Catalytic Fixation of Carbon Dioxide and Methane Based on Design and Synthesis of Pincer-Type Heterobimetallic Transition Metal Complexes
| Project/Area Number |
20200049
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| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research a proposed research project)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
Synthetic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
TAKAYA Jun 東京工業大学, 大学院・理工学研究科, 助教 (60401535)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥31,070,000 (Direct Cost: ¥23,900,000、Indirect Cost: ¥7,170,000)
Fiscal Year 2010: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Fiscal Year 2009: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Fiscal Year 2008: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
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| Keywords | 合成有機化学 / 錯体・有機金属化学 / 錯体化学 / 合成化学 / 二酸化炭素 / ピンサー型錯体 / パラジウム / ケイ素 |
|---|
| Research Abstract |
We have developed hydrocarboxylation reaction of simple unsaturated hydrocarbons such as allenes and 1,3-dienes with CO2 catalyzed by newly designed PSiP-pincer type palladium complex, giving synthetically useful beta, gamma-unsaturated carboxylic acid derivatives in high yield and regioselectivity. Moreover, the first example of direct carboxylation of non-activated sp2-C-H bond of arenes has been developed by the use of rhodium catalyst.
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Report
(4 results)
Research Products
(61 results)
