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Systematic syntheses of MOFs with sub-nanometer pores by structural transformation reaction for gas sieving

Research Project

Project/Area Number 19K05661
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 36010:Inorganic compounds and inorganic materials chemistry-related
Research InstitutionKonan University

Principal Investigator

Takashima Yohei  甲南大学, フロンティアサイエンス学部, 講師 (40720652)

Project Period (FY) 2019-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2021: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords多孔性金属錯体 / ガス分離 / ふるい / 構造変換 / サブナノメートル細孔
Outline of Research at the Start

現在の化学産業における分離・精製プロセスは、全プロセスの消費エネルギーの40%程度に達する場合もあり、その低エネルギー化に対する社会的ニーズは非常に大きい。特に、石油化学産業におけるガス分離のほとんどは、莫大なエネルギーを要する低温蒸留法を用いており、低エネルギーで駆動可能な代替システムである多孔体を利用したガス分離技術は大きな注目を集めている。本研究では、ガス分離が可能となるサブナノメートルサイズの細孔を有する多孔性金属錯体の合理的合成とそのガス分離特性評価を目的としている。

Outline of Final Research Achievements

Nowadays, we have used huge amount of energy for separation and purification processes in chemical industry and alternative systems that can work with lower energy are strongly required. Among some alternatives, the system with porous materials is one promising candidate. In this system, the precise control of porous structure is necessary to get applicable performance, but it is still not easy. Along this line, in this work, we have tried to generate a series of metal-organic frameworks with sub-nanometer pores by structural transformation reaction.

Academic Significance and Societal Importance of the Research Achievements

ガスを低コストで分離する方法として分離膜を用いる方法があるが、その方法で分離するためには分離膜内の細孔をサブナノメートルスケールで精密に制御する必要がある。本研究では我々が近年見出した構造変換反応を用いることにより、サブナノメートルサイズの細孔を有した一連の多孔性金属錯体の合成に成功した。ガスの分離は化学産業における重要なプロセスであるが、現在は、蒸留という非常に大きなエネルギーを消費するプロセスに依存している。本研究は、その代替手段である分離膜を用いたガス分離で必要となる多孔性材料の合成につながるものである。

Report

(4 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Research-status Report
  • Research Products

    (26 results)

All 2022 2021 2020 2019 Other

All Journal Article (7 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Open Access: 2 results) Presentation (18 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results) Remarks (1 results)

  • [Journal Article] Rational and site-selective formation of coordination polymers consisting of d10 coinage metal ions with thiolate ligands using a metal ion-doped polymer substrate2022

    • Author(s)
      Takaaki Tsuruoka, Yuri Miyashita, Ryuki Yoshino, Myu Fukuoka, Shoya Hirao, Yohei Takashima, Aude Demessence, Kensuke Akamatsu
    • Journal Title

      RSC Adv.

      Volume: 12 Issue: 6 Pages: 3716-3720

    • DOI

      10.1039/d2ra00269h

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Exploration of structural transition phenomenon in flexible metal-organic framework formed on polymer substrate2021

    • Author(s)
      Shoya Hirao, Ruho Hamagami, Takashi Ohhashi, Keiichi Eguchi, Neo Kubo, Yohei Takashima, Kensuke Akamatsu, Takaaki Tsuruoka
    • Journal Title

      CrystEngComm

      Volume: 23 Issue: 48 Pages: 8498-8505

    • DOI

      10.1039/d1ce01383a

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Precisely Controlled Reproducible Synthesis of Palladium Nanoparticles inside Metal-Organic Frameworks with H2 Gas as Reductant: Effects of Framework Crystallinity and H2 Gas Pressure2021

    • Author(s)
      Takashima Yohei、Sato Yasushi、Kubo Neo、Tsuruoka Takaaki、Akamatsu Kensuke
    • Journal Title

      Chemistry Letters

      Volume: 50 Issue: 2 Pages: 244-247

    • DOI

      10.1246/cl.200683

    • NAID

      130007986343

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Controlled syntheses of Ag nanoparticles inside MOFs by using amine?borans as vapour phase reductants2020

    • Author(s)
      Takashima Yohei、Sato Yasushi、Tsuruoka Takaaki、Akamatsu Kensuke
    • Journal Title

      Dalton Transactions

      Volume: 49 Issue: 47 Pages: 17169-17172

    • DOI

      10.1039/d0dt03259j

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] 固液界面での選択的MOF形成2019

    • Author(s)
      鶴岡孝章、平尾翔也、髙嶋洋平、赤松謙祐
    • Journal Title

      日本接着学会誌

      Volume: 55 Issue: 3 Pages: 301-307

    • DOI

      10.1021/acs.cgd.9b01622

    • NAID

      130007701593

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Control of the nucleation and growth processes of metal-organic frameworks using a metal ion-doped polymer substrate for the construction of continuous films2019

    • Author(s)
      Takashi Ohhashi, Takaaki Tsuruoka, Yohei Takashima, Kensuke Akamatsu
    • Journal Title

