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Development of Fluorous and Magnetic Catalytic Reactions for Green Chemistry

Research Project

Project/Area Number 19750128
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Environmental chemistry
Research InstitutionThe Noguchi Institute

Principal Investigator

YOSHIDA Akihiro  The Noguchi Institute, 研究部, 研究員 (10292301)

Project Period (FY) 2007 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥3,830,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥630,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2007: ¥1,100,000 (Direct Cost: ¥1,100,000)
Keywordsフルオラス化学 / ルイス酸触媒 / 多相系反応 / スルホンイミド / 磁性触媒 / グリーンケミストリー / PFOS問題 / イオン液体 / エステル化反応
Research Abstract

Several fluorous catalysts and media were developed for green chemistry. That is to say, development of fluorous Lewis acid of late transition metal with fluorous sulfonimide ligands, ethereal oxygen-containing fluorous Lewis acid for the counter-measure against the problem of PFOS, fluorous ionic liquid and fluorous mesoporous silica gel was accomplished. Development of the reactions using iron oxide nanoparticle was performed as a magnetic catalytic reactions.

Report

(6 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report   Self-evaluation Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (32 results)

All 2011 2010 2009 2008 2007 Other

All Journal Article (7 results) (of which Peer Reviewed: 5 results) Presentation (17 results) Book (3 results) Remarks (1 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] フルオラスLewis酸触媒反応の開発2011

    • Author(s)
      吉田彰宏
    • Journal Title

      Fluorine 3巻

      Pages: 10-16

    • Related Report
      2010 Final Research Report
  • [Journal Article] フルオラスLewis酸触媒反応の開発2011

    • Author(s)
      吉田彰宏
    • Journal Title

      Fluorine

      Volume: 3巻 Pages: 10-16

    • Related Report
      2010 Annual Research Report
  • [Journal Article] "Formation of O-Glycosidic Linkages from l-Hydroxy Sugars by Bismuth(III) Triflate-Catalyzed Dehydrative Glycosidation"2009

    • Author(s)
      Yamanoi, T; houe, R; Matsuda, S; Iwao, K; Oda, Y; Yoshida, A; Hamasaki, K.
    • Journal Title

      Heterocycles 77

      Pages: 445-460

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recyclable Hafnium(IV) Bis(perfluorooctanesulfonyl) amide Complex for Catalytic Friedel-Crafts acylation and Prins Reaction in Fluorous Biphase System2007

    • Author(s)
      X.Hao, A.Yoshida, N.Hoshi
    • Journal Title

      J.Fluorine Chem. 128巻

      Pages: 1396-1401

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Recyclable Hafnium(IV) Bis(perfluoro-octanesulfonyl)amide Complex for Catalytic Friedel-Crafts acylation and Prins Reaction in Fluorous Biphase System2007

    • Author(s)
      X. Hao, A. Yoshida, N. Hoshi
    • Journal Title

      J. Fluorine Chem. 128

      Pages: 1396-1401

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] "Recyclable Hafnium (IV) Bis (perfluorooctanesulfonyl) amide Complex for Catalytic Friedel-Crafts acylation and Prins Reaction in Fluorous Biphase System"2007

    • Author(s)
      Xiuhua Hao, Akihiro Yoshida, and Nobuto Hoshi
    • Journal Title

      Journal of Fluorine Chemistry 128

      Pages: 1396-1401

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Synthetic Approach to exo-Glycals from 1-C-Vinyl-D-glycopyranose Derivatives via an SN1'-Substitution Mechanism"2007

    • Author(s)
      Takashi Yamanoi, Yukari Nara, Sho Matsuda, Yoshiki Oda, Akihiro Yoshida, Kaname Katsuraya, Mikio Watanabe
    • Journal Title

      Synlett 2007

      Pages: 785-789

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] フルオラスケミストリーに基づくLewis酸触媒反応の開発2010

