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Preparation of High-Performance Green Nanohybrids through Precise Interface Control

Research Project

Project/Area Number 19205031
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionKyushu University

Principal Investigator

ATSUSHI Takahara (TAKAHARA Atsushi)  Kyushu University, 先導物質化学研究所, 教授 (20163305)

Co-Investigator(Kenkyū-buntansha) OTSUKA Hideyuki  九州大学, 先導物質化学研究所, 准教授 (00293051)
WADA Shinーichiro  九州大学, 農学研究院, 准教授 (60108678)
YAMAMOTO Kazuya  九州大学, 先導物質化学研究所, 特任助教 (10437759)
Project Period (FY) 2007 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥49,920,000 (Direct Cost: ¥38,400,000、Indirect Cost: ¥11,520,000)
Fiscal Year 2010: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
Fiscal Year 2009: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Fiscal Year 2008: ¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Fiscal Year 2007: ¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Keywords環境適合型高分子 / 天然無機ナノフィラー / 表面開始ラジカル重合 / 高性能グリーンナノハイブリッド材料 / イモゴライト / ARGET ATRP / ハイブリッド / α-メチレン-γ-ブチロラクトン / 共重合 / 耐熱性 / ポリ乳酸 / 有機無機ハイブリッド材料 / 界面構造制御 / 生分解性ポリウレタン / ハイブリッドハイドロゲル / 生分解性 / 表面グラフト重合 / ハブリッドハイドロゲル / ハイブリッド材料
Research Abstract

The purpose of this study is to develop novel high-performance green nanohybrids from environmentally friendly polymers and natural inorganic nanofiller. The obtained results from this project are as follows: (1) Purification of imogolite, synthesis of imogolite and its surface modification, (2) surface-initiated controlled radical polymerization from imogolite surface, (3) design of novel environmentally friendly elastomer, (4) design of (biodegradable polyurethane/poly lactic acid) hybrids and their characterization and biodegradability, (5) preparation and characterization of novel (biopolymer/inorganic nanotube) hybrids, (6) preparation and characterization of (PMMA-g-imogolite/poly (lactic acid)) hybrids.

Report

(6 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report   Self-evaluation Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (58 results)

All 2011 2010 2009 2008 2007 Other

All Journal Article (21 results) (of which Peer Reviewed: 14 results) Presentation (26 results) Book (10 results) Remarks (1 results)

  • [Journal Article] Chemical Communications article 'Poly (methyl methacrylate) Grafted Imogolite Nanotubes Prepared through Surface-Initiated ARGET ATRP2011

    • Author(s)
      W.Ma, H.Otsuka, A.Takahara
    • Journal Title

      Chem.Comm 47

      Pages: 5813-5815

    • Related Report
      2010 Final Research Report
  • [Journal Article] Surface Modification of Individual Imogolite Nanotubes with Alkyl Phosphate from an Aqueous Solution2011

    • Author(s)
      W.Ma, Jungeun Kim, H.Otsuka, A.Takahara
    • Journal Title

      Chemistry Letters 40

      Pages: 159-161

    • NAID

      10027814698

    • Related Report
      2010 Final Research Report
  • [Journal Article] Molecular Aggregation States of Imogolite/P3HT Nanofiber Hybrid2011

    • Author(s)
      W.-O.Yah, A.Irie, H.Otsuka, S.Sasaki, N.Yagi, M.Sato, T.Koganezawa, A.Takahara
    • Journal Title

      J.Phys.Conference Series 272

      Pages: 12021-12021

    • Related Report
      2010 Final Research Report
  • [Journal Article] Surface Modification of Individual Imogolite Nanotubes with Alkyl Phosphate from an Aqueous Solution2011

    • Author(s)
      W.Ma, Jungeun Kim, H.Otsuka, A.Takahara
    • Journal Title

      Chemistry Letters

      Volume: 40 Pages: 159-161

    • NAID

      10027814698

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Aggregation States of Imogolite/P3HT Nanofiber Hybrid2011