      CrystEngComm

      Volume: 21 Issue: 33 Pages: 4851-4854

    • DOI

      10.1039/c9ce01054h

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Formation of Metal-Organic Frameworks on Metal Ion-Doped Polymer Substrate: In-Depth Time-Course Analysis using Scanning Electron Microscopy2019

    • Author(s)
      Takaaki Tsuruoka, Manami Hata, Shoya Hirao, Takashi Ohhashi, Yohei Takashima, Kensuke Akamatsu
    • Journal Title

      Langmuir

      Volume: 35 Issue: 32 Pages: 10390-10396

    • DOI

      10.1021/acs.langmuir.9b01676

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Presentation] 疎水性MOF粒子を用いた新規リキッドマーブルの形成とその評価2022

    • Author(s)
      久保音生、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会第102春季年会(2022)
    • Related Report
      2021 Annual Research Report
  • [Presentation] 水分散性を有する多孔性金属錯体の合成とその評価2022

    • Author(s)
      山之内沙綾、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会第102春季年会(2022)
    • Related Report
      2021 Annual Research Report
  • [Presentation] アモルファス状態を経由する新規MOF合成法の開発2022

    • Author(s)
      覚知匠、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会第102春季年会(2022)
    • Related Report
      2021 Annual Research Report
  • [Presentation] AlベースMOFが示す特異な構造変換における置換基効果2022

    • Author(s)
      田中進太郎、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会第102春季年会(2022)
    • Related Report
      2021 Annual Research Report
  • [Presentation] 金属ナノ粒子―MOF複合体の新規合成法の開発2022

    • Author(s)
      髙嶋洋平
    • Organizer
      日本化学会第102春季年会(2022)
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Synhteses and Catalytic Properties of Pd Nanoparticles/Organic Polymers inside a MOF2021

    • Author(s)
      Yohei Takashima, Seiko Tetsusashi, Takaaki Tsuruoka, Kensuke Akamatsu
    • Organizer
      錯体化学会第71回討論会(2021)
    • Related Report
      2021 Annual Research Report
  • [Presentation] 多孔性金属錯体が示す特異な構造変換における置換基効果2021

    • Author(s)
      田中進太郎、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      錯体化学会第71回討論会(2021)
    • Related Report
      2021 Annual Research Report
  • [Presentation] 疎水性MOFを用いたMOFリキッドマーブルの形成とその評価2021

    • Author(s)
      久保音生、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      第72回コロイドおよび界面化学討論会(2021)
    • Related Report
      2021 Annual Research Report
  • [Presentation] 構造変換反応を利用した水分散性MOFの合成とその評価2021

    • Author(s)
      山之内沙綾、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      第72回コロイドおよび界面化学討論会(2021)
    • Related Report
      2021 Annual Research Report
  • [Presentation] Synthesis and Evaluaiton of New Liquid Marble with Metal-Organic Frameworks2021

    • Author(s)
      Neo Kubo, Yohei Takashima, Takaaki Tsuruoka, Kensuke Akamatsu
    • Organizer
      INTERFINISH2020
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 疎水化処理を施したMOFを用いたMOF超構造体の構築2021

    • Author(s)
      久保音生、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会第101春季年会(2021)
    • Related Report
      2020 Research-status Report
  • [Presentation] 構造変換反応を用いた水分散性MOFの合成2021

    • Author(s)
      山之内沙綾、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会第101春季年会(2021)
    • Related Report
      2020 Research-status Report
  • [Presentation] 多孔性金属錯体内での機能化Pdナノ粒子の合成および触媒性能評価2021

    • Author(s)
      鉄指聖子、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会第101春季年会(2021)
    • Related Report
      2020 Research-status Report
  • [Presentation] Development of new synthetic methodologies for metal nanoparticle/MOF hybrids2020

    • Author(s)
      Yohei Takashima
    • Organizer
      日本化学会 第100春季年会 (2020)
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] 構造変換特性を有する多孔性金属錯体の系統的合成とその評価2020

    • Author(s)
      堀越篤人、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      日本化学会 第100春季年会 (2020)
    • Related Report
      2019 Research-status Report
  • [Presentation] Wrapping Flexible Metal-Organic Framework with Organic Polymers via Site-Specific Radical Polymerization from Its Crystal Surface2019

    • Author(s)
      Yohei Takashima, Kenji Fukudome, Takaaki Tsuruoka, Kensuke Akamatusu\\
    • Organizer
      錯体化学会 第69回討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] Systematic Evaluation on the Structural Transformation Properties of Al-based Metal-Organic Frameworks2019

    • Author(s)
      Atsuto Horikoshi, Yohei Takashima, Takaaki Tsuruoka, and Kensuke Akamatsu
    • Organizer
      Okinawa Colloids 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Alベース多孔性金属錯体が示す構造変換特性の系統的評価2019

    • Author(s)
      堀越篤人、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      錯体化学会 第69回討論会
    • Related Report
      2019 Research-status Report
  • [Remarks]

    • URL

      http://www.konan-u.ac.jp/hp/FIRST_nanomaterials/

    • Related Report
      2021 Annual Research Report

URL: 

Published: 2019-04-18   Modified: 2023-01-30  

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