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Fabrication of high performance thermoelectric module and preparation of strontium titanate for thermoelectric material

Research Project

Project/Area Number 19360133
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 電力工学・電気機器工学
Research InstitutionTokyo University of Science

Principal Investigator

WATANABE Tsuneo  Tokyo University of Science, 基礎工学部, 教授 (70110947)

Co-Investigator(Kenkyū-buntansha) NISHIO Keishi  東京理科大学, 基礎工学部, 准教授 (90307710)
浜田 典昭  東京理科大学, 理工学部, 教授 (00126145)
飯田 努  東京理科大学, 基礎工学部, 准教授 (20297625)
常盤 和靖  東京理科大学, 基礎工学部, 講師 (60307709)
Co-Investigator(Renkei-kenkyūsha) HAMADA Noriaki   (00126145)
IIDA Tsutomu   (20297625)
TOKIWA Kazuyasu   (60307709)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2009: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2008: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2007: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Keywords熱電変換材料 / 熱電変換 / 金属酸化物 / 環境低負荷発電 / クエン酸錯体 / 通電パルス焼結 / チタン酸ストロンチウム / イットリウム添加 / 放電プラズマ焼結 / チタン酸ストロンチウ
Research Abstract

For the application to the thermoelectric device, layered metal oxide bulk ceramics were prepared by the spark plasma sintering method with fine metal oxide powders prepared using metal-organic compound decomposition method. Theoretical Seebeck coefficients of the Y doped SrTiO_3 and Sr_2TiO_4 were calculated by the first principles method. The results were compared with the experimental ones. Finally, we presented the fabrication of the high performance thermoelectric module.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (41 results)

All 2009 2008 2007 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (25 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] ゾル-ゲル法と放電プラズマ焼結法を併用した機能性セラミックスの創製2009

    • Author(s)
      西尾圭史
    • Journal Title

      J. the Inorganic Materials, Japan 16巻

      Pages: 62-67

    • NAID

      10024655278

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of delafossite CuYO2 by metal-citric acid complex decomposition method2009

    • Author(s)
      Keishi Nishio, Tomomi Okada, Naoto Kikuchi, Satoshi Mikusu, Tsutomu Iida, Kazuyasu Tokiwa, Tsuneo Watanabe, Tohru Kineri
    • Journal Title

      Mater. Res. Soc. Symp. Proc. 116巻

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermoelectric properties of Sb-doped sintered Mg2Si fabricated using commercial polycrystalline sources, Materials and Devices for Thermal-to-Electric Energy Conversion2009

    • Author(s)
      N. Fukushima, T. Iida, M. Akasaka, T. Nemoto, T. Sakamoto, R. Kobayashi, H. Taguchi, K. Nishio, Y. Takanashi
    • Journal Title

      Mater. Res. Soc. Proc. 1166巻

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of delafossite CuYO_2 by metal-citric acid complex decomposition method2009

    • Author(s)
      Keishi Nishio, 他8名
    • Journal Title

      Materials and Devices for Thermal-to-Electric Energy Conversion(Mater.Res.Soc.Proc.) 116

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermoelectric properties of Sb-doped sintered Mg_2Si fabricated using commercial polycrystalline sources2009

    • Author(s)
      N.Fukushima, 他8名
    • Journal Title

      Materials and Devices for Thermal-to-Electric Energy Conversion(Mater.Res.Soc.Proc.) 116

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Output power characteristics of Mg_2Si and the fabrication of a Mg_2Si TE module with a uni-leg structure2009

    • Author(s)
      T.Nemoto, 他8名
    • Journal Title

      Materials and Devices for Thermal-to-Electric Energy Conversion(Mater.Res.Soc.Proc.) 116

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and thermoelectric properties of Y doped SrTiO3 by modified Pechini's method, Thermoelectric Power Generation Mater.2008

    • Author(s)
      H. Takenouchi, T. Imai, H. Mae, M. Fujimoto, T. Kineri, T. Iida, N. Hamada, T. Watanabe, K. Nishio
    • Journal Title

      Mater. Res. Soc. Proc. Vol.1044

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Mg2Si from a Reused-silicon Source and its Thermoelectric Characteristics, Thermoelectric Power Generation2008

    • Author(s)
      M. Akasaka, T. Iida, Y. Mito, T. Omori, Y. Oguni, S. Yokoyama, K. Nishio, Y. Takanashi
    • Journal Title

