Creation of Surface MOF

• Project/Area Number: 20350030
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Kyushu University
• Principal Investigator: KITAGAWA Hiroshi Kyushu University, 大学院・理学研究科, 教授 (90234244)
• Co-Investigator(Kenkyū-buntansha): YAMADA Teppei 京都大学, 大学院・理学研究科, 助教 (10404071)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000); Fiscal Year 2010: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2009: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2008: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
• Keywords: 無機固体化学 / 多孔性金属錯体 / プロトン伝導性金属錯体 / 伝導性金属錯体 / 配位高分子 / プロトニクス / MOF

Research Abstract

Dynamics of molecules and ions in metal-organic hybrid nano-layer integrated system are acted by characteristic nano-fields such as intermolecular interaction, coulomb interaction, catalytic action, etc. This project is to construct the metal-organic nano-layer integrated system. In particular, we constructed functional nano-layer systems using metal-organic frameworks (MOFs) for energy conversions.

Research Products

• [Journal Article] Bottom-up Realization of A Porous Metal-Organic Nanotubular Assembly (2011)
  • Author(s): K.Otsubo, Y.Wakabayashi, J.Ohara, S.Yamamoto, H.Matsuzaki, H.Okamoto, K.Nitta, T.Uruga, H.Kitagawa
  • Journal Title: Nature Materials 10 Pages: 291-295
• [Journal Article] Wide Control of Proton Conductivity in Porous Coordination Polymers (2011)
  • Author(s): A.Shigematsu, T.Yamada, H.Kitagawa
  • Journal Title: J.Am.Chem.Soc. 133 Pages: 2034-2034
• [Journal Article] Highly-Crystalline Nanofilm by Layering Porphyrin MOF Sheets (2011)
  • Author(s): S.Motoyama, R.Makiura, O.Sakata, H.Kitagawa
  • Journal Title: J.Am.Chem.Soc. 133 Pages: 5640-5643
• [Journal Article] Bottom-up Realization of A Porous Metal-Organic Nanotubular Assembly (2011)
  • Author(s): K.Otsubo, Y.Wakabayashi, J.Ohara, S.Yamamoto, H.Matsuzaki, H.Okamoto, K.Nitta, T.Uruga, H.Kitagawa
  • Journal Title: Nature Materials Volume: 10 Pages: 291-295
  • Peer Reviewed
• [Journal Article] Hydrogen-Storage Properties of Solid-Solution Alloys of Immiscible Neighboring Elements with Pd (2010)
  • Author(s): K.Kusada, M.Yamauchi, H.Kobayashi, H.Kitagawa, Y.Kubota
  • Journal Title: J.Am.Chem.Soc. 132 Pages: 15896-15896
• [Journal Article] Surface Nano-Architecture of A Metal-Organic Framework (2010)
  • Author(s): R.Makiura, S.Motoyama, Y.Umemura, H.Yamanaka, O.Sakata, H.Kitagawa
  • Journal Title: Nature Materials 9 Pages: 565-571
• [Journal Article] A Metal-Organic Framework as An Electrocatalyst for Ethanol Oxidation (2010)
  • Author(s): L.Yang, S.Kinoshita, T.Yamada, S.Kanda, H.Kitagawa, M.Tokunaga, T.Ishimoto, T.Ogura, A.Miyamoto, M.Koyama
  • Journal Title: Angew.Chem.Int.Ed. 49 Pages: 5348-5348
• [Journal Article] Atomic-Level Pd-Pt Alloying and Largely Enhanced Hydrogen-Storage Capacity in Bimetallic Nanoparticles Reconstructed from Core/Shell Structure by a Process of Hydrogen Absorption/Desorption (2010)
  • Author(s): H.Kobayashi, M.Yamauchi, H.Kitagawa, Y.Kubota, K.Kato, M.Takata
  • Journal Title: J.Am.Chem.Soc. 132 Pages: 5576-5577
• [Journal Article] Surface Nano-Architecture of A Metal-Organic Framework (2010)
  • Author(s): R.Makiura, S.Motoyama, Y.Umemura, H.Yamanaka, O.Sakata, H.Kitagawa
  • Journal Title: Nature Materials Volume: 9 Pages: 956-571
