Searches for clay minerals with asymmetric structures and their identification

• Project/Area Number: 19340159
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Petrology/Mineralogy/Science of ore deposit
• Research Institution: Ochanomizu University
• Principal Investigator: YAMAGISHI Akihiko Ochanomizu University, 理学部, 訪問教授 (70001865)
• Co-Investigator(Kenkyū-buntansha): KOGURE Toshihiro 東京大学, 理学研究科, 准教授 (50282728) ; INOUE Atsuyuki 千葉大学, 理学部, 教授 (30150270)
• Project Period (FY): 2007 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000); Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000); Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000); Fiscal Year 2008: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000); Fiscal Year 2007: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
• Keywords: 不斉構造 / 粘土鉱物 / シス型スメクタイト / カオリナイト / イモグライト / 粘土LB膜 / 振動円二色性 / 立体選択的吸着 / 鋳型反応 / キラルゲル / 天然・人工結晶 / キラリティ

Research Abstract

This project aimed at searching clay minerals with asymmetric structures and identifying their chiral structures. As a result, the presence of single crystals of chiral kaolinite was confirmed by scanning electron microscopy. By applying the method of liquid column chromatography, a racemic mixture of kaolinite particles was attempted to be resolved into a pair of opposite enantiomers. The ultra-thin film of clay single layers was prepared by applying the Langmuir-Blodgett method.

Research Products

• [Journal Article] Hybridization of Clay Minerals with the Floating Film of a Cationic Ir(III) Complex at an Air-water Interface (2011)
  • Author(s): Hisako Sato, Kenji Tamura, Keishi Ohara, Shin-ichi Nagaoka, Akihiko Yamagishi
  • Journal Title: New Journal of Chemistry 35 Pages: 394-399
  • Peer Reviewed
• [Journal Article] Enantioselective Sensing by Luminescence from Cyclometalated Iridium (III) Complexes Adsorbed on a Colloidal Saponite (2011)
  • Author(s): Hisako Sato, Kenji Tamura, R ie Aoki, Masako Kato, Akihiko Yamagishi
  • Journal Title: Chem.Lett. 40 Pages: 65-67
  • Peer Reviewed
• [Journal Article] Effect of Coccolith Polysaccharides Isolated from the occolithophorid, Emiliania huxleyi, on Calcite Crystal Formation in In Vitro CaCO3 Crystallization (2011)
  • Author(s): Kayano K., K. Saruwatari, T. Kogure, Yoshihiro Shiraiwa
  • Journal Title: Marine Biotechnology 13 Pages: 83-92
  • Peer Reviewed
• [Journal Article] Fabrication of Anatase Thin Film with Perfect c-Axis Orientation on Glass Substrate Promoted by a Two-Dimensional Perovskite Nanosheet Seed Layer (2010)
  • Author(s): Shibata T., Y. Ebina, T. Ohnishi, K. Takada, T. Kogure, T. Sasaki
  • Journal Title: Cryst. Growth Des. 10 Pages: 3787-3793
  • Peer Reviewed
• [Journal Article] Application of Chlorite Geothermometry to Hydrothermal Alteration in Toyoha Geothermal System, Southwestern Hokkaido, Japan (2010)
  • Author(s): A. Inoue, K. Kurokawa, T. Hatta
  • Journal Title: Resource Geeology 60 Pages: 52-70
