Project/Area Number |
19205027
|
Research Category |
Grant-in-Aid for Scientific Research (A)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic industrial materials
|
Research Institution | Tokyo Institute of Technology |
Principal Investigator |
YAMADA Atsuo Tokyo Institute of Technology, 大学院・工学系研究科, 教授 (30359690)
|
Co-Investigator(Kenkyū-buntansha) |
NISHIMURA Shinichi 東京大学, 大学院・工学系研究科, 主任研究員 (00549264)
菅野 了次 東京工業大学, 大学院・総合理工学研究科, 教授 (90135426)
八島 正知 東京工業大学, 大学院・総合理工学研究科, 准教授 (00239740)
関 志朗 (財)電力中央研究所, 材料科学研究所, 研究員 (70371325)
|
Co-Investigator(Renkei-kenkyūsha) |
SHIRO Seki 電力中央研究所, 材料化学研究所, 主任研究員 (70371325)
YASHIMA Masatomo 東京大学, 大学院・理工学研究科, 教授 (00239740)
KANNO Ryoji 東京工業大学, 大学院・総合理工学研究, 教授 (90135426)
|
Project Period (FY) |
2007 – 2010
|
Project Status |
Completed (Fiscal Year 2010)
|
Budget Amount *help |
¥50,830,000 (Direct Cost: ¥39,100,000、Indirect Cost: ¥11,730,000)
Fiscal Year 2010: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2009: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2008: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000)
Fiscal Year 2007: ¥27,170,000 (Direct Cost: ¥20,900,000、Indirect Cost: ¥6,270,000)
|
Keywords | リチウム電池 / 正極 / 拡散 / 相分離 / 局在電子 / 核生成 / 結晶成長 / オリビン / 鉄 / マンガン |
Research Abstract |
We have focused on the electrode function of insulating materials which had been believed inactive. Some compounds with high activity were discovered during the project, of which structure was also determined. Atomic-scale anisotropic lithium diffusion and subsequent clustering, together with their kinetics, were experimentally elucidated. Thermodynamic approach was made to understand the size-dependency of these phenomena.
|