      Mater. Res. Soc. Proc. Vol.1044

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and properties of Srn+1TinO3n+1 Ruddlesden-popper homologous series by metal-citric acid complex decomposition method, Thermoelectric Power Generation Mater.2008

    • Author(s)
      K. Nishio, K. Fukuda, H. Takenouchi, H. Mae, M. Fujimoto, T. Imai, N. Hamada, T. Iida, T. Kineri, T. Watanabe
    • Journal Title

      Mater. Res. Soc. Proc. Vol.1044

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermoelectric properties of bulk crystals of n-, p-type Mg2Si prepared by the vertical Bridgman method2008

    • Author(s)
      M. Akasaka
    • Journal Title

      Journal of Applied Physics 104

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and properties of Sr_<n+1>Ti_nO_<3+1> Ruddlesden-popper homologous series by metal-citric acid complex decomposition method2008

    • Author(s)
      K. Nishio
    • Journal Title

      Materials Research Society Symposium Proceedings 1044

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and thermoelectric properties of Y doped SrTiO_3 by modified Pechini's method2008

    • Author(s)
      H. Takenouchi
    • Journal Title

      Materials Research Society Symposium Proceedings 1044

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Composition dependent thermoelectric properties of sintered Mg2Si1-xGex (x=0 to 1) initiated from melt-grown polycrystalline source2007

    • Author(s)
      M. Akasaka, T. Iida, T. Baba, S. Kawakami, K. Nishio, Y. Takanashi
    • Journal Title

      THIN SOLID FILMS 515

      Pages: 8237-8241

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Non-wetting crystal growth of Mg_2Si by vertical Bridgman method and thermoelectric characteristics2007

    • Author(s)
      M. Akasaka
    • Journal Title

      Journal of Crystal Growth 304

      Pages: 196-201

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Direct thermal-to-electric energy conversion material of environmentally-benign Mg2Si synthesized using wasted Si sludge and recycled Mg alloy2009

    • Author(s)
      Yasuhiko Honda, Tsutomu Iida, Tatsuya Sakamoto, ShiroSakuragi, Yutaka Taguchi, Yohiko Mito, Takashi Nemoto, Tadao Nakajima, Hirohisa Taguchi, Keishi Nishio, Yoshifumi Takanashi
    • Organizer
      Materials Research Society Fall Meeting 2009
    • Place of Presentation
      Boston, MA, USA
    • Year and Date
      2009-12-01
    • Related Report
      2009 Final Research Report
  • [Presentation] Preparation of Sr-Ru-O system ceramics by Spark Plasma Sintering method with fine powder from metal-citric acid complex solution2009

    • Author(s)
      Keishi Nishio, Takuro Haraguchi, Tomomi Okada, Junichiro Takahashi, Tsutomu Iida, Kazuyasu Tokiwa, Tohru Kineri, Tsuneo Watanabe
    • Organizer
      Materials Research Society Fall Meeting 2009
    • Place of Presentation
      Boston, MA, USA
    • Year and Date
      2009-12-01
    • Related Report
      2009 Final Research Report
  • [Presentation] Preparation of Sr-Ru-O system ceramics by Spark Plasma Sintering me thod with fine powder from metal-citric acid complex solution2009

    • Author(s)
      Keishi Nishio, 他7名
    • Organizer
      Materials Research Society Fall Meeting 2009
    • Place of Presentation
      Boston(USA)
    • Year and Date
      2009-12-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] Direct thermal-to-electric energy conversion material of environmentally-benign Mg_2Si synthesized using wasted Si sludge and recycled Mg alloy2009

    • Author(s)
      Yasuhiko Honda, 他10名
    • Organizer
      Materials Research Society Fall Meeting 2009
    • Place of Presentation
      Boston(USA)
    • Year and Date
      2009-12-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] Characteristics of a pin-fin structure thermal-to-electric uni-leg device using a commercial n-type Mg2Si source2009

    • Author(s)
      T. Nemoto, T. Iida, J. Sato, Y. Oguni, A. Matsumoto, T. Miyata, T. Sakamoto, T. Nakajima, H. Taguchi, K. Nishio, Y. Takanashi
    • Organizer
      The 28th International Conference on Thermoelectrics and the 7th European Conference on Thermoelectrics
    • Place of Presentation
      Freiburg, Germany
    • Year and Date
      2009-07-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Characteristics of apin-fin structure thermal-to-electric uni-leg device using a commercial n-type Mg_2Si source2009