    • Author(s)
      W.-O.Yah, A.Irie, H.Otsuka, S.Sasaki, N.Yagi, M.Sato, T.Koganezawa, A.Takahara
    • Journal Title

      J.Phys.Conference Series

      Volume: 272 Pages: 12021-12021

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemical Communications article 'Poly (methyl methacrylate) Grafted Imogolite Nanotubes Prepared through Surface-Initiated ARGET ATRP2011

    • Author(s)
      W.Ma, H.Otsuka, A.Takahara
    • Journal Title

      Chem.Comm

      Volume: (In press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Aggregation States of Terthiophene Derivatives on Aluminosilicate Nanofiber Imogolite : Novel Optical and Electrical Properties2011

    • Author(s)
      W.-O.Yah, A.Irie, N.Jiravanichanun, H.Otsuka, A.Takahara
    • Journal Title

      Bull Chem.Soc.Japan

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Imogolite Reinforced Nanocomposites : Multifaceted Green Materials2010

    • Author(s)
      W.-O.Yah, K.Yamamoto, N.Jiravanichanun., H.Otsuka, A.Takahara
    • Journal Title

      Materials 3

      Pages: 1709-1745

    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Journal Article] Imogolite Reinforced Nanocomposites : Multifaceted Green Materials2010

    • Author(s)
      W.-O. Yah, K. Yamamoto N. Inoue., N. Jiravanichanun., H. Otsuka, A. Takahara
    • Journal Title

      Materials 3

      Pages: 1709-1745

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] 生分解性セグメント化ポリウレタンとそのポリ乳酸ブレンドの構造と物性2009

    • Author(s)
      白波瀬朋子、波多野道子、大塚英幸、高原淳
    • Journal Title

      日本ゴム協会誌 82

      Pages: 349-355

    • NAID

      10025009927

    • Related Report
      2010 Final Research Report
  • [Journal Article] Synthesis and characterization of semi-interpenetrating polymer networks based on polyurethane and N-isopropylacrylamide for wound dressing2009

    • Author(s)
      T.-T.Reddy, A.Kano, A.Maruyama, A.Takahara
    • Journal Title

      J.Biomed. Mater. Res 88B

      Pages: 32-40

    • Related Report
      2010 Final Research Report
  • [Journal Article] 生分解性セグメント化ポリウレタンとそのポリ乳酸ブレンドの構造と物性2009

    • Author(s)
      白波瀬朋子, 波多野道子, 大塚英幸, 高原淳
    • Journal Title

      日本ゴム協会誌 82

      Pages: 349-355

    • NAID

      10025009927

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of semi-interpenetrating polymer networks based on polyurethane and N-isopropylamide for wound dressing2009

    • Author(s)
      T. Thimma Reddy, A. Kano, A. Maruyama, M. Hadano, A. Takahara
    • Journal Title

      J.Biomed.Mater.Res. 88B

      Pages: 32-40

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] 生分解性セグメント化ポリウレタンとそのポリ乳酸ブレンドの構造と物性2009

    • Author(s)
      白波瀬朋子, ら
    • Journal Title

      日本ゴム協会誌 82

      Pages: 349-355

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of semi-interpenetrating polymer networks based on polyurethane and N-isopropylacrylamide for wound dressing2009

    • Author(s)
      T. Thimma Reddyら
    • Journal Title

      J. Biomed. Mater. Res 88B

      Pages: 32-40

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 生分解性セグメント化ポリウレタンとそのポリ乳酸ブレンドの構造と物性2009

    • Author(s)
      白波瀬朋子ら
    • Journal Title

      日本ゴム協会誌 (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermosensitive, Transparent Semi-Interpenetrating Polymer Networks for Wound Dressing and Cell Adhesion Control2008

    • Author(s)
      T. Thimma Reddy, A. Kano, A. Maruyama, M. Hadano, A. Takahara
    • Journal Title

      Biomacromolecules 9

      Pages: 1313-1321

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Thermosensitive Transparent Semi-Interpenetrating Polymer Networks for Wound Dressing and Cell Adhesion Control2008

    • Author(s)
      T.Thimma Reddy, et. al.
    • Journal Title

      Biomacromolecules 9

      Pages: 1313-1321

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two dimensional alignment of the alumino-silicate nanofiber, imogolite, on a solid surface2007

    • Author(s)
      S.Park, Y.Lee, B.Kim,J.Lee, Y.Jeong, J.Noh, A.Takahara, D.Sohn
    • Journal Title

      Chem.Comm.