  • NAID: 10030172753
  • Peer Reviewed
• [Journal Article] Highly Luminescent Langmuir-Blodgett Films of Amphiphilic Ir(III) Complexes for an Application of Gas Sensing (2010)
  • Author(s): Hisako Sato, Kenji Tamura, Masahiro Taniguchi, Akihiko Yamagishi
  • Journal Title: New Journal of Chemistry(2010) 34 Pages: 617-622
  • Peer Reviewed
• [Journal Article] Molecular Recognition of Star-burst Tetranuclear Ru(III) Complexes on a Chirally Modified Clay Surface (2010)
  • Author(s): Noriko Fujimoto, Yukie Mori, Akihiko Yamagishi, Hisako Sato
  • Journal Title: J.Chem.Soc., Chem., Comm. 46 Pages: 5473-5475
  • Peer Reviewed
• [Journal Article] Molecular Recognition of Star-burst Tetranuclear Ru(III) Complexes on a Chirally Modified Clay Surface (2010)
  • Author(s): N.Fujimoto, Y.Mori, A.Yamagishi, H.Sato
  • Journal Title: J.Chem.Soc.Chem., Comm. Volume: 46 Pages: 5473-5475
  • Peer Reviewed
• [Journal Article] Application of Chlorite Geothermometry to Hydrothermal Alteration in Toyoha Geothermal System, Southwestern Hokkaido, Japan (2010)
  • Author(s): A.Inoue, K.Kurokawa, T.Hatta
  • Journal Title: Resource Geeology Volume: 60 Pages: 52-70
  • NAID: 10030172753
  • Peer Reviewed
• [Journal Article] Stacking Disorder in a Sedimentary Kaolinite (2010)
  • Author(s): T.Kogure, C.T.Johnston, J.E.Kogel, D.Bish
  • Journal Title: Clays Clay Miner. Volume: 58 Pages: 63-72
  • NAID: 130005008180
  • Peer Reviewed
• [Journal Article] A Comparative study on Chiral and Racemic 12-Hydorxyoctadecanoic Acids in the Solutions and Aggregation States : Does the Racemic Form really Form a Gel? (2010)
  • Author(s): Takara Sakurai, Yuichi Masuda, Hisako Sato, Akihiko Yamagishi, Hitoshi, Kawaji, Tooru Atake, Kayako Hori
  • Journal Title: Bull. Chem. Soc. Jpn. 83 Pages: 145-150
  • Peer Reviewed
• [Journal Article] Non-centrosymmetric behavior of a clay film ion-exchanged with chiral metal complexes (2009)
  • Author(s): Suzuki Y., R. Matsunaga, H. Sato, T. Kogure, A. Yamagishi, J. Kawamata
  • Journal Title: Chem.Commun. 45 Pages: 6964-6966
  • NAID: 120003088004
  • Peer Reviewed
• [Journal Article] Well-controlled crystal growth of zinc oxide films on plastics at room temperature using 2D nanosheet seed layer (2009)
  • Author(s): Shibata, T., T. Ohnishi, I. Sakaguchi, M. Osada, K. Takada, T. Kogure, T. Sasaki
  • Journal Title: J.Phys.Chem.C 113 Pages: 19096-19101
  • Peer Reviewed
• [Journal Article] Metal Ion Sensing by Luminescence from an Ionexchange Adduct of Clay and Cationic Cyclometalated Iridium (III) Complex (2009)
  • Author(s): Hisako Sato, Kenji Tamura, Masahiro Taniguchi, Akihiko Yamagishi
  • Journal Title: Chem Lett 38 Pages: 14-15
  • NAID: 10023990054
  • Peer Reviewed
• [Journal Article] Highly Enantioselective Asymmetric Autocatalysis using Chiral Ruthenium Complex-ion-exchanged Synthetic Hectorite as a Chiral Initiator (2009)
  • Author(s): Tsuneomi Kawasaki, Toshiki Omine, Kenta Suzuki, Hisako Sato, Akihiko Yamagishi, Kenso Soai
