Supramolecular self-supporting membrane having chiral nano-channel from supramolecular ladder chiral double helical polymer

• Project/Area Number: 19350054
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer chemistry
• Research Institution: Niigata University
• Principal Investigator: AOKI Toshiki Niigata University, 自然科学系, 教授 (80212372)
• Co-Investigator(Kenkyū-buntansha): KANEKO Takashi 新潟大学, 超域研究機構, 教授 (90272856) ; TERAGUCHI Masahiro 新潟大学, 自然科学系, 助教 (30334650) ; NAMIKOSHI Takeshi 新潟大学, ベンチャー・ビジネス・ラボラトリー, VBL研究機関研究員 (30452072) ; HADANO Shingo 京都大学, 工学研究科, 産学官連携研究員 (70397157)
• Project Period (FY): 2007 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000); Fiscal Year 2009: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000); Fiscal Year 2008: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000); Fiscal Year 2007: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
• Keywords: らせん選択重合 / ラダー高分子 / キラルらせん高分子 / 膜 / 高分子反応 / 分解反応 / 自立膜 / 超分子膜

Research Abstract

独創的な構造を持つ「超分子ラダーキラル二重らせん高分子」を申請者らの見出した手法で数種類合成することに成功した。この高分子のみよりなる自立膜が、光により定量的な選択芳香族環化分解を行い、しかも自立膜性を保つことを見出した。これにより『超分子ポリマー膜』の新しい調製法、超高分子量ポリマーのミクロ構造分析法、キラルナノチャンネル超分子ポリマー自立膜の調製法を見出した。