      Pages: 2917-2919

    • Related Report
      2010 Final Research Report
  • [Journal Article] Two Dimensional Alignment of the Alumino-silicate Nanofiber, Imogolite, on a Solid Surface2007

    • Author(s)
      G. Park, Y,-H. Lee, B.-J. Kim, J.-S. Lee, Y.-D. Jeong, J.-G. Noh, A. Takahara, D.-W. Sohn
    • Journal Title

      Chem.Comm.

      Pages: 2917-2919

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Two dimensional alignment of the alumino-silicate nanofiber, imogolite, on a solid surface2007

    • Author(s)
      S.-G Park, et. Al.
    • Journal Title

      Chemical Communication

      Pages: 2917-2919

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Imogolite Clay Nanotubes for Polymer Nanohybrids2011

    • Author(s)
      高原淳
    • Organizer
      ACS national Symposium
    • Place of Presentation
      Anaheim, U.S.A.
    • Year and Date
      2011-03-31
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Preparation and Characterization of Poly (lactic acid) Hybrids with Surface Modified Imogolite2010

    • Author(s)
      T.Shirahase, W.Ma, R.Okazaki, H.Soejima, Y.Terayama, A.Takahara
    • Organizer
      International Conference on Polymer Analysis and Characterization & 15^<th> Symposium on Polymer Analysis in Japan
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      2010-12-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] Functionalization and Hybridization of Tubular Clay-like Material for Versatile Nanohybrids2010

    • Author(s)
      W.-O.Yah, W.Ma, A.Takahara, Y.Lvov.
    • Organizer
      South East/South West Regional ACS Meeting
    • Place of Presentation
      New Orleans, USA.
    • Year and Date
      2010-12-01
    • Related Report
      2010 Final Research Report
  • [Presentation] Functionalization and Hybridization of Tubular Clay-like Material for Versatile Nanohybrids2010

    • Author(s)
      W.-O.Yah, W.Ma, A.Takahara, Y.Lvov.
    • Organizer
      South East/South West Regional ACS Meeting
    • Place of Presentation
      New Orleans, USA
    • Year and Date
      2010-12-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] Dispersion of imogolite nanotubes into organic solvents by surface modification2010

    • Author(s)
      W.Ma, H.Otsuka, A.Takahara
    • Organizer
      The 3^<rd> International Kyushu Colloid Colloquium
    • Place of Presentation
      Fukuoka, Japan
    • Year and Date
      2010-09-23
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Influence of Interfacial Interaction on the Structure and Properties of Imogolite/Polymer Nanocomposites2010

    • Author(s)
      W.Ma, W.-O.Yah, H.Otsuka, A.Takahara
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Fabrication and characterization of PMMA grafted imogolite nanotubes2010

    • Author(s)
      W.Ma, H.Otsuka, A.Takahara
    • Organizer
      ACS National Meeting & Exposition
    • Place of Presentation
      Boston, U.S.A.
    • Year and Date
      2010-08-24
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Preparation and Characterization of Polystyrene/Imogolite Nanocomposites2010

    • Author(s)
      W.Ma, H.Otsuka, A.Takahara
    • Organizer
      PP'2010
    • Place of Presentation
      Ji'nan, China
    • Year and Date
      2010-06-09
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Influence of Interfacial Interaction on Physicochemical Properties of Imogolite/Polymer Nanocomposites2010

    • Author(s)
      W.Ma, W.-O.Yah, H.Otsuka, A.Takahara
    • Organizer
      第59回 高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Fabrication of Polymer Grafted Imogolite Nanotubes2010