    • Author(s)
      吉田彰宏
    • Organizer
      茨城大学講演会
    • Place of Presentation
      茨城大(茨城県)
    • Year and Date
      2010-12-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Bfp基結合型フルオラスクラウンエーテル類の合成と有機合成反応への利用2010

    • Author(s)
      山ノ井孝, 小池健仁, 小田慶喜, 吉田彰宏, 渡邊幹夫
    • Organizer
      フルオラス科学研究会第3回シンポジウム
    • Place of Presentation
      長良川国際会議場(岐阜県)
    • Year and Date
      2010-10-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] フルオラスLewis酸触媒反応の開発2010

    • Author(s)
      吉田彰宏
    • Organizer
      第17回有機フッ素化学セミナー(岡山)その2
    • Place of Presentation
      岡山
    • Year and Date
      2010-09-25
    • Related Report
      2010 Final Research Report
  • [Presentation] フルオラスLewis酸触媒反応の開発2010

    • Author(s)
      吉田彰宏
    • Organizer
      第17回有機フッ素化学セミナー(岡山)その2
    • Place of Presentation
      岡山大(岡山県)
    • Year and Date
      2010-09-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of Fluorous Crown Ethers and Their Application to Fluorous Biphase Organic Reaction2010

    • Author(s)
      Koike, K.; Yamanoi, T.; Oda, Y.; Yoshida, A.; Watanabe, M.
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
    • Place of Presentation
      Hawaii Convention Center (Honolulu)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Nonsulfuric Acid Hydrolysis of Microcrystalline Cellulose by Metal Salts Treatment2010

    • Author(s)
      Katsuraya, K.; Yoshida, N.; Osumi, K.; Yamamoi, T.; Yoshida, A.; Mizuno, M.; Moto, M.; Okamoto, Y.; Murota, A.
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
    • Place of Presentation
      Hawaii Convention Center (Honolulu)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Syntheses of Spirocompounds from 1-C-Vinylated Sugar2010

    • Author(s)
      Yamanoi, T.; Matsuda, S.; Oda, Y.; Yoshida, A.
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
    • Place of Presentation
      Hawaii Convention Center (Honolulu)
    • Related Report
      2010 Annual Research Report
  • [Presentation] フルオラスケミストリーへの適用を目指したクラウンエーテル体の合成と設計2010

    • Author(s)
      山ノ井孝, 小池健仁, 吉田彰宏, 小田慶喜, 渡邊幹夫
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪
    • Related Report
      2009 Annual Research Report
  • [Presentation] タンデム型スピロ環化反応を用いたスピロクロマン配糖体合成2010

    • Author(s)
      松田翔, 田部井要, 吉田彰宏, 小田慶喜, 山ノ井孝
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪
    • Related Report
      2009 Annual Research Report
  • [Presentation] Environmental Aspect in Fluorous Biphasic System (Our Approach)2009

    • Author(s)
      N.Hoshi, A.Yoshida
    • Organizer
      The 19th International Symposium on Fluorine Chemistry including ISoFT'09 (19thISFC-ISoFT'09)
    • Place of Presentation
      Jackson Hole.
    • Related Report
      2010 Final Research Report
  • [Presentation] Environmental Aspect in Fluorous Biphasic System (Our Approach)2009

    • Author(s)
      N. Hoshi, A. Yoshida
    • Organizer
      The 19th International Symposium on Fluorine Chemistry including ISoFT'09 (19thISFC-ISoFT'09)
    • Place of Presentation
      Jackson Hole
    • Related Report
      2009 Self-evaluation Report
  • [Presentation] Environmental Aspect in Fluorous Biphasic System(Our Approach)2009

    • Author(s)
      Hoshi, N., Yoshida, A.
    • Organizer
      The 19^<th> International Symposium on Fluorine Chemistry including ISoFT'09(19thISFC-ISoFT'09)
    • Place of Presentation
      Jackson Hole
    • Related Report
      2009 Annual Research Report
  • [Presentation] 「タンデム型スピロ環化反応によるスピロクロマン配糖体の合成研究」2009

