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Synthesis of graphite anodes for flexible all-solid-state thin-film rechargeable batteries

Research Project

Project/Area Number 18K18844
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Review Section Medium-sized Section 21:Electrical and electronic engineering and related fields
Research InstitutionUniversity of Tsukuba

Principal Investigator

Toko Kaoru  筑波大学, 数理物質系, 准教授 (30611280)

Project Period (FY) 2018-06-29 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2020: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2019: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2018: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords二次電池 / 多層グラフェン / 結晶成長 / グラファイト薄膜 / 二次電池負極
Outline of Final Research Achievements

The flexible all-solid-state thin-film rechargeable battery is light and soft, and thereby, can be installed anywhere. Moreover, the battery performance can be improved easily by stacking. Therefore, this will be the best form of rechargeable battery. In this study, by using the "layer exchange phenomenon" between carbon and metal thin films, which was found by the principal investigator, the synthesis of graphite thin films below the heat-resistant temperature of plastic substrates and their anode operation for lithium-ion batteries were demonstrated. In addition to completing the original research plan, the anode performance exceeded the target values.

Academic Significance and Societal Importance of the Research Achievements

電気自動車や携帯機器のバッテリーの革新を目指し、二次電池の全固体化・薄膜化の研究が活発化している。本研究は、従来電池として実績のある炭素負極を用いたフレキシブル二次電池の実現につながる成果である。また、「層交換」は、従来の多層グラフェンの合成技術とは異なるメカニズムに基づいた合成法であり、特に多層グラフェンの膜厚を広いレンジで制御できる点はユニークである。今後、様々な分野への応用が期待される。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (26 results)

All 2021 2020 2019 2018

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Open Access: 3 results) Presentation (17 results) (of which Int'l Joint Research: 11 results,  Invited: 4 results) Book (1 results)

  • [Journal Article] Multilayer Graphene Battery Anodes on Plastic Sheets for Flexible Electronics2020

    • Author(s)
      Murata Hiromasa、Nakajima Yoshiki、Kado Yuya、Saitoh Noriyuki、Yoshizawa Noriko、Suemasu Takashi、Toko Kaoru
    • Journal Title

      ACS Applied Energy Materials

      Volume: 3 Issue: 9 Pages: 8410-8414

    • DOI

      10.1021/acsaem.0c01030

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Impact of the carbon membrane inserted below Ni in the layer exchange of multilayer graphene2020

    • Author(s)
      Murata H.、Saitoh N.、Yoshizawa N.、Suemasu T.、Toko K.
    • Journal Title

      CrystEngComm

      Volume: 22 Issue: 18 Pages: 3106-3109

    • DOI

      10.1039/d0ce00394h

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 350 °C synthesis of high-quality multilayer graphene on an insulator using Ni-induced layer exchange2020

    • Author(s)
      Murata Hiromasa、Nozawa Koki、Saitoh Noriyuki、Yoshizawa Noriko、Suemasu Takashi、Toko Kaoru
    • Journal Title

      Applied Physics Express

      Volume: 13 Issue: 5 Pages: 055502-055502

    • DOI

      10.35848/1882-0786/ab839d

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fe-Induced Layer Exchange of Multilayer Graphene for Rechargeable Battery Anodes2020

    • Author(s)
      Y. Nakajima, H. Murata, N. Saitoh, N. Yoshizawa, T. Suemasu, and K. Toko
    • Journal Title

      Applied Physics Express

      Volume: 13 Issue: 2 Pages: 25501-25501

    • DOI

      10.7567/1882-0786/ab5e3a

    • NAID

      120007127619

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Impact of Amorphous-C/Ni Multilayers on Ni-Induced Layer Exchange for Multilayer Graphene on Insulatores2019

    • Author(s)
      H. Murata, N. Saitoh, N. Yoshizawa, T. Suemasu, and K. Toko
    • Journal Title

      ACS Omega

      Volume: 4 Issue: 10 Pages: 14251-14251

    • DOI

      10.1021/acsomega.9b01708

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Low-Temperature (400 °C) Synthesis of Multilayer Graphene by Metal-Assisted Sputtering Deposition2019

    • Author(s)
      Y. Nakajima, H. Murata, N. Saitoh, N. Yoshizawa, T. Suemasu, and K. Toko
    • Journal Title

      ACS Omega

      Volume: 4 Issue: 4 Pages: 6677-6677

    • DOI

      10.1021/acsomega.9b00420

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] High-Electrical-Conductivity Multilayer Graphene Formed by Layer Exchange with Controlled Thickness and Interlayer2019

    • Author(s)
      H. Murata, Y. Nakajima, N. Saitoh, N. Yoshizawa, T. Suemasu, and K. Toko
    • Journal Title

      Scientific Reports

      Volume: 9 Issue: 1 Pages: 1-5

    • DOI

      10.1038/s41598-019-40547-0

    • NAID

      120007128094

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Metal Catalysts for Layer Exchange Growth of Multilayer Graphene2018

    • Author(s)
      Y. Nakajima, H. Murata, N. Saitoh, N. Yoshizawa, T. Sueamsu, and K. Toko
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 10 Issue: 48 Pages: 41664-41669

