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Development of in-situ near-field fluorescence and Raman microscopy and structural analyses of radionuclide adsorption

Research Project

Project/Area Number 20246137
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear engineering
Research InstitutionThe University of Tokyo

Principal Investigator

TANAKA Satoru  東京大学, 大学院・工学系研究科, 教授 (10114547)

Co-Investigator(Kenkyū-buntansha) NAGASAKI Shinya  東京大学, 大学院・工学系研究科, 教授 (20240723)
SAITO Takumi  東京大学, 大学院・工学系研究科, 助教 (90436543)
Co-Investigator(Renkei-kenkyūsha) KIMURA Takaumi  独立行政法人日本原子力研究開発機構, 原子力基礎工学研究部門, グループリーダー (20354897)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥47,840,000 (Direct Cost: ¥36,800,000、Indirect Cost: ¥11,040,000)
Fiscal Year 2010: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2009: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2008: ¥37,440,000 (Direct Cost: ¥28,800,000、Indirect Cost: ¥8,640,000)
Keywordsバックエンド / 近接場光顕微鏡 / 吸着構造 / 天然バリア / 表面錯体 / 放射性廃棄物処分 / 移行遅延 / 近接場光 / 性能評価 / 放射性核種 / 吸着 / 移行 / 蛍光分光 / アクチニド元素
Research Abstract

Subsurface environments from the vicinity of disposed wastes to our-living biosphere are called natural barrier and expected to provide barrier function to retard the migration of released radionuclides through the diffusion and sorption to rocks. In order to improve the performance assessment of nuclear waste disposal, one must understand such sorption phenomena and model it. In this study, near-field optical technique was focused and used to detect emission from radionuclides adsorbed on the surfaces of minerals, which could be major constituents of real subsurface environments. The obtained fluorescence spectra and decays were further used to investigate their sorption structures on the basis of known surface structures of the surfaces.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (14 results)

All 2012 2010 2009 2008 Other

All Journal Article (5 results) (of which Peer Reviewed: 2 results) Presentation (7 results) Remarks (2 results)

  • [Journal Article] Surface Speciation of Eu3+Ads+AX1374orbed on Kaolinite by Time-Resolved Laser Fluorescence Spectroscopy(TRLFS) and Parallel Factor Analysis(PARAFAC)2012

    • Author(s)
      Ishida, K., Saito, T., Aoyagi, N., Kimura, T., Nagaishi, R., Nagasaki, S. and Tanaka, S.
    • Journal Title

      J. Colloid Interface Sci

      Volume: 374(1) Pages: 258-266

    • Related Report
      2010 Final Research Report
  • [Journal Article] Surface Speciation of Eu^<3+> Adsorbed on Kaolinite by Time-Resolved Laser Fluorescence Spectroscopy (TRLFS) and Parallel Factor Analysis (PARAFAC)2012

    • Author(s)
      Ishida, K., Saito, T., Aoyagi, N., Kimura, T., Nagaishi, R., Nagasaki, S., Tanaka, S.
    • Journal Title

      Journal of Colloid and Interface Science

      Volume: 374 Pages: 258-266

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of Parallel Factor Analysis for Time-Resolved Laser Fluorescence Spectroscopy : Implication for Metal Speciation Study2010

    • Author(s)
      Saito, T., Sao, H., Ishida, K., Aoyagi, N., Kimura, T., Nagasaki, S. and Tanaka, S.
    • Journal Title

      Environ. Sci. Technol

      Volume: 44 Pages: 5055-5060

    • Related Report
      2010 Final Research Report
  • [Journal Article] Adsorption of Eu(III) on a Heterogeneous Surface Studied by Time-Resolved Laser Fluorescence Microscopy(TRLFM)2009

    • Author(s)
      Ishida, K., Kimura, T., Saito, T. and Tanaka, S.
    • Journal Title

      Environ. Sci. Technol

      Volume: 43 Pages: 1744-1749

    • Related Report
      2010 Final Research Report
  • [Journal Article] Adsorption of Eu(III) on a Heterogeneous Surface Studied by Time-Resolved Laser Fluorescence Microscopy (TRLFM)2009

    • Author(s)
      Ishida, K., Kimura, T., Saito, T. and Tanaka, S.
    • Journal Title

      Environmental Science & Technology 43

      Pages: 1744-1749

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Actinide Adsorption at Solid-Liquid Interfaces : Current Status and Future Challenges2010

    • Author(s)
      Saito, T.
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Honolulu, Hawaii(招待講演)
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 時間分解型近接場蛍光顕微鏡の開発と核種/鉱物吸着系への適用2010

    • Author(s)
      石田圭輔, 他
    • Organizer
      日本原子力学会2010年春の年会
    • Place of Presentation
      茨城大学
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Parallel factor analysis for time-resolved laser fluorescence spectroscopy : A powerful tool for speciation studies2010

    • Author(s)
      Saito, T., Aoyagi, N., Kimura, T., Nagasaki, S. and Tanaka, S.
    • Organizer
      Goldschmidt 2010
    • Place of Presentation
      Knoxville, USA
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 時間分解型レーザ誘起発光分光法を用いたEu(III)のカオリナイト表面錯体に関する研究:H2O/D2O系における蛍光測定2009

    • Author(s)
      石田圭輔,斉藤拓巳,田中知,長崎晋也,木村貴海
    • Organizer
      日本原子力学会春の年会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2009-03-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] ADSORPTION OF Eu(III) ON A HETEROGENEOUS SURFACE STUDIED BY TIME-RESOLVED LASER FLUORESCENCE MICROSCOPY(TRLFM)2009

    • Author(s)
      Ishida, K., Kimura, T., Saito, T. and Tanaka, S.
    • Organizer
      Migration' 09
    • Place of Presentation
      Kennewich, USA
    • Related Report
      2010 Final Research Report
  • [Presentation] STUDY ON THE SURFACE COMPLEXES OF Eu(III) ON KAOLINITE BY TIME-RESOLVED LASER FLUORESCENCE SPECTROSCPY(TRLFS): TRLFS MEASUERMENT IN H2O/D2O SYSTEMS2009

    • Author(s)
      Ishida, K., Saito, T., Aoyagi, N., Kimura, T., Nagasaki, S. and Tanaka, S.
    • Organizer
      Migration' 09
    • Place of Presentation
      Kennewich, USA
    • Related Report
      2010 Final Research Report
  • [Presentation] Fluorescence Lifetime ImagingMicroscopy applied for Eu(III) adsorbed on Granite2008

    • Author(s)
      Ishida, K., Kimura, T., Saito, T., Toraishi, T. and Tanaka, S.
    • Organizer
      IAP 2008
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.flanker.n.t.u-tokyo.ac.jp/environment/modules/pico/index.php/content0017.html

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.flanker.n.t.u-tokyo.ac.jp/environment/modules/pico/index.php/content0017.html

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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