Synthesis and anatiaromatic character of a dianionic ccompound bearing a heavier group 14 element
| Project/Area Number |
18K14203
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| Research Category |
Grant-in-Aid for Early-Career Scientists
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| Allocation Type | Multi-year Fund |
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| Review Section |
Basic Section 33010:Structural organic chemistry and physical organic chemistry-related
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| Research Institution | Chuo University |
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Principal Investigator |
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| Project Period (FY) |
2018-04-01 – 2020-03-31
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| Project Status |
Completed (Fiscal Year 2019)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2018: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | 反芳香族性 / 非芳香族性 / 高周期14族元素 / ジアニオン / 芳香族性 / スズ / π共役系 / ヘテロサイクル / 低配位化学種 |
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| Outline of Final Research Achievements |
We synthesized a tin analogue of cycloheptatrienyl anion from the reduction of the corresponding diphenyl derivative with lithium under low temperatures. A lithium salt of diphenylstannepinyl anion has been successfully isolated and characterized by NMR and X-ray diffraction studies, which indicates its non-aromatic character. In contrast, a similar reaction with a longer reaction time resulted in the formation of a further reduced species, dilithiostannepin, the formation of which was confirmed by a quenching reaction using iodomethane. Although isolation of this compound is unsuccessful so far due to its thermal instability, our theoretical studies indicate its global antiaromatic nature.
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| Academic Significance and Societal Importance of the Research Achievements |
本研究では、スズのジアニオン種という高周期元素の特異な電子状態を組み込んだ新たな反芳香族化合物の合成に成功した。本成果は、既存の反芳香族化合物が炭素や窒素などの第二周期の元素で構成される、という一般常識を覆し、スズのような第５周期の元素をもつ4nπ電子系化合物でも反芳香族化合物が発現する、ということを見いだした、基礎化学的に重要な成果である。
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Report
(3 results)
Research Products
(13 results)
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[Journal Article] Ruthenium Vinylidene Complexes Generated by Selective 1,2-Migration of P- and S- Substituents: Synthesis, Structures, and Dichromism Arising from an Intermolecular CH…O Hydrogen Bond2020
Author(s)
Takuya Kuwabara, Yutaka Aoki, Kousuke Sakajiri, Kazuki Deguchi, ShuheiTakamori, Ai Hamano, Keiko Takano, Hirohiko Houjou and Youichi Ishii
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Journal Title
Organometallics
Volume: 39
Issue: 5
Pages: 711-718
DOI
Related Report
Peer Reviewed
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