭素電極触媒を創製することである。空気極におけるPt代替酸素還元電極触媒としてバイオマス炭素系材料を使用することで、金属空気電池や燃料電池等高効率発電デバイスの本格的な普及に大きく貢献すると確信される。一方、本研究で得られる特異な炭素材料は、電極触媒の用途以外に、各種ガス吸蔵・吸着材、熱伝導・放出材、ろ過材等にも極めて有用である。

Report

(3 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • Research Products

    (14 results)

All 2019 2018

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (11 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Heteroatom-doped porous carbon with tunable pore structure and high specific surface area for high performance supercapacitors2019

    • Author(s)
      Cheong Kim; Chunyu Zhu; Yoshitaka Aoki; Hiroki Habazaki
    • Journal Title

      Electrochimica Acta

      Volume: 314 Pages: 173-187

    • DOI

      10.1016/j.electacta.2019.05.074

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exothermically Efficient Exfoliation of Biomass Cellulose to Value-Added N-Doped Hierarchical Porous Carbon for Oxygen Reduction Electrocatalyst2019

    • Author(s)
      Kim, Cheong Zhu, Chunyu Aoki, Yoshitaka Habazaki, Hiroki
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 58 Issue: 8 Pages: 3047-3059

    • DOI

      10.1021/acs.iecr.8b06410

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Nitrogen-doped porous carbon as-mediated by a facile solution combustion synthesis for supercapacitor and oxygen reduction electrocatalyst2018

    • Author(s)
      Zhu, Chunyu Takata, Manami Aoki, Yoshitaka Habazaki, Hiroki
    • Journal Title

      Chemical Engineering Journal

      Volume: 350 Pages: 278-289

    • DOI

      10.1016/j.cej.2018.06.001

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] Preparation of N-doped porous carbon with adjustable pore size for supercapacitors2019

    • Author(s)
      C. Kim, C. Zhu, Y. Aoki, H. Habazaki
    • Organizer
      電気化学会第86回大会,3月27-29日,京都大学,京都
    • Related Report
      2019 Annual Research Report
  • [Presentation] 多孔質炭素の階層的細孔構造の制御とその酸素還元特性2019

    • Author(s)
      高田 愛実,朱 春宇,青木 芳尚,幅崎 浩樹
    • Organizer
      電気化学会第86回大会,3月27-29日,京都大学,京都
    • Related Report
      2019 Annual Research Report
  • [Presentation] 硝酸塩補助燃焼合成による階層的多孔質炭素の合成と電極特性2019

    • Author(s)
      高田 愛実,朱 春宇,青木 芳尚,幅崎 浩樹
    • Organizer
      第4回材料WEEK 材料シンポジウム,10月15-16日,京都テルサ,京都(2019)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 階層的な多孔質構造をもつ窒素ドープ炭素の作製とそのスーパーキャパシタ電極特性2018

    • Author(s)
      高田 愛実,金 淸,朱 春宇,青木 芳尚,幅崎 浩樹
    • Organizer
      化学系学協会北海道支部2018年冬季研究発表会
    • Related Report
      2018 Research-status Report
  • [Presentation] Facile synthesis of N-doped porous carbon as efficient metal-free electrocatalyst for oxygen reduction reaction2018

    • Author(s)
      C. Kim, C. Zhu, Y. Aoki, and H. Habazaki
    • Organizer
      化学系学協会北海道支部2018年冬季研究発表会
    • Related Report
      2018 Research-status Report
  • [Presentation] Exothermic reaction promoted production of hierarchical porous carbon for electrochemical energy storage and conversion2018

    • Author(s)
      C. Zhu, M. Takata, C. Kim, J. Cao, Y. Aoki, H. Habazaki
    • Organizer
      22nd Topical Meeting of ISE, 15-18 April, Waseda University, Tokyo
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Nitrogen-Doped Carbon with Hierarchical Porous Structure as Electrocatalyst for Oxygen Reduction Reaction2018

    • Author(s)
      M. Takata, C. Kim, C. Zhu, Y. Aoki, and H. Habazaki
    • Organizer
      22nd Topical Meeting of ISE, 15-18 April, Waseda University, Tokyo
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Nitrogen-containing porous carbon electrocatalyst for efficient oxygen reduction reaction2018

    • Author(s)
      C. Kim, C. Zhu, Y. Aoki, and H. Habazaki
    • Organizer
      22nd Topical Meeting of ISE, 15-18 April, Waseda University, Tokyo
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Hierarchically porous N-doped carbon for electrocatalysts of Zinc-air batteries2018

    • Author(s)
      C. Kim, C. Zhu, Y. Aoki, H. Habazaki
    • Organizer
      ECSJ Fall Meeting 2018
    • Related Report
      2018 Research-status Report
  • [Presentation] Novel exothermic synthesis of N-doped porous carbon as efficient electrocatalyst for oxygen reduction reaction2018

    • Author(s)
      金 淸,朱 春宇,青木 芳尚,幅崎 浩樹
    • Organizer
      第34回ライラックセミナー・第24回若手研究者交流会
    • Related Report
      2018 Research-status Report
  • [Presentation] 酸素還元触媒用窒素ドープ多孔質炭素の作製2018

    • Author(s)
      高田 愛実,朱 春宇,青木 芳尚,幅崎 浩樹
    • Organizer
      第34回ライラックセミナー・第24回若手研究者交流会
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2021-02-19  

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