Developing reliable methods for the design of the immobilization of heavy metals in soil : for the application to heterogeneous systems.

• Project/Area Number: 19310047
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Environmental technology/Environmental materials
• Research Institution: Kanazawa University
• Principal Investigator: KAWANISHI Takuya Kanazawa University, 自然システム学系, 准教授 (80234087)
• Co-Investigator(Kenkyū-buntansha): SATO Tsutomu 北海道大学, 工学研究科, 准教授 (10313636) ; SAITO Masahiko 神戸大学, 都市安全研究センター, 助教 (40283915) ; FUKUSHI Keisuke 金沢大学, 環日本海域環境研究センター, 助教 (90444207)
• Project Period (FY): 2007 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000); Fiscal Year 2009: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000); Fiscal Year 2008: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000); Fiscal Year 2007: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
• Keywords: 土壌汚染対策 / 不溶化 / 吸着 / 不均質性 / 土壌水流 / 環境技術 / 環境材料 / 土壌圏現象 / 重金属汚染

Research Abstract

We summarized the effects of pH, coexisting substances, etc. on the adsorption of arsenic on the adsorbent, schwertmannite, with surface complex model. We found that in the heterogeneous water distribution, diffusive efflux of pollutants obeys power law with the exponent ranging from minus 1.0 to minus 0.5, whereas in regular systems the exponent is fixed to minus 0.5. In addition, we validated the effectiveness of barrier system for immobilization with laboratory experiments. We successfully constructed several sub-models for the design of immobilization in heterogeneous polluted sites.

