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Development of lithium superionic conducting oxide-based solid electrolytes with low melting point and their application to all-solid-state batteries

Research Project

Project/Area Number 18K14318
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 36020:Energy-related chemistry
Research InstitutionNagoya University

Principal Investigator

Yamamoto Takayuki  名古屋大学, 工学研究科, 助教 (50810884)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2020: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2019: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2018: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords固体電解質 / イオン伝導 / 全固体電池
Outline of Final Research Achievements

In this research, solid electrolytes for all-solid-state lithium secondary batteries were investigated. A novel synthetic method of anti-perovskite-type solid electrolyte Li2OHBr and related materials was developed, and their fundamental properties, typically ionic conductivity, were investigated. Furthermore, all-solid-state lithium secondary battery with Li2OHBr was fabricated, and high charge/discharge cycle stability was achieved. This results contribute realization of all-solid-state batteries with high cycle stability.

Academic Significance and Societal Importance of the Research Achievements

2050年にカーボンニュートラル社会を実現するためには、電気自動車の本格普及が大きな柱となる。現行のリチウムイオン電池では走行距離、充電時間ともにガソリン車に劣っており、高エネルギー密度、高出入力特性、高安全、長寿命な次世代電池の実現が望まれる。次世代電池として全固体リチウム二次電池が期待されており、全固体電池の実現に向けては中心材料である固体電解質の開発が不可欠である。本研究では固体電解質Li2OHBrとその周辺物質を調べ、新規固体電解質材料の設計指針を示した。また、Li2OHBrを用いて全固体電池を構築し、長寿命な全固体電池の実現可能性を示した。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (13 results)

All 2021 2020 2019

All Journal Article (4 results) (of which Peer Reviewed: 3 results) Presentation (9 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] アンチペロブスカイト型結晶構造を有する低融点固体電解質の研究開発2021

    • Author(s)
      山本貴之、本山宗主、入山恭寿
    • Journal Title

      車載テクノロジー

      Volume: 8 Pages: 55-60

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Room Temperature Synthesis of Anti-Perovskite Structured Li2OHBr2020

    • Author(s)
      M. K. Sugumar, T. Yamamoto, M. Motoyama, and Y. Iriyama
    • Journal Title

      Solid State Ionics

      Volume: 349 Pages: 115298-115298

    • DOI

      10.1016/j.ssi.2020.115298

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of the Metastable Cubic Phase of Li2OHCl by a Mechanochemical Method2020

    • Author(s)
      T. Yamamoto, H. Shiba, N. Mitsukuchi, M. K. Sugumar, M. Motoyama, and Y. Iriyama
    • Journal Title

      Inorg. Chem.

      Volume: 59 Issue: 17 Pages: 11901-11904

    • DOI

      10.1021/acs.inorgchem.0c01631

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tailoring the Lithium-Ion Conductivity of Li2OHBr by Substitution of Bromine with Other Halogens2020

    • Author(s)
      M. K. Sugumar, T. Yamamoto, M. Motoyama, and Y. Iriyama
    • Journal Title

      Chem. Lett.

      Volume: 50 Issue: 3 Pages: 448-451

    • DOI

      10.1246/cl.200778

    • NAID

      130007995513

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Presentation] アンチペロブスカイト型構造を有する固体電解質Li2OHBrのメカノケミカル合成、及び全固体リチウム電池への応用2020

    • Author(s)
      吉川慶佑, M. K. Sugumar,山本貴之,池田一貴,本山宗主,入山恭寿
    • Organizer
      第46回固体イオニクス討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] アンチペロブスカイト型固体電解質Li2OHBrのメカノケミカル合成と全固体リチウム電池への応用2020

    • Author(s)
      吉川慶佑, M. K. Sugumar,山本貴之,池田一貴,本山宗主,入山恭寿
    • Organizer
      2020年度ヤングエレクトロケミスト研究会・光電気化学研究会
    • Related Report
      2020 Annual Research Report
  • [Presentation] アンチペロブスカイト型構造を有する固体電解質Li2OHBrのメカノケミカル合成と全固体リチウム電池への応用2020

    • Author(s)
      吉川慶佑, M. K. Sugumar,山本貴之,池田一貴,本山 宗主,入山恭寿
    • Organizer
      第61回電池討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Mechanochemical Synthesis of Modified Li2OHBr to Improve Ionic Conductivity2020

    • Author(s)
      M. K. Sugumar, T. Yamamoto, K. Ikeda, M. Motoyama, Y. Iriyama
    • Organizer
      PRiME2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mechanochemical Synthesis of Modified Li2OHBr to Improve Ionic Conductivity2020

    • Author(s)
      M. K. Sugumar, T. Yamamoto, M. Motoyama, Y. Iriyama
    • Organizer
      日本セラミックス協会第33回秋季シンポジウム
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mechanochemical synthesis of lithium-ion conducting solid electrolytes Li2OHX (X=Cl,Br) with anti-perovskite structure2020

    • Author(s)
      Takayuki Yamamoto, Manoj Krishna Sugumar, Hinata Shiba, Naohiro Mitsukuchi, Munekazu Motoyama, Yasutoshi Iriyama
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Room Temperature Synthesis of Anti-Perovskite Structured Li+-conductive Solid Electrolyte2020

    • Author(s)
      Manoj Krishna Sugumar, Kota Urabe, Takayuki Yamamoto, Munekazu Motoyama, Yasutoshi Iriyama
    • Organizer
      電気化学会第87回大会
    • Related Report
      2019 Research-status Report
  • [Presentation] Novel approach on room temperature synthesis of anti-perovskite structured Li2OHBr2019

    • Author(s)
      Manoj Krishna Sugumar, Takayuki Yamamoto, Munekazu Motoyama, Yasutoshi Iriyama
    • Organizer
      2nd World Conference on Solid Electrolytes for Advanced Applications
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Li+伝導性低融点酸臭化物系固体電解質の合成と基礎物性の調査2019

    • Author(s)
      浦部晃太,吉川慶佑,山本貴之,本山宗主,入山恭寿
    • Organizer
      2019年度電気化学会関西支部・東海支部合同シンポジウム
    • Related Report
      2019 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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