Fabrication of Nanoarchitecture Using Self-Assembly of Dendritic Molecule Having Photofunctionality

• Project/Area Number: 19510105
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Nanostructural science
• Research Institution: Okayama University
• Principal Investigator: TAKAGUCHI Yutaka Okayama University, 大学院・環境学研究科, 准教授 (10293482)
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000); Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2007: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
• Keywords: デンドリマー / 自己組織化 / ゲル / 光応答性 / フラーレン / 液晶 / 光触媒 / 蛍光プローブ / フラロデンドロン / LB膜 / 一重項酸素 / 有機薄膜トランジスタ / 有機半導体 / CdSクラスター

Research Abstract

ナノメートルスケールの構造をボトムアップアプローチで構築するための構成単位として, 光機能性部位持つデンドロンが有用であることを見出した。フラーレンをはじめとする光機能性部位をナノ構造材料中に規則正しく配置することで, 光応答性をはじめとする様々な機能発現が見出された。

Research Products

• [Journal Article] Photoinducedisomerization of allyl alcohols tocarbonyl compounds using dendrimerdisulfide as catalyst (2009)
  • Author(s): Tsuboi, Takaaki ; Takaguchi, Yutaka ; Tsuboi, Sadao
  • Journal Title: Heteroatom Chemistry 20 Pages: 1-11
• [Journal Article] Photoinduced isomerization of allyl alcohols to carbonyl compounds using dendrimer disulfideas catalyst (2009)
  • Author(s): Tsuboi, Takaaki, Takaguchi, Yutaka, Tsuboi, Sadao
  • Journal Title: Heteroatom Chemistry 20 Pages: 1-11
  • Peer Reviewed
• [Journal Article] A photo-responsive hydrogelator havinggluconamides at peripheral branches (2008)
  • Author(s): Sako, Yuuki ; Takaguchi, Yutaka
  • Journal Title: Organic and Biomolecular Chemistry 6 Pages: 3843-3847
• [Journal Article] シアノビフェニル基末端に持つフラロデンドロンの合成と液晶性 (2008)
  • Author(s): 酒向祐輝, 高口豊
  • Journal Title: 繊維学会誌 64(11) Pages: 324-328
• [Journal Article] A high performance oxidation method for secondary alcohols by inductive activation of TEMPO in combination with pyridine-bromine complexes (2008)
  • Author(s): Mei, Zhen-Wu ; Omote, Takumi ; Mansour, Mounir ; Kawafuchi, Hiroyuki ; Takaguchi, Yutaka ; Jutand, Anny ; Tsuboi, Sadao ; Inokuchi, Tsutomu
  • Journal Title: Tetrahedron 64 Pages: 10761-10766
• [Journal Article] Preparation and electrochemical and optical properties of unsymmetrically substituted phthalocyanines with one or two trithi le rings and related symmetric derivatives (2008)
  • Author(s): Kimura, Takeshi ; Kanota, Nagisa ; Matsui, Kenji ; Tanaka, Ichiro ; Tsuboi, Takaaki ; Takaguchi, Yutaka ; Yomogita, Akinori ; Wakahara, Takatsugu ; Kuwahara, Shunsuke ; Nagatsugi, Fumi ; Akasaka, Takeshi
  • Journal Title: Inorganic Chemistry 47(9) Pages: 3577-3583
• [Journal Article] Novel fluorescent probe based on anthryl dendron having oligo(ethyleneoxide)groups at the terminals (2008)
  • Author(s): Takaguchi, Yutaka ; Yasushi Yanagimoto
  • Journal Title: Okayama Daigaku Kankyo Rikogakubu Kenkyu Hokoku 13(1) Pages: 121-124
  • NAID: 120002304793
• [Journal Article] Novel photoreaction using diphenyl disulfide derivatives : photoinduced oxidation of allyl Alcohol (2008)
  • Author(s): Tsuboi, Takaaki ; Takaguchi, Yutaka ; Tsuboi, Sadao
  • Journal Title: Bulletin of the Chemical Society of Japan 81(3) Pages: 361-368
  • NAID: 10021074351
• [Journal Article] Preparation and photosensitizing property of novel Cd_<10>S_<16> molecular cluster dendrimer (2008)