Research Products

• [Journal Article] Power-law decay in rate of solute removal from ground water with various exponents associated with matrix diffusion in granular packed bed (2010)
  • Author(s): Dastagir Muhammad Rehan, Yuko Hatano, Takuya Kawanishi
  • Journal Title: Advanced Powder Technology 21(3) Pages: 284-291
  • NAID: 10027277012
  • Peer Reviewed
• [Journal Article] 中国の野菜畑からあふれ出す窒素 (2009)
  • Author(s): 川西琢也
  • Journal Title: 科学 78 Pages: 754-755
• [Journal Article] 連続時間ランダムウォークモデルのエアースパージング法への適用 (2008)
  • Author(s): 清水航士, 羽田野祐子, 蜷川幸司, 川西琢也
  • Journal Title: 水工学論文集 52 Pages: 415-420
  • NAID: 130004044048
  • Peer Reviewed
• [Journal Article] 中国の野菜畑からあふれ出す窒素 (2008)
  • Author(s): 川西琢也
  • Journal Title: 岩波,科学 78(7) Pages: 754-755
• [Journal Article] 連続時間ランダムウォークモデルのエアースパージング法への適用 (2008)
  • Author(s): 清水 航士・羽田野 祐子・蜷川 幸司・川西 琢也
  • Journal Title: 水工学論文集 52 Pages: 415-420
  • NAID: 130004044048
  • Peer Reviewed
• [Journal Article] Partition of polycyclic aromatic hydrocarbons between the river water and sediments at downstream locations of rivers in Kanazawa, Japan. (2007)
  • Author(s): Van Dieu Anh, K.Uchida, Y.Sano, K.Hayakawa, N.Tang, A.Toriba, T.Kameda Y.Hayashi and T.Kawanishi
  • Journal Title: Journal of Ecotechnology Research 13 Pages: 97-107
  • NAID: 130004956018
  • Peer Reviewed
• [Journal Article] Litter carbon dynamics analysis in forests in an arid ecosystem with a model incorporating the physical removal of litter.
  • Author(s): S.Kumada, T.Kawanishi, Y. Hayashi, K.Ogomori, Y Kobayashi, N.Takahashi, M.Saito, H.Hamano, T.Kojima, K.Yamada
  • Journal Title: Ecological Modelling (印刷中)(掲載確定)
  • NAID: 120001130126
  • Peer Reviewed
• [Presentation] シュベルトマナイトのヒ素吸着に及ぼす腐植物質の影響 (2010)
  • Author(s): 岡道隆, 木戸良介, 高松裕美, 福士圭介, 汲田幹夫, 川西琢也
  • Organizer: 化学工学会第42秋季大会
  • Place of Presentation: 京都
• [Presentation] 天然鉱物系吸着剤を用いたヒ素汚染土壌の不溶化について(財)土壌環境センターセミナーin北陸 (2009)
  • Author(s): 川西琢也
  • Organizer: 土地取引と土壌汚染対策の基礎講座
  • Place of Presentation: 金沢歌舞伎座(招待講演)
  • Year and Date: 2009-02-20
• [Presentation] Power Law Tailing Associated with Matrix Diffusion with the Exponent Other than Minus 1.5 (2008)
  • Author(s): Kawanishi, T., Rehan, D. M., Hatano, Y.
  • Organizer: American Geophysical Union 2008 Fall Meeting
  • Place of Presentation: San Francisco
  • Year and Date: 2008-12-17
• [Presentation] Soil Carbon Distribution and Soil Carbon Content of Arid Land Near Leonora in Western Australia (2008)
  • Author(s): Osono, Y., Kumada, S., Kawanishi, T., Suganuma, H., Hamano, H., Kojima T., Yamada K.
  • Organizer: 15th Asian Symposium on Ecotechnology
  • Place of Presentation: 金沢
  • Year and Date: 2008-10-19
• [Presentation] Partition of Polycyclic Aromatic Hydrocarbons in Water-Sediment System Containing Humic Acid (2008)
  • Author(s): Sugiura, S., Van, D. A., Kawanishi, T.
  • Organizer: 15th Asian Symposium on Ecotechnology
  • Place of Presentation: 金沢
  • Year and Date: 2008-10-19
• [Presentation] Enzymatic Saccharification of Hydrothermal Treated Woody Biomass by Cellulase (2008)
  • Author(s): Kyoya, M., Hayashi, Y., Kawanishi, T.
  • Organizer: 15th Asian Symposium on Ecotechnology
  • Place of Presentation: 金沢
  • Year and Date: 2008-10-19
• [Presentation] Random Simulation of Power Law Tailing of Groundwater (2008)
  • Author(s): Rehan, D. M., Kawanishi, T.
  • Organizer: 15th Asian Symposium on Ecotechnology
  • Place of Presentation: 金沢
  • Year and Date: 2008-10-19
• [Presentation] Immobilization of Arsenic by Using Natural Mineral Adsorbent Schwertmannite (2008)
  • Author(s): Inomata, N., Arakawa, M., Kodo, R., Sugiyama, H., Fukushi, K., Sato, T., Ito, K. Ota, K., Ikeda, H. Kawanishi, T.
  • Organizer: 15th Asian Symposium on Ecotechnology
  • Place of Presentation: 金沢
  • Year and Date: 2008-10-19
• [Presentation] 天然鉱物系吸着剤を用いたヒ素汚染土壌の不溶化 : 設計指針の予備的検討 (2008)
  • Author(s): 川西琢也, 猪股夏子, 杉山博則, 荒川正宏, 木戸良介, 伊藤健一, 池田穂高, 福士圭介, 佐藤努
  • Organizer: 化学工学会第40回秋季大会
  • Place of Presentation: 仙台
  • Year and Date: 2008-09-26
• [Presentation] Power law tailing in removal of pollutants from water to gas : A invasion percolation and random walk model study (2008)
  • Author(s): Kawanishi, T., Rehan, D. M., Sugiyama, H.
  • Organizer: 5th International Conference, Interfaces Against Pollution
  • Place of Presentation: 京都
  • Year and Date: 2008-06-03
• [Presentation] Power law tailing in air-sparging of groundwater (2008)
  • Author(s): Dastagir Muhammad Rehan, Ninagawa Koji, Fujimaru Atsushi, Hayashi Yoshishige, Kawanishi Takuya
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 静岡
  • Year and Date: 2008-03-19
• [Presentation] 乾燥地植林における保水材の混入位置による保水効果の差異の検討 (2008)
  • Author(s): 平松 享, 熊田 俊吾, 林 良茂, 川西 琢也
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 静岡
  • Year and Date: 2008-03-19
• [Presentation] 西オーストラリア州レオノラ近郊の乾燥地における植生と土壌炭素の関係 (2008)
  • Author(s): 大園 侑利, 熊田 俊吾, 川西 琢也, 林 良茂, 菅沼 秀樹, 濱野 裕之, 小島 紀徳, 山田 興一
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 静岡
  • Year and Date: 2008-03-19
• [Presentation] 西オーストラリア州Sturt Meadowsに広がる乾燥地植生の炭素動態解析 (2008)
  • Author(s): 熊田 俊吾, 大園 侑利, 川西 琢也, 林 良茂, 菅沼 秀樹, 濱野 裕之, 小島 紀徳, 山田 興一
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 静岡
  • Year and Date: 2008-03-19
• [Presentation] 腐植物質の存在する水、底質中での多環芳香族炭化水素(PAHs)の固液間分配の解析 (2008)
  • Author(s): 杉浦 修平, Van Anh Dieu, 木下 千尋, 林 良茂, 川西 琢也
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 静岡
  • Year and Date: 2008-03-17
• [Presentation] Power law tailing in removal of pollutants from water to gas : A invasion percolation and random walk model study, 5th International Conference (2008)
  • Author(s): Kawanishi T., Rehan, D.M., Sugiyama, H.
  • Organizer: Interfaces Against Pollution
  • Place of Presentation: Kyoto, Japan.
• [Presentation] Power Law Tailing in Air-sparging of Groundwater (2008)
  • Author(s): Dastagir Muhammad Rehan , Ninagawa Koji, Fujimaru Atsushi, Hayashi Yoshishige, Kawanishi Takuya
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 静岡
• [Presentation] 天然鉱物系吸着剤によるヒ素汚染土壌の不溶化-吸着平衡・カラム実験 (2008)
  • Author(s): 猪股夏子, 荒川正広, 木戸良介, 林良茂, 川西琢也, 伊藤健一, 池田穂高
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 静岡
• [Presentation] Power law tailing in air-sparging and invasion-percolation model for calculating diffusion rates in the liquid phase. (2007)
  • Author(s): T.Kawanishi and Y.Hayashi
  • Organizer: American Geophysical Union 2007 Fall Meeting
  • Place of Presentation: San Francisco,USA
  • Year and Date: 2007-12-11
• [Presentation] Effect of humic adid on the partition of polycyclic aromatic hydrocarbons(PAHs)in water sediment system. (2007)
  • Author(s): D.Anh Van, K.Hayakawa, N.Tang, A.Toriba, Y.Hayashi and T.Kawanishi
  • Organizer: The 21st International Symposium for Polycyclic Aromatic Compounds(ISPAC 21)
  • Place of Presentation: Trondheim,Norway
  • Year and Date: 2007-08-06
• [Presentation] Power law tailing in air-sparging and invasion- percolation model for calculating diffusion rates in the liquid phase (2007)
  • Author(s): 川西琢也, 林良茂
  • Organizer: American Geophysical Union 2007 Fall Meeting, H23G-1712
  • Place of Presentation: San Francisco, USA.
• [Book] 沙漠を森に (2011)
  • Author(s): 小島紀徳, 江頭靖幸, 川西琢也, 他
  • Total Pages: 220
  • Publisher: コロナ社