    • Author(s)
      W.Ma, H.Otsuka, A.Takahara
    • Organizer
      SIMS 2010
    • Place of Presentation
      Miyazaki, Japan
    • Year and Date
      2010-04-23
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Preparation and Characterization of Polymer Nanohybrids Prepared from Imogolite Nanofiber2010

    • Author(s)
      A. Takahara
    • Organizer
      SIMS 2010
    • Place of Presentation
      Miyazaki
    • Year and Date
      2010-04-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation and Characterization of Poly (3-hexylthiophene)/Imogolite Nanofiber Composites2009

    • Author(s)
      W.-O.Yah, A.Irie, H.Otsuka, A.Takahara
    • Organizer
      The 1st FAPS Polymer Congress
    • Place of Presentation
      名古屋国際会議場
    • Related Report
      2010 Final Research Report
  • [Presentation] A Novel Method towards Organically Modified Imogolite Nonofibers2009

    • Author(s)
      W.Ma, H.Otsuka, A.Takahara
    • Organizer
      2nd Asian Symposium on Advanced Materials (ASAM-2)
    • Place of Presentation
      Fudan University, China
    • Related Report
      2010 Final Research Report
  • [Presentation] (ポリへキシルチオフェン/無機ナノフィラー)ハイブリッドの結晶化挙動2009

    • Author(s)
      葉永安, 王哲, 大塚英幸, 増永啓康, 佐々木園, 坂田修身, 高田昌樹, 高原淳
    • Organizer
      平成22年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2010 Final Research Report
  • [Presentation] A Novel Method towards Organically Modified Imogolite Nonofibers2009

    • Author(s)
      W. Ma, H. Otsuka, A. Takahara
    • Organizer
      2nd Asian Symposium on Advanced Materials (ASAM-2)
    • Place of Presentation
      Shanghai, China
    • Related Report
      2009 Self-evaluation Report
  • [Presentation] Preparation and Characterization of Poly(3-hexylthiophene)/Imogolite Nanofiber Composites2009

    • Author(s)
      W.-O. Yah, A. Irie, H. Otsuka, A. Takahara
    • Organizer
      The 1st FAPS Polymer Congress
    • Place of Presentation
      名古屋
    • Related Report
      2009 Self-evaluation Report
  • [Presentation] (ポリヘキシルチオフェン/無機ナノフィラー)ハイブリッドの結晶化挙動2009

    • Author(s)
      葉永安, 王哲, 大塚英幸, 増永啓康, 佐々木園, 坂田修身, 高田昌樹, 高原淳
    • Organizer
      平成22年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2009 Annual Research Report
  • [Presentation] A Novel Method towards Organically Modified Imogolite Nonofibers2009

    • Author(s)
      Wei Ma, Hideyuki Otsuka, Atsushi Takahara
    • Organizer
      2nd Asian Symposium on Advanced Materials(ASAM-2)
    • Place of Presentation
      Fudan University, China
    • Related Report
      2009 Annual Research Report
  • [Presentation] Preparation and Characterization of Poly(3-hexylthiophene)/Imogolite Nanofiber Composites2009

    • Author(s)
      Weng On Yah, Atsushi Irie, Hideyuki Otsuka, Atsushi Takahara
    • Organizer
      The 1st FAPS Polymer Congress
    • Place of Presentation
      名古屋国際会議場
    • Related Report
      2009 Annual Research Report
  • [Presentation] (ポリ乳酸/セグメント化ポリウレタンウレア)ブレンドの相分離状態と分解特性2008

    • Author(s)
      白波瀬朋子ら
    • Organizer
      ポリマー材料フォーラム
    • Place of Presentation
      広島国際会議場
    • Year and Date
      2008-11-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] 生分解性ポリウレタンの分子設計と特性解析2008

    • Author(s)
      高原 淳
    • Organizer
      創造機能化学第116委員会
    • Place of Presentation
      学士会館(東京)
    • Year and Date
      2008-10-07
    • Related Report
      2008 Annual Research Report
  • [Presentation] (ポリ乳酸/セグメント化ポリウレタンウレア)複合材料の特性解析と分解挙動2008