  • Author(s): Tsuboi, Takaaki ; Takaguchi, Yutaka ; Tsuboi, Sadao
  • Journal Title: Chemical Communications (1) Pages: 76-78
• [Journal Article] A photo-responsive hydrogelator having gluconamides at peripheral branches (2008)
  • Author(s): Sako, Yuuki, Takaguchi, Yutaka
  • Journal Title: Organic and Bioraolecular Chemistry 6 Pages: 3843-3847
  • Peer Reviewed
• [Journal Article] シアノビフェニル基末端に持つフラロデンドロンの合成と液晶性 (2008)
  • Author(s): 酒向祐輝, 高口 豊
  • Journal Title: 繊維学会誌 64 Pages: 324-328
  • Peer Reviewed
• [Journal Article] A high performance oxidation method for secondary alcohols by inductive activation of TEMPO in combination with pyridine-bromine complexes (2008)
  • Author(s): Mei, Zhen-Wu, Omote, Takumi, Mansour, Mounir, Kawafuchi, Hiroyuki, Takaguchi, Yutaka, Jutand, Anny, Tsuboi, Sadao, Inokuchi, Tsutomu
  • Journal Title: Tetrahedron 64 Pages: 10761-10766
  • Peer Reviewed
• [Journal Article] Preparation and electrochemical and optical properties of unsymmetrically substituted phthalocyanines with one or two trithiole rings and related symmetric derivatives (2008)
  • Author(s): Kimura, Takeshi, Kanola, Nagisa, Matsui, Kenji, Takaguchi, Yutaka, Yomogita, Akinori, Nagatsugi, Fumi, Akasaka, Takeshi
  • Journal Title: Inorganic Chemistry 47 Pages: 3577-3583
  • Peer Reviewed
• [Journal Article] Novel fluorescent probe based on anthryl dendron havingoligo(ethyleneoxide)groups at the terminals (2008)
  • Author(s): Takaguchi, Yutaka, Yasushi Yanagimot
  • Journal Title: Okayama Daigaku Kankyo Rikogakubu Kenkyu Hokoku 13 Pages: 121-124
  • Peer Reviewed
• [Journal Article] Novel photoreaction using diphenyl disulfide derivatives: photoinduced oxidation of allyl Alcohol (2008)
  • Author(s): Tsuboi, Takaaki; Takaguchi, Yutaka; Tsuboi, Sadao
  • Journal Title: Bulletin of the Chemical Society of Japan 81 Pages: 361-368
  • NAID: 10021074351
  • Peer Reviewed
• [Journal Article] Preparation and photosensitizing property of novel Cd10S16 molecular cluster dendrimer (2008)
  • Author(s): Tsuboi, Takaaki; Takaguchi, Yutaka; Tsuboi, Sadao
  • Journal Title: Chemical Communications 2008 Pages: 76-78
  • Peer Reviewed
• [Journal Article] Transport properties of field-effect transistor with Langmuir-Blodgett films of C_<60> dendrimer and estimation of impurity levels (2007)
  • Author(s): Kawasaki, Naoko ; Nagano, Takayuki ; Kubozono, Yoshihiro ; Sako, Yuuki ; Morimoto, Yu ; Takaguchi, Yutaka ; Fujiwara,Akihiko; Chu, Chih-Chien ; Imae, Toyoko
  • Journal Title: Applied Physics Letters 91(24)
• [Journal Article] Effect of the photolysis of dendritic caged compound within the vaterite crystal on the crystalline phase transformation (2007)
  • Author(s): Yanagimoto, Yasushi ; Takaguchi, Yutaka ; Tsuboi, Sadao ; Watanabe, Soichiro ; Iwamura, Michiko
  • Journal Title: ITE Letters on Batteries, New Technologies & Medicine 8(3) Pages: 277-282
• [Journal Article] One-pot synthesis of 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction of 4-arylthio-3-hydroxy-2-pyrones (2007)
  • Author(s): Komiyama, Takuzo ; Takaguchi, Yutaka ; Tsuboi, Sadao
  • Journal Title: Synthetic Communications 37(13) Pages: 2131-2136