    • Author(s)
      T.Nemoto, 他11名
    • Organizer
      The 28th International Conference on Thermoelec trics and the 7th European Conference on Therm oelectrics
    • Place of Presentation
      Freiburg, Germany
    • Year and Date
      2009-07-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Thermoelectric characteristics of commercialized Mg_2Si source doped with Al, Bi, Ag and Cu2009

    • Author(s)
      T.Sakamoto, 他10名
    • Organizer
      The 28th International Conference on Thermoelec tries and the 7th European Conference on Therm oelectrics
    • Place of Presentation
      Freiburg, Germany
    • Year and Date
      2009-07-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Preparation of delafossite CuYO2 by metal-citric acid complex decomposition method2009

    • Author(s)
      Tomomi Okada, Naoto Kikuchi, Satoshi Mikusu, Tsutomu Iida, Kazuyasu Tokiwa, Tsuneo Watanabe, Tohru Kineri, Keishi Nishio
    • Organizer
      MATERIALS RESEARCH SOCIETY 2009 Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2009-04-14
    • Related Report
      2009 Final Research Report
  • [Presentation] Thermoelectric properties of Sb-doped sintered Mg2Si fabricated using commercial polycrystalline sources2009

    • Author(s)
      N. Fukushima, T. Iida, M. Akasaka, T. Nemoto, T. Sakamoto, R. Kobayashi, H. Taguchi, K. Nishio, Y. Takanashi
    • Organizer
      MATERIALS RESEARCH SOCIETY 2009 Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2009-04-14
    • Related Report
      2009 Final Research Report
  • [Presentation] Raman scattering characterization for crystalline quality of doped n-type Mg2Si prepared by melt growth and plasma activated sintering techniques2009

    • Author(s)
      D. Mori, T. Iida, T. Nemoto, M. Ogi, M. Akasaka, K. Nishio, H. Taguchi, Y. Takanashi
    • Organizer
      MATERIALS RESEARCH SOCIETY 2009 Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2009-04-14
    • Related Report
      2009 Final Research Report
  • [Presentation] Preparation of delafossite CuYO_2 by metal-citric acid complex decomposition method2009

    • Author(s)
      Tomomi Okada, 他7名
    • Organizer
      MATERIALS RESEARCH SOCIETY 2009 Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2009-04-14
    • Related Report
      2009 Annual Research Report
  • [Presentation] Raman scattering characterization for crystalline quality of doped n-type Mg_2Si prepared by melt growth and plasma activated sintering techniques2009

    • Author(s)
      D.Mori, 他7名
    • Organizer
      MATERIALS RESEARCH SOCIETY 2009 Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2009-04-14
    • Related Report
      2009 Annual Research Report
  • [Presentation] Thermoelectric properties of Sb-doped sintered Mg_2Si fabricated using commercial polycrystalline sources2009

    • Author(s)
      N.Fukushima, 他8名
    • Organizer
      MATERIALS RESEARCH SOCIETY 2009 Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2009-04-14
    • Related Report
      2009 Annual Research Report
  • [Presentation] SrTiO3基板表面の平坦化の検討2009

    • Author(s)
      林良和・渡部一訓・姫野修平・三楠聰・常盤和靖・渡辺恒夫
    • Organizer
      日本セラミックス協会2009年年会
    • Place of Presentation
      東京理科大学野田キャンパス
    • Year and Date
      2009-03-17
    • Related Report
      2009 Final Research Report
  • [Presentation] クエン酸金属錯体の熱分解法によるCuY1-xCaxO2の合成2008

    • Author(s)
      岡田友美・菊池直人・飯田努・三楠聰・常盤和靖・渡辺恒夫・木練透・安盛敦雄・西尾圭史
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2008-09-17
    • Related Report
      2009 Final Research Report
  • [Presentation] クエン酸金属錯体の熱分解法によるCuY1-xCaxO2 の合成2008

    • Author(s)
      岡田友美
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2008-09-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] クエン酸熱分解法によるCuYO2の低温合成2008

    • Author(s)
      岡田友美, 菊地直人, 竹之内宏文, 飯田努, 渡辺恒夫, 西尾圭史
    • Organizer
      第24回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      神奈川県足柄下郡箱根町・ホテル花月園
    • Year and Date
      2008-07-24
    • Related Report
      2009 Final Research Report
  • [Presentation] Electrical characteristics and thermal stability of Ni electrode for n-Mg2Si prepared by plasma activated sintering method2008