    • Author(s)
      松田 翔,田部井 要,吉田 彰宏,山ノ井孝
    • Organizer
      日本農芸化学会2009年度大会
    • Place of Presentation
      福岡
    • Related Report
      2008 Annual Research Report
  • [Presentation] "Synthesis of exo-Glycals from 1-C-Vinyl-D-glycopyranose via anS_N1'-Substitution Mechanism and Their Spirocyclization to Givel6,6]-Spiroketals"2008

    • Author(s)
      Yamanoi, T; Matsuda,S.;Yoshida,A.
    • Organizer
      XXIV International Carbohydrate Symposium(ICS 2008)
    • Place of Presentation
      Oslo
    • Related Report
      2008 Annual Research Report
  • [Presentation] Low-leaching Fluorous Biphasic Solvent System for Fluorous Lewis Acid Catalysis2007

    • Author(s)
      A.Yoshida, N.Hoshi
    • Organizer
      The 2nd International Symposium on Fluorous Technologies (ISoFT'07)
    • Place of Presentation
      横浜
    • Related Report
      2010 Final Research Report
  • [Presentation] Low-leaching Fluorous Biphasic Solvent System for Fluorous Lewis Acid Catalysis2007

    • Author(s)
      A. Yoshida, N. Hoshi
    • Organizer
      The 2nd International Symposium on Fluorous Tech-nologies (ISoFT'07)
    • Place of Presentation
      Yokohama
    • Related Report
      2009 Self-evaluation Report
  • [Presentation] "Low-leaching Fluorous Biphasic Solvent System for Fluorous Lewis Acid Catalysis"2007

    • Author(s)
      Akihiro Yoshida and Nobuto Hoshi
    • Organizer
      International Symposium on Fluorous Technologies (ISoFTO7)
    • Place of Presentation
      横浜
    • Related Report
      2007 Annual Research Report
  • [Book] 「フルオラスLewis酸触媒」,「固定化触媒のルネッサンス」内(小林修, 小山田秀和監修)2007

    • Author(s)
      吉田彰宏, 錦戸條二
    • Publisher
      シーエムシー出版
    • Related Report
      2010 Final Research Report
  • [Book] 固定化触媒のルネッサンス2007

    • Author(s)
      吉田彰宏, 錦戸條二
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Self-evaluation Report
  • [Book] 固定化触媒のルネサンス2007

    • Author(s)
      吉田彰宏, 錦戸條二
    • Publisher
      シーエムシー出版
    • Related Report
      2007 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.noguchi.or.jp/

    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] フルオラス化糖結合型クラウンエーテル誘導体2010

    • Inventor(s)
      山ノ井孝, 吉田彰宏, 小田慶喜
    • Industrial Property Rights Holder
      財団法人野口研究所
    • Industrial Property Number
      2010-055097
    • Filing Date
      2010-03-11
    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 低リーチング性のフルオラス多相系反応方法2009

    • Inventor(s)
      星信人, 吉田彰宏
    • Industrial Property Rights Holder
      公益財団法人野口研究所, 旭化成株式会社
    • Industrial Property Number
      2009-190116
    • Filing Date
      2009-08-19
    • Related Report
      2010 Final Research Report 2009 Annual Research Report 2009 Self-evaluation Report
  • [Patent(Industrial Property Rights)] ルイス酸触媒含有組成物2008

    • Inventor(s)
      錦戸條二, 吉田彰宏, 池田正紀
    • Industrial Property Rights Holder
      公益財団法人野口研究所, 旭化成株式会社
    • Acquisition Date
      2008-05-02
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] ルイス酸触媒含有組成物2008

    • Inventor(s)
      錦戸條二, 吉田彰宏, 池田正紀
    • Industrial Property Rights Holder
      財団法人野口研究所, 旭化成株式会社
    • Filing Date
      2008-05-02
    • Related Report
      2009 Self-evaluation Report

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Published: 2007-04-01   Modified: 2016-04-21  

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