Development of novel molecular films based on self-assembly of coordination compounds
| Project/Area Number |
19205030
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer/Textile materials
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| Research Institution | Kyushu University |
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Principal Investigator |
KIMIZUKA Nobuo Kyushu University, 大学院・工学研究院, 教授 (90186304)
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| Co-Investigator(Kenkyū-buntansha) |
森川 全章 九州大学, 大学院・工学研究院, 助教 (10363384)
黒岩 敬太 九州大学, 大学院・工学研究院, 助教 (70336006)
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| Co-Investigator(Renkei-kenkyūsha) |
KUROIWA Keita 九州大学, 大学院・工学研究院, 助教 (70336006)
MORIKAWA Masa-aki 九州大学, 大学院・工学研究院, 助教 (10363384)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥52,260,000 (Direct Cost: ¥40,200,000、Indirect Cost: ¥12,060,000)
Fiscal Year 2009: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2008: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Fiscal Year 2007: ¥37,440,000 (Direct Cost: ¥28,800,000、Indirect Cost: ¥8,640,000)
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| Keywords | ナノ金属錯体 / トリアゾール / 自己組織化 / 一次元金属錯体 / 混合原子価 / 強誘電性 / スピン転移 / ラメラフィルム / 原子間力顕微鏡 / 分子組織化 / 電気力顕微鏡 / 一次元錯体 / 鉄イオン / 円偏光二色性 / 疎媒性収縮 |
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| Research Abstract |
We developed the lipid packageing technique to 1D Fe^<11> 1,2,4-triazole complexes. Surprisingly, the complex leads to the stabilization of low spin (LS) complexes in organic media and consequent control of spin conversion via dynamic self-assembly of linear coordination chain. Therefore, supramolercular control of coordination polymer or introduction of dynamic self-assembly are of great value to optimize the spin state in organic media.
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Report
(4 results)
Research Products
(104 results)
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[Journal Article] Nanoparticles of Adaptive Supramolecular Networks Self-Assembled from Nucleotides and Lanthanide Ions2009
Author(s)
Ryuhei Nishiyabu, Nozomi Hashimoto, Ten Cho, Kazuto Watanabe, Takefumi Yasunaga, Ayataka Endo, Kenji Kaneko, Takuro Niidome, Masaharu Murata, Chihaya Adachi, Yoshiki Katayama, Makoto Hashizume, Nobuo Kimizuka
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Journal Title
J. Am. Chem. Soc 131
Pages: 2151-2158
Related Report
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[Journal Article] Nanoparticles of Adaptive Supramolecular Networks Self-Assembled from Nucleotides and Lanthanide Ions2009
Author(s)
R. Nishiyabu, N. Hashimoto, T. Cho, K. Watanabe, T. Yasunaga, A. Endo, K. Kaneko, T. Niidome, M. Murata, C. Adachi, Y. Katayama, M. Hashizume, N. Kimizuka
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Journal Title
J. Am. Chem. Soc 131
Pages: 2151-2158
Related Report
Peer Reviewed
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