• [Journal Article] Synthesis of 4-arylthio-3-hydroxyphthalate by the Diels-Alder reaction of 4-arylthio-3-hydroxy-2-pyrone (2007)
  • Author(s): Komiyama, Takuzo ; Takaguchi, Yutaka ; Tsuboi, Sadao
  • Journal Title: Synthetic Communications 37(4) Pages: 531-534
• [Journal Article] Transport properties of field-effect transistor with Langmuir-Blodgett films of C60 dendrimer and estimation of impurity levels (2007)
  • Author(s): Kawasaki, Naoko Nagano, Takayuki; Kubozono, Yoshihiro; Sako, Yuuki; Morinoto, Yu; Takaguchi, Yutaka; Fujiwara, Akiliko; Chu, Chih-Chien; Imae, Toyoko
  • Journal Title: Applied Physics Letters 91
  • Peer Reviewed
• [Journal Article] Effect of the photolysis of dendritic caged compound within the vaterite crystal on the crystalline phase transformation (2007)
  • Author(s): Yanagimoto, Yasushi; Takaguchi, Yutaka; Tsuboi, Sadao; Watanabe, Soichiro; Iwamura, Michiko
  • Journal Title: ITE Letters on Batteries, New Technologies & Medicine 8 Pages: 277-282
  • Peer Reviewed
• [Journal Article] One-potsynthesis of 2-arylthio-2-cyclohexenone derivatives by the Diels-Alder reaction of 4-arylthio-3-hvdroxy-2-pyrones (2007)
  • Author(s): Komiyama, Takuzo; Takaguchi, Yutaka; Tsuboi, Sadao
  • Journal Title: Synthetic Communications 37 Pages: 2131-2136
  • Peer Reviewed
• [Journal Article] Synthesis of 4-arylthio-3-hydroxyphthalate by the Diels-Alder reaction of 4-arylthio-3-hydroxy-2-pyrone",2007, 37(4),531-534. (2007)
  • Author(s): Komiyama, Takuzo; Takaguchi, Yutaka; Tsuboi, Sadao
  • Journal Title: Synthetic Communications 37 Pages: 531-534
  • Peer Reviewed
• [Presentation] Water-Dispersible Fullerene Whisker (2009)
  • Author(s): Yasuhiko Fujita, Yutaka Takaguchi
  • Organizer: Abstract of the 36th Fullerene-Nanotube General Symposium(168)
• [Presentation] EnantiomericSeparation of Fullerodendron Formed byDiastereoselective Diels-Alder Reaction (2009)
  • Author(s): Naoki Tsugawa, Nobuhiro Takahashi,Yutaka Takaguchi
  • Organizer: Abstract of the 36th Fullerene-Nanotube General Symposium(119)
• [Presentation] Fabrication of CaCO_<3>/SWNT Nanocomposite Using Fullerodendron-Assisted Approach (2009)
  • Author(s): Akira Tsutsui, Yutaka Takaguchi
  • Organizer: Abstract of the 36th Fullerene-Nanotube General Symposium(101)
• [Presentation] Dispersion of Single-Walled Carbon Nanotubes Using Poly(amidoamine)Dendrimer Having Alkyl Chain at the Core (2009)
  • Author(s): Ryouta Ikeuchi, Tetsuya Uchida, TatsuoFujii, Jun Takada, Yutaka Takaguchi
  • Organizer: Abstract of the 36th Fullerene-Nanotube General Symposium(99)
• [Presentation] 分子を並べて創る有機機能材料 : ナノカーボンで挑むメソ構造と機能 (2008)
  • Author(s): 高口豊
  • Organizer: 近畿大学理工学部応用化学科「応用化学セミナー」
  • Year and Date: 2008-11-08
• [Presentation] 末端にジエチレンオキシド部位を持つ双性イオン型フラロデンドロンの生成 (2008)
  • Author(s): 細川真希, 高口豊
  • Organizer: 第35回有機典型元素化学討論会要旨集(361-362)
• [Presentation] フラロデンドロンを用いた新規機能性材料の創製 (2008)
  • Author(s): 高口豊
  • Organizer: 第17回ポリマー材料フォーラム講演予稿集(160)
• [Presentation] 水分散性フラーレンウィスカー (2008)
  • Author(s): 藤田泰彦, 高口豊
  • Organizer: 第17回ポリマー材料フォーラム講演予稿集(74)
• [Presentation] ポリアミドアミンデンドリマーを利用したフッ素イオンセンシング (2008)
  • Author(s): 山路大介, 高口豊
  • Organizer: 第17回ポリマー材料フォーラム講演予稿集(199)
• [Presentation] 末端にジエチレンオキシド部位を持つ双性イオン型フラロデンドロンの生成 (2008)