    • DOI

      10.1021/acsami.8b14960

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Presentation] 層交換多層グラフェンの二次電池特性における合成温度効果2021

    • Author(s)
      鈴木大成, 村田博雅, 加登裕也, 吉澤徳子, 末益崇, 都甲薫
    • Organizer
      第68回応用物理学会春季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Ni-Induced Layer Exchange of Multilayer Graphene on Plastic Substrate for Flexible Rechargeable Battery Anode2020

    • Author(s)
      Hiromasa Murata, Takashi Suemasu, Kaoru Toko
    • Organizer
      2020 International Conference on Solid State Devices and Materials
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 多層グラフェンの層交換合成と二次電池応用2020

    • Author(s)
      村田 博雅, 中島 義基, 加登 裕也, 吉澤 徳子, 末益 崇, 都甲 薫
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] 金属誘起層交換合成によるグラファイト薄膜の合成と薄膜二次電池応用2019

    • Author(s)
      村田 博雅,中島 義基, 加登 裕也, 吉澤 徳子, 末益 崇, 都甲 薫
    • Organizer
      第46回炭素材料学会年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 多層グラフェンの金属誘起層交換合成と薄膜二次電池応用?2019

    • Author(s)
      中島 義基, 村田 博雅, 加登 裕也, 吉澤 徳子, 松村 亮, 深田 直樹, 末益 崇, 都甲 薫
    • Organizer
      第80回応用物理学会秋季学術講演会?
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Multilayer graphene: Layer-exchange synthesis of multilayer graphene for flexible carbon electronics2019

    • Author(s)
      Hiromasa Murata, Takashi Suemasu, Kaoru Toko
    • Organizer
      2019 European Materials Research Society (E-MRS) Fall Meeting
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] High-quality multilayer graphene formed by thickness-controlled metal-induced layer exchange2019

    • Author(s)
      Hiromasa Murata, Takashi Suemasu, Kaoru Toko
    • Organizer
      2019 European Materials Research Society (E-MRS) Fall Meeting
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Comprehensive study of metal-induced layer-exchange for high-quality multilayer graphene2019

    • Author(s)
      Hiromasa Murata, Yoshiki Nakajima, Takashi Suemasu, Kaoru Toko
    • Organizer
      2019 International Conference on Solid State Devices and Materials (SSDM 2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Improving Crystal and Electrical Properties of Multilayer Graphene on Insulator formed by Ni-Induced Layer Exchange2019

    • Author(s)
      H. Murata, Y. Nakajima, T. Suemasu, and K. Toko
    • Organizer
      The 5th Asia-Pacific Conference on Semiconducting Silicides and Related Materials,
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Transfer Free Synthesis of Multilayer Graphene on Insulator: Comprehensive Study of Carbon/metal Solid-phase Reaction2019

    • Author(s)
      Y. Nakajima, H. Murata, T. Suemasu, and K. Toko
    • Organizer
      The 5th Asia-Pacific Conference on Semiconducting Silicides and Related Materials,
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Expansion of Solid-phase Interactions between Carbon and Metals: Layer Exchange for Multilayer Graphene on Insulator2019

    • Author(s)
      Y. Nakajima, H. Murata, T. Suemasu, and K. Toko
    • Organizer
      Compound Semiconductor Week 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Low-temperature synthesis of group IV semiconductors on insulators2019

    • Author(s)
      K. Toko and T. Suemasu,
    • Organizer
      MRS Spring Meeting
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 多層グラフェンの合成に向けた炭素/金属固相反応の包括的研究2019

    • Author(s)
      中島 義基, 村田 博雅, 末益 崇, 都甲 薫
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 層交換の新展開:多層グラフェンのFe誘起成長2018

    • Author(s)
      中島 義基, 村田 博雅, 末益 崇, 都甲 薫
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] Guidelines for metal selection to induce layer exchange growth of multilayer graphene2018

    • Author(s)
      Hiromasa Murata, Yoshiki Nakajima, Takashi Suemasu, Kaoru Toko
    • Organizer
      2018 European Materials Research Society (E-MRS) Fall Meeting
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Low-temperature synthesis of multilayer graphene on glass by Ni-induced layer exchange2018

    • Author(s)
      Hiromasa Murata, Takashi Suemasu, Kaoru Toko
    • Organizer
      2018 European Materials Research Society (E-MRS) Fall Meeting
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Metal-induced Layer Exchange for Multilayer Graphene on Insulator: Effects of Metal Species2018

    • Author(s)
      Yoshiki Nakajima, Hiromasa Murata, Takashi Suemasu, Kaoru Toko
    • Organizer
      2018 International Conference on Solid State Devices and Materials (SSDM 2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Book] リチウムイオン二次電池用炭素系負極材の開発動向「全固体二次電池負極に向けた多層グラフェンの新規合成技術」2019

    • Author(s)
      都甲薫
    • Total Pages
      8
    • Publisher
      シーエムシー出版
    • ISBN
      9784781314358
    • Related Report
      2019 Research-status Report

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Published: 2018-07-25   Modified: 2022-01-27  

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