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Deformation, shape memory and superelastic effects of high entropy alloy single crystals based on cocktail effect

Research Project

Project/Area Number 18K18949
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Review Section Medium-sized Section 26:Materials engineering and related fields
Research InstitutionOsaka University

Principal Investigator

Yasuda Hiroyuki  大阪大学, 工学研究科, 教授 (60294021)

Co-Investigator(Kenkyū-buntansha) 趙 研  大阪大学, 工学研究科, 講師 (00633661)
Project Period (FY) 2018-06-29 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2019: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2018: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsハイエントロピー合金 / カクテル効果 / 形状記憶合金 / 超弾性
Outline of Final Research Achievements

Single crystalline specimens of bcc-HfNbTaTiZr high entropy alloys can be obtained from the coarse grains and the deformation behavior was investigated. As a result, the single crystals exhibit a high yield strength around 1000MPa at room temperature. It is also noted that high strength can also be obtained at 600℃ due to the precipitation of the hcp phase. The deformation behavior of non-equiatomic (TiZrHf)100-x(NbTa)x and V-doped alloys was also examined. The phase constituent and phase transformation of the non-equiatomic alloys are found to be similar to those of Ti-based and Zr-based alloys. However, at present, elastic anomaly, shape memory effect and superelasticity which are typical in β-Ti alloys cannot be observed.

Academic Significance and Societal Importance of the Research Achievements

申請者の知る限り、HfNbTaTiZrハイエントロピー合金のバルク単結晶を用いて、その変形挙動に関する研究を行ったのは、申請者らが世界で初めてである。さらに、HfNbTaTiZr合金を初めとするbccハイエントロピー合金をβチタン合金に見立てて、構成元素を(TiZrHf)と(NbTa)とに分けて考え、形状記憶・超弾性合金としての可能性を探るアイディアは、申請者が世界で最初に提案したものである。学会発表などを通じて、こうしたアイディアが広まり、新しい研究開発の潮流が生まれている。

Report

(3 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • Research Products

    (1 results)

All 2018

All Presentation (1 results)

  • [Presentation] HfNbTaTiZr 合金の相変態挙動および力学特性に及ぼすβ安定化元素の影響2018

    • Author(s)
      山田祐介、趙研、永瀬丈嗣、安田弘行
    • Organizer
      日本金属学会2018年秋期大会
    • Related Report
      2018 Research-status Report

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Published: 2018-07-25   Modified: 2021-02-19  

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