    • Author(s)
      Y. Oguni, T. Iida, A. Matumoto, T. Nemoto, J. Onosaka, H. Takaniwa, T. Sakamoto, D. Mori, M. Akasaka, J. Sato, T. Nakajima, K. Nishio, Y. Takanashi
    • Organizer
      European Materials Research Society
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2008-05-27
    • Related Report
      2009 Final Research Report
  • [Presentation] Thermoelectric characteristics of n-type Mg2Si, fabricated by melt growth and plasma activated sintering methods using a reused-silicon source2008

    • Author(s)
      T. Nemoto, T. Iida, R. Ogawa, M. Akasaka, M. Fukano, Y. Mito, Y. Taguchi, S. Yokoyama, S. Sakuragi, K. Nishio, H. Taguchi, T. Nakajima, Y. Takanashi
    • Organizer
      European Materials Research Society
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2008-05-27
    • Related Report
      2009 Final Research Report
  • [Presentation] Preparation and properties of Srn+1TinO3+1 Ruddlesden-popper homologous series by metal-citric acid complex decomposition method2007

    • Author(s)
      K. Nishio, K. Fukuda, H. Takenouchi, H. Mae, M. Fujimoto, T. Imai, N. Hamada, T. Iida, T. Kineri, T. Watanabe
    • Organizer
      Materials Research Society 2007 Fall Meeting
    • Place of Presentation
      Boston, MA, U.S.A.
    • Year and Date
      2007-11-26
    • Related Report
      2009 Final Research Report
  • [Presentation] Fabrication of Mg2Si from a Reused-silicon Source and its Thermoelectric Characteristics2007

    • Author(s)
      M. Akasaka, T. Iida, Y. Mito, T. Omori, Y. Oguni, S. Yokoyama, K. Nishio, Y. Takanashi
    • Organizer
      Materials Research Society 2007 Fall Meeting
    • Place of Presentation
      Boston, MA, U.S.A.
    • Year and Date
      2007-11-26
    • Related Report
      2009 Final Research Report
  • [Presentation] Takanashi, Doping characteristics of silver in Mg2Si(1-x)Gex prepared by plasma activated sintering method2007

    • Author(s)
      T. Nemoto, J. Sato, T. Iida, M. Akasaka, T. Nakajima, K. Nishio, Y. Takanashi
    • Organizer
      Materials Research Society 2007 Fall Meeting
    • Place of Presentation
      Boston, MA, U.S.A.
    • Year and Date
      2007-11-26
    • Related Report
      2009 Final Research Report
  • [Presentation] Synthesis and thermoelectric properties of Y doped SrTiO3 by modified Pechini's method2007

    • Author(s)
      H. Takenouchi, T. Imai, H. Mae, M. Fujimoto, T. Kineri, T. Iida, N. Hamada, T. Watanabe, K. Nishio
    • Organizer
      Materials Research Society 2007 Fall Meeting
    • Place of Presentation
      Boston, MA, U.S.A.
    • Year and Date
      2007-11-26
    • Related Report
      2009 Final Research Report
  • [Presentation] Preparation and properties of Sr_<n+1>Ti_nO_<3+1> Ruddlesden-popper homologous series by metal-citric acid complex decomposition method2007

    • Author(s)
      Keishi Nishio
    • Organizer
      Materials Research Society 2007 Fall Meeting
    • Place of Presentation
      Boston, MA, U.S.A.
    • Year and Date
      2007-11-26
    • Related Report
      2007 Annual Research Report
  • [Presentation] Preparation of Y-doped SrTiO3 by modified Pechini's method2007

    • Author(s)
      H. Takenouchi, T. Imai, H. Mae, M. Fujimoto, T. Kineri, T. Iida, N. Hamada, T. Watanabe, K. Nishio
    • Organizer
      7th Pacific Rim Conference on Ceramic and Glass Technology, Shanghai International Convention Center
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-11-14
    • Related Report
      2009 Final Research Report
  • [Remarks] 研究室HP

    • URL

      http://web.mac.com/nishiolabl/

    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 熱電変換材料およびその製造方法2007

    • Inventor(s)
      飯田努
    • Industrial Property Rights Holder
      東京理科大学
    • Acquisition Date
      2007-12-20
    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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