  • Peer Reviewed
• [Journal Article] Hydrogen-Storage Properties of Solid-Solution Alloys of Immiscible Neighboring Elements with Pd (2010)
  • Author(s): K.Kusada, M.Yamauchi, H.Kobayashi, H.Kitagawa, Y.Kubota
  • Journal Title: J.Am.Chem.Soc. Volume: 132 Pages: 15896-15898
  • Peer Reviewed
• [Journal Article] Surface Nano-Architecture of A Metal-Organic Framework (2010)
  • Author(s): H.Kitagawa, et al.
  • Journal Title: Nature Materials Volume: (印刷中)
  • Peer Reviewed
• [Journal Article] Transported into Fuel Cells (2009)
  • Author(s): H.Kitagawa
  • Journal Title: Nature Chemistry 1 Pages: 689-689
• [Journal Article] Size-Controlled Stabilisation of the Superionic Phase to Room Temperature in Polymer-Coated AgI Nanoparticles (2009)
  • Author(s): R.Makiura, T.Yonemura, T.Yamada, M.Yamauchi, R.Ikeda, H.Kitagawa, K.Kato, M.Takata
  • Journal Title: Nature Materials 8 Pages: 476-480
• [Journal Article] Size-Controlled Stabilisation of the Superionic Phase to Room Temperature in Polymer-Coated AgI Nanoparticles (2009)
  • Author(s): H.Kitagawa, et al.
  • Journal Title: Nature Materials Volume: 8 Pages: 476-480
  • Peer Reviewed
• [Journal Article] A Protection and Deprotection Approach for the Introduction of Functional Group to Metal-Organic Frameworks (2009)
  • Author(s): H.Kitagawa, et al.
  • Journal Title: J.Am.Chem.Soc. Volume: 131 Pages: 6312-6313
  • Peer Reviewed
• [Journal Article] Size-Controlled Stabilisation of The Superionic Phase to Room Temperature in Polymer-Coated AgI Nanoparticles. (2009)
  • Author(s): R. Makiura, T. Yonemura, T. Yamada, M. Yamauchi, R. Ikeda, H. Kitagawa, K, Kato, M. Takata
  • Journal Title: Nature Materials (in press)
  • Peer Reviewed
• [Journal Article] High Proton Conductivity of One-Dimensional Ferrous Oxalate Dihydrate (2009)
  • Author(s): T. Yamada, M. Sadakiyo, H. Kitagawa
  • Journal Title: J. Am, Chem. Soc. 131 Pages: 3144-3145
  • Peer Reviewed
• [Journal Article] Thermochromism in an Organic Crystal Based on the Co-Existence of σ- and π-Dimers (2008)
  • Author(s): Y.Morita, S.Suzuki, K.Fukui, S.Nakazawa, H.Kitagawa, et al.
  • Journal Title: Nature Materials 7 Pages: 41-51
• [Journal Article] Construction of Highly-Oriented Crystalline Surface Coordination Polymers Composed of Copper Dithiooxamide Complex (2008)
  • Author(s): K. Kanaizuka, R. Haruki, O. Sakata, M. Yoshimoto, Y. Akita, H. Kitagawa
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 15778-15779
  • Peer Reviewed
• [Presentation] 多彩な電子・水素相の創出と固体プロトニクス材料への展開 (2010)
  • Author(s): 北川宏
  • Organizer: 日本化学会第90春季年会学術賞受賞講演
  • Year and Date: 2010-03-27
• [Presentation] Solid-State & Surface Protonics in Metal-Organic Framewworks (2010)
  • Author(s): 北川宏
  • Organizer: Eurasia Conference on Chemical Sciences-11, The Death Sea, Jordan
  • Place of Presentation: ヨルダン(招待講演)
• [Presentation] 水素吸蔵/放出に伴うAg-Rh合金ナノ粒子の構造変化 (2009)
  • Author(s): 草田康平, 山内美穂, 小林浩和, 北川 宏
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉
• [Presentation] 4本鎖を有するMX-Ladder型金属錯体の構造と物性 (2008)
  • Author(s): 大坪主弥, 北川宏, 松崎弘幸, 岡本 博
  • Organizer: 錯体化学討論会
  • Place of Presentation: 石川
• [Presentation] Ag-Rh合金ナノ粒子の合成と水素吸蔵特性 (2008)
  • Author(s): 草田康平, 山内美穂, 北川宏
  • Organizer: 分子科学討論会
  • Place of Presentation: 福岡
• [Remarks] ホームページ等
  • URL: http://kuchem.kyoto-u.ac.jp/ossc/index.html