Research Products

• [Journal Article] Synthesis and helix-sense-selective polymerization of a novel phenylacetylene having a trisiloxanyl group and two hydroxyl groups and enantioselective permeability of the resulting chiral polymeric membrane (2010)
  • Author(s): Lijia Liu, Yoshiyuki Oniyama, Yu Zang, Shingo Hadano, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Takeshi Namikoshi
  • Journal Title: Edy Marwanta, Polymer 51(in press)
  • Peer Reviewed
• [Journal Article] Helix-Sense-Selective Polymerization of Achiral Bis(hydroxymethyl)phenylacetylenes Having an Alkyl Group of Different Lengths (2009)
  • Author(s): Shingo Hadano, Takuya Kishimoto, Tomonori Hattori, Daisuke Tanioka, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko, Takeshi Namikoshi
  • Journal Title: Edy Marwanta, Macromol. Chem. Phys 210(9) Pages: 717-727
  • Peer Reviewed
• [Journal Article] Two Modes of Asymmetric Polymerization of Phenylacetylene Having a L-Valinol Residue and Two Hydroxy Groups (2009)
  • Author(s): Hongge Jia, Masahiro Teraguchi, Toshiki Aoki, Yunosuke Abe, Takashi Kaneko, Shingo Hadano, Takeshi Namikoshi
  • Journal Title: Edy Marwanta, Macromolecules 42(1) Pages: 17-19
• [Journal Article] Syntesis of Poly(1,3-phenyleneethynylenes) Membranes having One-Handed helical Conformation without Any Chiral Side Groups by In-Situ Desubstitution of D-menthoxy groups (2009)
  • Author(s): Makoto Inoue
  • Journal Title: Synth.Met. 159 Pages: 854-858
  • Peer Reviewed
• [Journal Article] Helix-Sense-Selective Polymerization of Achiral Bis(hydroxymethyl)pheny lacetylenes Having an Alkyl Group of Different Lengths (2009)
  • Author(s): Shingo Hadano
  • Journal Title: Macromol.Chem.Phys. 210 Pages: 717-727
  • Peer Reviewed
• [Journal Article] Two Modes of Asymmetric Polymerization of Phenylacetylene Having a L-Valinol Residue and Two Hydroxy Groups (2009)
  • Author(s): Jia, Hongge
  • Journal Title: Macromolecules 42 Pages: 17-19
  • Peer Reviewed
• [Journal Article] Synthesis of Poly (1, 3-phenyleneethynylenes) Membranes having One-Handed helical Conformation without Any Chiral Side Groups by In-Situ Desubstitution of D-menthoxy groups (2009)
  • Author(s): Makoto Inoue
  • Journal Title: Synth. Met. (印刷中)
  • Peer Reviewed
• [Journal Article] Helix-Sense-Selective Polymerization of Achiral Bis (hydroxymethyl) phenylacetylenes Having an Alkyl Group of Different Lengths (2009)
  • Author(s): Shingo Hadano
  • Journal Title: Macromol. Chem. Phys. (印刷中)
  • Peer Reviewed
• [Journal Article] Phenyleneethynylene Macrocycle-Fused Phenylacetylene Monomers : Synthesis and Polymerization (2009)
  • Author(s): Takashi Kaneko
  • Journal Title: Macromol. Chem. Phys. 210 Pages: 22-36
  • Peer Reviewed
• [Journal Article] Synthesis of an Optically Active Poly(aryleneethynylene) Bearing Galvinoxyl Residues and Its Chiroptical and Magnetic Properties (2009)
  • Author(s): Takashi Kaneko
  • Journal Title: Synth. Met. (印刷中)
  • Peer Reviewed
• [Journal Article] Optically Active Helical Structure and Magnetic Interaction of Poly(phenylacetylene)-based Polyradicals (2009)
  • Author(s): Takashi Kaneko
  • Journal Title: Polyhedron (印刷中)
  • Peer Reviewed
• [Journal Article] Copper(I) Iodide Accelerates Catalytic Activation in Rhodium Complex-catalyzed Helix-sense-selective Polymerization of Achiral Phenylacetylene Monomers (2008)
  • Author(s): Hiroo Katagiri, Takashi Kaneko, Masahiro Teraguchi, Toshiki Aoki
  • Journal Title: Chem. Lett 37(4) Pages: 390-391
  • NAID: 10021079170
  • Peer Reviewed
• [Journal Article] Copper (I) Iodide Accelerates Catalytic Activation in Rhodium Complex- catalyzed Helix-sense-selective Polymerization of Achiral Phenylacetylene Monomers (2008)
  • Author(s): Hiroo Katagiri
  • Journal Title: Chem. Lett. 37 Pages: 390-391
  • Peer Reviewed
• [Journal Article] Helix-Sense Tunability Induced by Achiral Diene Ligands in the Chiral Catalytic System for the Helix-Sense-Selective Polymerization of Achiral and Bulky Phenylacetylene Monomers (2007)
  • Author(s): Takashi Kaneko, Yasuhiro Umeda, Honge Jia, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
  • Journal Title: Macromolecules 40(20) Pages: 7098-7102
• [Journal Article] Helix-Sense Tunability Induced by Achiral Diene Ligands in the Chiral Catalytic System for the Helix-Sense-Selective Polymerization of Achiral and Bulky Phenylacetylene Monomers (2007)
  • Author(s): Takashi Kaneko
  • Journal Title: Macromolecules 40 Pages: 7098-7102
  • Peer Reviewed
• [Presentation] 立体規則性共役ポリマーの合成と光とポロジカル超分子ポリマー化 (2010)
  • Author(s): 青木俊樹
  • Organizer: 東海シンポジウム、高分子学会東海支部主催
  • Place of Presentation: 名古屋国際会議場
  • Year and Date: 2010-01-14
• [Presentation] ポリフェニルアセチレン膜の高選択的芳香環生成反応による超分子自己支持膜の調製(2)-反応条件の選択性への効果 (2009)
  • Author(s): 鬼山祥幸
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本
  • Year and Date: 2009-09-18
• [Presentation] ポリフェニルアセチレン膜の高選択的芳香環生成反応による超分子自己支持膜の調製(1)-ポリマーの一次および高次構造の選択性への効果 (2009)
  • Author(s): 浪越毅
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本
  • Year and Date: 2009-09-18
• [Presentation] Two Modes of Asymmetric Polymerization of Phenylacetylene Having a L-Valinol Residue and Two Hydroxy Groups (2009)
  • Author(s): Toshiki Aoki
  • Organizer: International Symposium on Fusion Tech 2009, Incheon
  • Place of Presentation: Incheon, Korea
• [Presentation] Function of one-handed helical backbone of polyphenylacetylenes (2008)
  • Author(s): Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
  • Organizer: The 5th International Symposium on Advanced Materials in Asia-Pacific Rim (5th ISAMAP)
  • Place of Presentation: Zhengzhou, China
• [Presentation] Synthesis and Properties of Chiral Polyphenylacetylenes Having their Chiral Structures Only in the Backbone (2008)
  • Author(s): Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
  • Organizer: International Symposium on Polymer Chemistry (PC'2008, Hefei)
  • Place of Presentation: Hefei, China
• [Presentation] Synthesis of Chiral Polyphenylacetylenes Having their Chiral Structures Only in the Backbone via Desubstitution of the Chiral Groups in Membrane States (2008)
  • Author(s): Toshiki Aoki
  • Organizer: 18th Iketani Conference : Interanational Conferenceof Super-Hierarchical Structures and Innivative Functions of Next-Generation Conjugated Polymers
  • Place of Presentation: Awaji Yumebutai International Conference Center, Hyogo, Japan
• [Presentation] Synthesis and Properties of Chiral Polyphenylacetylenes Having their Chiral Structures Only in the Backbone (2008)
  • Author(s): Toshiki Aoki
  • Organizer: International Symposium on Polymer Chemistry (PC' 2008, Hefei)
  • Place of Presentation: Hefei, China
• [Presentation] Application of Chiral Helical Poly (phenylacetylene)s for Optical Resolution (2007)
  • Author(s): Shingo Hadano
  • Organizer: The 4th International Symposium on Advanced Materials in Asia-Pacific Rim
  • Place of Presentation: Niigata
  • Year and Date: 2007-07-14
• [Patent(Industrial Property Rights)] ポリフェニルアセチレン膜の芳香環形成による超分子自立膜の製造方法 (2009)
  • Inventor(s): 青木俊樹、金子隆司、浪越毅、寺口昌宏、鬼山祥幸、波多野慎悟、エディマルワンタ
  • Industrial Property Rights Holder: 新潟大学
  • Filing Date: 2009
• [Patent(Industrial Property Rights)] ポリフェニルアセチレン膜の芳香環形成による超分子自立膜の製造方法 (2009)
  • Inventor(s): 青木俊樹, ら
  • Industrial Property Rights Holder: 新潟大学
  • Industrial Property Number: 2009-038313
  • Filing Date: 2009-02-20