    • Author(s)
      白波瀬朋子, ら
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2008-09-24
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] 天然無機ナノファイバー「イモゴライト」のハイブリッド材料への応用2008

    • Author(s)
      高原淳
    • Organizer
      日本セラミック協会 第21回秋季シンポジウム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2008-09-18
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] Surface Modification of silica nanoparticle and Si-wafer through surface-initiated controlled radical polymerization2008

    • Author(s)
      高原淳
    • Organizer
      Particle 2008
    • Place of Presentation
      Wyndham Orlando Resort
    • Year and Date
      2008-05-10
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] 天然無機ナノファイバー「イモゴライト」のハイブリッド材料への応用2008

    • Author(s)
      高原淳
    • Organizer
      日本セラミック協会 第21回秋季シンポジウム
    • Place of Presentation
      北九州
    • Related Report
      2009 Self-evaluation Report
  • [Presentation] 環境低負荷型セグメント化ポリウレタンウレアの分子設計とその特性評価2007

    • Author(s)
      波多野道子, ら
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-19
    • Related Report
      2010 Final Research Report 2007 Annual Research Report
  • [Book] Structure and Properties of Imogolite Nanotubes and Their Application to Polymer Nanocomposites in Inorganic and Metallic Nanotubular Materials2011

    • Author(s)
      H, Otsuka, A.Takahara
    • Publisher
      Springer
    • Related Report
      2010 Final Research Report
  • [Book] Structure and Properties of Imogolite Nanotubes and Their Application to Polymer Nanocomposites in Inorganic and Metallic Nanotubular Materials2010

    • Author(s)
      H, Osyuka, A.takahar
    • Total Pages
      21
    • Publisher
      Springer
    • Related Report
      2010 Annual Research Report
  • [Book] Chapter 13, Structure and Properties of Imogolite Nanotubes and Their Application to Polymer Nanocomposites in Inorganic and Metallic Nanotubular Materials2010

    • Author(s)
      H. Otsuka, A. Takahara
    • Publisher
      Springer
    • Related Report
      2009 Self-evaluation Report
  • [Book] Structure and Properties of Imogolite Nanotubes and Their Application to Polymer Nanocomposites in Inorganic and Metallic Nanotubular Materials2010

    • Author(s)
      H.Otsuka, A.Takahara
    • Publisher
      Springer(印刷中)
    • Related Report
      2009 Annual Research Report
  • [Book] 超分子サイエンス&テクノロジー(18 イモゴライトチューブ)2009

    • Author(s)
      大塚英幸、高原淳
    • Publisher
      NTS
    • Related Report
      2010 Final Research Report
  • [Book] 超分子サイエンス&テクノロジー2009

    • Author(s)
      大塚英幸, 高原淳
    • Publisher
      NTS
    • Related Report
      2009 Self-evaluation Report
  • [Book] 18イモゴライトチューブ 、「超分子サイエンス&テクノロジー」2009

    • Author(s)
      大塚英幸, 高原 淳
    • Total Pages
      8
    • Publisher
      NTS
    • Related Report
      2008 Annual Research Report
  • [Book] 有機・無機・金属ナノチューブ(イモゴライトナノチューブの構造・特長とポリマーナノコンポジットへの応用)2008

    • Author(s)
      高原淳、山本和弥
    • Publisher
      フロンティア出版
    • Related Report
      2010 Final Research Report
  • [Book] イモゴライトナノチューブの構造・特長とポリマーナノコンポジットヘの応用、「有機・無機・金属ナノチューブ」2008

    • Author(s)
      高原 淳, 山本 和弥
    • Total Pages
      8
    • Publisher
      フロンティア出版
    • Related Report
      2008 Annual Research Report
  • [Book] 有機・無機・金属ナノチューブ2008

    • Author(s)
      高原 淳, 山本 和弥
    • Total Pages
      9
    • Publisher
      フロンティア出版
    • Related Report
      2007 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://takahara.ifoc.kyushu-u.ac.jp

    • Related Report
      2010 Final Research Report

URL: 

Published: 2007-04-01   Modified: 2016-04-21  

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