| Project/Area Number |
19685004
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
WAKAMIYA Atsushi Nagoya University, 化学研究所, 准教授 (60362224)
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| Co-Investigator(Renkei-kenkyūsha) |
YAMAGUCHI Shigehiro 名古屋大学, 大学院・理学研究科, 教授 (60260618)
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| Project Period (FY) |
2007 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥24,960,000 (Direct Cost: ¥19,200,000、Indirect Cost: ¥5,760,000)
Fiscal Year 2009: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2008: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2007: ¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
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| Keywords | 有機元素化学 / ホウ素 / π電子系 / 機能性材料 / 吸収スペクトル / 蛍光スペクトル / 1,2ジボリン / ホウ素置換基 / π共役系 |
|---|
| Research Abstract |
Utilization of boron, a group 13 element, as a key element for developing new functional electronic and optoelectronic materials is an important direction in the organoboron chemistry. Boron has several characteristic features, such as trigonal planar geometry for trivalent boron compounds, high Lewis acidity, and effective orbital interaction with π-conjugated frameworks through the vacant p-orbital (i.e., p_π-π* conjugation). Exploiting these features of the boron element for molecular designs, we succeeded in the creation of some sophisticated π-electron materials having attractive photophysical and electronic properties, such as high electron mobility and highly emission in the solid state.
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