Development of operando electrochemical CT-XAFS technique and its application for theree dimentional analysis of reaction distrituion in secondary batteries
| Project/Area Number |
18K19123
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| Research Category |
Grant-in-Aid for Challenging Research (Exploratory)
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| Allocation Type | Multi-year Fund |
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| Review Section |
Medium-sized Section 36:Inorganic materials chemistry, energy-related chemistry, and related fields
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| Research Institution | Tohoku University |
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Principal Investigator |
Amezawa Koji 東北大学, 多元物質科学研究所, 教授 (90263136)
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| Project Period (FY) |
2018-06-29 – 2020-03-31
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| Project Status |
Completed (Fiscal Year 2019)
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| Budget Amount *help |
¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2019: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2018: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
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| Keywords | CT-XAFS / オペランド / 蓄電池 / コンピュータ断層撮影法 / X線吸収微細構造 / 反応分布 / 放射光 |
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| Outline of Final Research Achievements |
In this work, we succeeded to develop "operando electrochemical CT-XAFS (computed tomography X-ray absorption fine structure) technique", which enables to 3-dimensionally investigate the reaction and its propagation in battery electrode under operation. This technique was applied to investigate the distribution of charge-discharge reactions in a composite cathode for all-solid-state lithium ion secondary battery in real time. This was the first report to experimentally evaluate the 3-dimensional reaction distribution and its temporal change in a practical battery electrode, and therefore the validity of the methodology was confirmed.
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| Academic Significance and Societal Importance of the Research Achievements |
本研究で開発された「オペランド電気化学CT-XAFS法」は，実用に近いリチウムイオン二次電池電極における反応の分布およびその進展を，三次元かつ非接触・非破壊で評価できる，現状では唯一の新規計測手法である。これにより，これまでブラックボックスであった蓄電池内の反応をリアルタイムで追跡することが初めて可能となり，憶測に頼るしかなかった電極設計・開発指針を大きく転換させることができる。さらに同手法は，他のさまざまな電気化学デバイスへの適用も可能な，有用性と汎用性を兼ね備えた反応評価手法であり，今後のさらなる展開・発展も期待される。
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Report
(3 results)
Research Products
(19 results)
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[Journal Article] 3D Operando Imaging and Quantification of Inhomogeneous Electrochemical Reactions in Composite Battery Electrodes2020
Author(s)
Yuta Kimura, Aina Tomura, Mahunnop Fakkao, Takashi Nakamura, Nozomu Ishiguro, Oki Sekizawa, Kiyofumi Nitta, Tomoya Uruga, Toyoki Okumura, Mizuki Tada, Yoshiharu Uchimoto, Koji Amezawa
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Journal Title
J. Phys. Chem. Lett.
Volume: 11
Issue: 9
Pages: 3629-3636
DOI
Related Report
Peer Reviewed
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[Presentation] Operando Observation of Reaction Distribution in All-Solid-State Lithium Ion Battery Cathode by Using CT-XAFS2019
Author(s)
Koji Amezawa, Yuta Kimura, Mahunnop Fakkao, Aina Tomura, Takashi Nakamura, Toyoki Okumura, Oki Sekizawa, Kiyofumi Nitta, Nozomu Ishiguro, Mitsuki Tada, Yoshiharu Uchimoto
Organizer
2nd World Conference on Solid Electrolytes for Advanced Applications: Garnets and Competitors
Related Report
Int'l Joint Research / Invited
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[Presentation] Investigation of the Mechanism of the Reaction Distribution Formation in a Composite Positive Electrode for Bulk-Type All-Solid-State Lithium-Ion Batteries by Using Operando CT-XAFS2019
Author(s)
Yuta Kimura, Mahunnop Fakkao, Aina Tomura, Takashi Nakamura, Nozomu Ishiguro, Oki Sekizawa, Kiyofumi Nitta, Tomoya Uruga, Toyoki Okumura, Mitsuki Tada, Yoshiharu Uchimoto, Koji Amezawa
Organizer
22nd International Conference on Solid State Ionics
Related Report
Int'l Joint Research
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[Presentation] Operando Visualization of Reaction Distribution in a Composite Electrode for Bulk-Type All-Solid-State Lithium-Ion Batteries by Using CT-XAFS2019
Author(s)
Aina Tomura, Yuta Kimura, Mahunnop Fakkao, Takashi Nakamura, Nozomu Ishiguro, Oki Sekizawa, Kiyofumi Nitta, Tomoya Uruga, Toyoki Okumura, Mitsuki Tada, Yoshiharu Uchimoto, Koji Amezawa
Organizer
9th Lithium Battery Discussions
Related Report
Int'l Joint Research
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