| Project/Area Number |
19205030
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer/Textile materials
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| Research Institution | Kyushu University |
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Principal Investigator |
KIMIZUKA Nobuo Kyushu University, 大学院・工学研究院, 教授 (90186304)
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| Co-Investigator(Kenkyū-buntansha) |
森川 全章 九州大学, 大学院・工学研究院, 助教 (10363384)
黒岩 敬太 九州大学, 大学院・工学研究院, 助教 (70336006)
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| Co-Investigator(Renkei-kenkyūsha) |
KUROIWA Keita 九州大学, 大学院・工学研究院, 助教 (70336006)
MORIKAWA Masa-aki 九州大学, 大学院・工学研究院, 助教 (10363384)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥52,260,000 (Direct Cost: ¥40,200,000、Indirect Cost: ¥12,060,000)
Fiscal Year 2009: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2008: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Fiscal Year 2007: ¥37,440,000 (Direct Cost: ¥28,800,000、Indirect Cost: ¥8,640,000)
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| Keywords | ナノ金属錯体 / トリアゾール / 自己組織化 / 一次元金属錯体 / 混合原子価 / 強誘電性 / スピン転移 / ラメラフィルム / 原子間力顕微鏡 / 分子組織化 / 電気力顕微鏡 / 一次元錯体 / 鉄イオン / 円偏光二色性 / 疎媒性収縮 |
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| Research Abstract |
We developed the lipid packageing technique to 1D Fe^<11> 1,2,4-triazole complexes. Surprisingly, the complex leads to the stabilization of low spin (LS) complexes in organic media and consequent control of spin conversion via dynamic self-assembly of linear coordination chain. Therefore, supramolercular control of coordination polymer or introduction of dynamic self-assembly are of great value to optimize the spin state in organic media.
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