Development of Novel Synthetic Method using C-H and C-Heteroatom bond Functionalization
| Project/Area Number |
20350019
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (B)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | Kyoto University |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
KURAHASHI Takuya 京都大学, 大学院・工学研究科, 助教 (50432365)
|
|---|
| Project Period (FY) |
2008 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2010: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2009: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2008: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
|
|---|
| Keywords | 複素環 / ニッケル / 環化付加 / アルキル鎖 / 銅触媒反応 / Mannich反応 / Click反応 / 付加反応 / C-H結合活性 / C-N給合活性 / カルボアミノヒ / カルボエーテル化 / 複素環化合物 / メタラサイクル / 脱カルボニル / C-H結合活性化 / 触媒 / 環化反応 / カルボアミノ化 / アルキン / 原子効率 |
|---|
| Research Abstract |
A nickelacycle, which was formed from easily available carbonyl compounds and nickel(0) via oxidative insertion and decarbonylation, added to an alkyne to produce the corresponding heterocyclic compound. It was found that phthalic imide gives tha isoquinolone ; phthalic anhydride gives the isochromenone.
|
Report
(4 results)
Research Products
(27 results)