  • Journal Title: Organic & Biomolecular Chemistry 7(Hot article & Front cover) Pages: 1073-1075
  • Peer Reviewed
• [Journal Article] Non-centrosymmetric behavior of a clay film ion-exchanged with chiral metal complexes (2009)
  • Author(s): Yasutaka Suzuki, Ryoya Matsunaga, Hisako Sato, Toshihiro Kogure, Akihiko Yamagishi, Jun Kawamata
  • Journal Title: Chem. Commun Pages: 6964-6966
  • NAID: 120003088004
  • Peer Reviewed
• [Journal Article] Metal Ion Sensing by Luminescence from an Ion -exchange Adduct of Clay and Cationic Cyclometalated Iridium(III)Complex (2009)
  • Author(s): Hisako Sato, Kenji Tamura, Masahiro Taniguchi, Akihiko Yamagishi
  • Journal Title: Chemistry Letters 38 Pages: 14-15
  • NAID: 10023990054
  • Peer Reviewed
• [Journal Article] Highly Enantioselective Asymmetric Autocatalysis using Chiral Ruthenium Complex-ion-exchanged Synthetic as a Chiral Initiator (2009)
  • Author(s): Tsuneomi Kawasaki, toshiki Omine, Kenta Suzuki, Hisako Sato, Akihiko Yamagishi, Kenso Soai
  • Journal Title: Organic & Biomolecular Chemistry 7 Pages: 1073-1075
  • Peer Reviewed
• [Journal Article] Non-centrosymmetric behavior of a clay film ion-exchanged with chiral metal complexes (2009)
  • Author(s): Yasutaka Suzuki, Ryoya Matsunaga, Hisako Sato, Toshihiro Kogure, Akihiko Yamagishi, Jun Kawamata
  • Journal Title: Chemical Communication Pages: 6964-6966
  • NAID: 120003088004
  • Peer Reviewed
• [Journal Article] Chiral Bead-like Trimer of Tris(2, 4-pentaedioneate)ruthenium(III) (2008)
  • Author(s): Hisako Sato, Jun Kameda, Yutaka Fukuda, Masa-aki Haga, Akihiko Yamagishi
  • Journal Title: Chemistry Letters 37 Pages: 720-721
  • Peer Reviewed
• [Journal Article] Long Distance Chiral Transfer in a Gel : Experimental and ab initio Analyses of Vibrational Circular Dichroism Spectra of R-and S-12 Hydroxyoctadecanoic Acid Gels (2008)
  • Author(s): Hisako Sato, Kayako Hori, Takara Sakurai, Akihiko Yamagishi
  • Journal Title: Chemical Physics Letters 467 Pages: 140-143
  • Peer Reviewed
• [Journal Article] Metal Ion Sensing by Luminescence from an Ion -exchange Adduct of Clay and Cationic Cyclometalated Iridium (III) Complex (2008)
  • Author(s): Hisako Sato, Kenji Tamura, Masahiro Taniguchi, Akihiko Yamagishi
  • Journal Title: Chemistry Letters 38 Pages: 14-15
  • NAID: 10023990054
  • Peer Reviewed
• [Journal Article] High-Resolution TEM and XRD Simulation of Stacking Disorder in 2:1 Pyllosilicates (2008)
  • Author(s): Kogure Tishihiro, Jun Kameda
  • Journal Title: Zeitschrift fur Kristallography 223 Pages: 69-75
  • Peer Reviewed
• [Journal Article] XRD and HRTEM analyses of stacking structure in sudoite, di-trioctahedral chlorite (2007)
  • Author(s): Kameda, J., R. Miyawaki, R. Kitagawa and T. Kogure
  • Journal Title: Am. Mineral. 92 Pages: 1586-1592
  • Peer Reviewed
• [Journal Article] Novel 2:1 structure of phyllosilicates formed by annealing Fe3+, Mg-rich dioctahedral mica (2007)
