Structural control of peroxoheteropolytungstates :the role ofthe solvent and counter cations
Project/Area Number |
19550065
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
|
Research Institution | Wakayama University |
Principal Investigator |
HASHIMOTO Masato Wakayama University, システム工学部, 教授 (50237947)
|
Project Period (FY) |
2007 – 2010
|
Project Status |
Completed (Fiscal Year 2010)
|
Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2007: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
|
Keywords | ポリオキソメタレート / 金属過酸化物 / タングステン / 溶液内錯形成反応 / 結晶構造 / 構造制御 / 多核NMR / 自己集積化 / ヘテロポリオキソメタレート / ペルオキソ錯体 / 錯形成反応 / 溶媒 / 対陽イオン / 溶液内反応 / 超分子化学 |
Research Abstract |
A peroxopolytungstate is an anionic aggregate of tungsten peroxides. Effe cts of solvent compositions and coexisting canons to build up peroxopolytungstateswere examined. Solvents did not affect so much in the range of the present work. On the other hand coexisting cations showed significant effects on the composition, structure and amount of the anion.
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Report
(6 results)
Research Products
(58 results)