  • Author(s): 細川真希, 高口豊
  • Organizer: 第23回中国四国地区高分子若手研究会講演要旨集(PA01)
• [Presentation] 末端にシアノビフェニル基を持つアントリルデンドロンの自己組織化と光反応性 (2008)
  • Author(s): 徳光俊和, 酒向祐輝, 市原正寛, 太田和親, 高口豊
  • Organizer: 第23回中国四国地区高分子若手研究会講演要旨集(PB01)
• [Presentation] フラロデンドロンを利用した炭酸カルシウム/単層カーボンナノチューブ複合体の作製 (2008)
  • Author(s): 筒井徹, 高口豊
  • Organizer: 第23回中国四国地区高分子若手研究会講演要旨集(PB02)
• [Presentation] 2, 9位にデンドロン型置換基を持つ6, 13-ジヒドロペンタセン誘導体の合成と性質 (2008)
  • Author(s): 山川晃生, 高口豊
  • Organizer: 第23回中国四国地区高分子若手研究会講演要旨集(PB02)
• [Presentation] アルキル鎖をコアに持つポリアミドアミンデンドリマーを用いた単層カーボンナノチューブの可分散化 (2008)
  • Author(s): 池内亮太, 内田哲也, 藤井達生, 高田潤, 高口豊
  • Organizer: Polymer Preprints, Japan(Vol.57, No.2)
• [Presentation] 2, 7位に置換基を持つアントラセン誘導体の自己組織化と光反応性 (2008)
  • Author(s): 中野正浩, 市原正寛, 太田和親, 高口豊
  • Organizer: Polymer Preprints, Japan(Vol.57, No.2)
• [Presentation] 2, 7位に置換基を持つアントラセン誘導体の分子集合状態と光反応性 (2008)
  • Author(s): 中野正浩, 市原正寛, 太田和親, 高口豊
  • Organizer: 2008光化学討論会講演要旨集(39)
• [Presentation] Cd10S16分子クラスターデンドリマーの合成と一重項酸素光増感作用 (2008)
  • Author(s): 高口豊, 塩本陽平, 坪井隆明
  • Organizer: 2008光化学討論会講演要旨集(326)
• [Presentation] Fabrication of CaCO3/SWNT nanocomposite using fullerodendron-assisted approach (2007)
  • Author(s): Yutaka Takaguchi, Shuhei Hayakawa, Yuuki Sakoa, Sadao Tsuboi
  • Organizer: International Dendrimer Symposium 5
  • Place of Presentation: トゥールーズ(フランス)
  • Year and Date: 2007-08-31
• [Presentation] Self-Assembly and Photoreactivity of Disubstituted Anthracenes",p.293(2007). (2007)
  • Author(s): Yutaka Takaguchi, Yuuki Sako, Sho Kaneko, Sadao Tsuboi
  • Organizer: 23rd International Conference on Photochemistry(IPC2007)
  • Place of Presentation: ケルン(ドイツ)
  • Year and Date: 2007-07-30
• [Book] ナノカーボンハンドブック(株式会社エヌ・ティー・エス) (2007)
  • Author(s): 高口豊
  • Publisher: CNT/フラロデンドロン超分子複合体 : CNTの外側にフラーレンを付着させた新規複合材料
• [Book] ナノカーボンハンドブック(の一部「CNT/フラロデンドロン複合体」) (2007)
  • Author(s): 高口 豊
  • Total Pages: 8
  • Publisher: 株式会社エヌティーエス
• [Remarks] (1)日経産業新聞(2008年12月11日11面)に水分散性フラーレンウィスカーに関する以下の記事が掲載された。
• [Remarks] (2)セラミックス(2009年3月号44ページ)に水分散性フラーレンウィスカーに関する以下の記事が掲載された。
• [Remarks] (3)高分子(2009年4月号174ページ)にフラロデンドロンの自己組織化による機能性材料構築に関する以下の記事が掲載された。
• [Remarks] 研究成果は以下のホームページ上で常に最新のものを公開している。
  • URL: http://150.46.228.3/yuki/index.htm
• [Remarks]
  • URL: http://www.ecm.okayama-u.ac.jp/yuki/index.htm
• [Remarks]
  • URL: http://www.ecm.okayama-u.ac.jp/yuki/index.htm
• [Patent(Industrial Property Rights)] 溶解性の高いペンタセン化合物およびそれを用いた有機半導体素子 (2009)
  • Inventor(s): 高口豊, 金子聖, 堀田清行, 小松利喜
  • Industrial Property Rights Holder: 岡山大学, チッソ石油化学株式会社, チッソ株式会社
  • Industrial Property Number: 2007-238078
  • Filing Date: 2009-09-13
• [Patent(Industrial Property Rights)] 新規デンドリマーおよびその用途 (2009)
  • Inventor(s): 高口豊, 池内亮太
  • Industrial Property Rights Holder: 岡山大学
  • Industrial Property Number: 2009-035490
  • Filing Date: 2009-02-18
• [Patent(Industrial Property Rights)] 新規デンドリマー及びその用途 (2009)
  • Inventor(s): 高口 豊, 池内亮太
  • Industrial Property Rights Holder: 岡山大学
  • Industrial Property Number: 2009-035490
  • Filing Date: 2009-02-18
• [Patent(Industrial Property Rights)] フラーレン誘導体の製造方法およびフラーレン誘導体 (2007)
  • Inventor(s): 高口 豊
  • Industrial Property Rights Holder: 独立行政法人科学技術振興機構
  • Acquisition Date: 2007-08-31