  • Author(s): Kogure, T., J. Kameda and V. A. Drits
  • Journal Title: Am. Mineral. 92 Pages: 1531-1534
  • Peer Reviewed
• [Journal Article] Application of the Δ∧ Isomerism of Octahedral Metal Complexes as a Chiral Source in Photochemistry (2007)
  • Author(s): Hisako Sato and Akihiko Yamagishi
  • Journal Title: Jourmal of Photochemistry and Photobiology. C: Photochemistry Reviews. 8 Pages: 67-84
  • Peer Reviewed
• [Presentation] イリジウム金属錯体とモンモリロナイトハイブリッドLB膜の発光挙動 (2011)
  • Author(s): 佐藤久子、中江隆博、田村堅志、山岸晧彦
  • Organizer: 第91回日本化学会春季大会
  • Place of Presentation: 講演予稿集
  • Year and Date: 2011-03-11
• [Presentation] イリジウム金属錯体とモンモリロナイトハイブリッドLB膜の発光挙動 (2010)
  • Author(s): 佐藤久子、中江隆博、田村堅志、山岸晧彦
  • Organizer: 第29回 無機高分子研究討論会
  • Place of Presentation: 東京
• [Presentation] アミノ基含有ラダー型ポリシルセスキオキサンへのキラル基の導入とナノ構造制御 (2010)
  • Author(s): 金子芳郎、豊留寿也、佐藤久子、山岸晧彦
  • Organizer: 第29回 無機高分子研究討論会
  • Place of Presentation: 東京
• [Presentation] 混合配位子錯体の幾何異性に対する振動円二色性分光法による研究 (2010)
  • Author(s): 佐藤久子、宇野英満、中野晴之、山岸晧彦
  • Organizer: 第60回錯体化学討論会
  • Place of Presentation: 大阪
• [Presentation] 配位性Ru(III)錯体を用いたキラルテクトニクスの構築 (2010)
  • Author(s): 山岸晧彦、藤本慎子、森幸恵、佐藤久子
  • Organizer: 第60回錯体化学討論会
  • Place of Presentation: 大阪
• [Presentation] キラル基含有ラダー型ポリシルセスキオキサンの創製とナノ構造制御 (2010)
  • Author(s): 金子芳郎、豊留寿也、佐藤久子、山岸晧彦
  • Organizer: 第59回 高分子討論会
  • Place of Presentation: 北海道(依頼講演)
• [Presentation] 一次元無機高分子へのキラル基の導入とナノ構造制御 (2010)
  • Author(s): 金子芳郎、豊留寿也、佐藤久子、山岸晧彦
  • Organizer: 第54回粘土科学討論会
  • Place of Presentation: 名古屋大学
• [Presentation] 粘土鉱物と発光性イリジウム錯体とのハイブリッドLB膜による発光挙動 (2010)
  • Author(s): 堤響子、中江隆博、田村堅志、山岸晧彦、佐藤久子
  • Organizer: 第54回粘土科学討論会
  • Place of Presentation: 名古屋大学
• [Presentation] 振動円二色性分光法の混合配位子錯体への応用 (2010)
  • Author(s): 佐藤久子、宇野英満、山岸晧彦
  • Organizer: MC2010(モレキュラーキラリティ)
  • Place of Presentation: 北海道
• [Presentation] 粘土と発光性イリジウム錯体のハイブリッドLB膜を用いた酸素センシング (2009)
  • Author(s): 国吉勇司、田村堅志、山岸晧彦、佐藤久子
  • Organizer: 第53回粘土科学討論会
  • Place of Presentation: 岩手大学(盛岡市)
  • Year and Date: 2009-09-11
• [Presentation] 発光性イリジウム錯体と粘土との複合膜の製造 (2008)
  • Author(s): 山岸晧彦, 佐藤久子, 谷口昌弘, 田村堅志, 山田裕久
  • Organizer: 第52回粘土科学討論会
  • Place of Presentation: 沖縄ポートホテル
  • Year and Date: 2008-09-03
• [Presentation] 粘土薄膜の伝導性 (2007)
  • Author(s): 山岸晧彦、佐藤久子、岡本健太郎、田村堅志、山田裕久、猿渡和子、小暮敏博
  • Organizer: 第51回粘土科学討論会
  • Place of Presentation: 北海道大学
• [Presentation] 粘土と発光性イリジウム錯体のハイブリッドLB膜を用いた酸素センシング
  • Author(s): 国吉勇司, 田村堅志, 山岸晧彦, 佐藤久子
  • Organizer: 第53回粘土科学討論会
  • Place of Presentation: 岩手大学
• [Presentation] 粘土-イリジウム錯体複合からの発光を用いたキラルセンシング
  • Author(s): 山岸晧彦, 佐藤久子, 田村堅志, 加藤昌子, 青木理恵
  • Organizer: 第53回粘土科学討論会
  • Place of Presentation: 岩手大学
• [Presentation] 粘土薄膜の電気伝導性 : 合成ヘクトライト
  • Author(s): 佐藤久子, 田村堅志, 小暮敏博, 山岸晧彦
  • Organizer: 第53回粘土科学討論会
  • Place of Presentation: 岩手大学
• [Patent(Industrial Property Rights)] ハイブリッド膜およびガスセンサ (2011)
  • Inventor(s): 佐藤、田村、山岸
  • Industrial Property Rights Holder: 愛媛大学
  • Industrial Property Number: 2011-097322
  • Filing Date: 2011-04-25