Construction of Polymers Containing Typical Elements Based on Radical Bismetallation of Acetyleneic Compounds

• Project/Area Number: 20350054
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer chemistry
• Research Institution: Kyoto Institute of Technology
• Principal Investigator: NAKA Kensuke Kyoto Institute of Technology, 工芸科学研究科, 教授 (70227718)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥19,890,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥4,590,000); Fiscal Year 2010: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000); Fiscal Year 2009: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000); Fiscal Year 2008: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
• Keywords: 高分子合成 / 合成化学 / 金属錯体 / 典型元素 / 無機高分子

Research Abstract

The study of various metal complexes of organoaresenic polymers and cyclic compounds, which were prepared by radical bismetallation of cycloorganoarsines with acetylenic compounds, suggests that the flexibility of the bond angles at around the arsenic center is inherent property in organoarsenic compounds. This characteristic provides various unique optical properties of the present organnoaresenic compounds.

Research Products

• [Journal Article] Synthesis and low-temperature dehydrating imidation polymerization of 1, 4-dihydro-1, 4-diarsininetetracarboxylic acid dianhydride (2011)
  • Author(s): Naka, K., Arita, M., Shimamoto, T., Morisaki, Y., Chujo, Y.
  • Journal Title: Polym.J. 43 Pages: 358-363
  • NAID: 10028159363
  • Peer Reviewed
• [Journal Article] Synthesis and low-temperature dehydrating imidation polymerization of 1,4-dihydro-1,4-diarsininetetracarboxylic acid dianhydride (2011)
  • Author(s): Naka, K.; Arita, M.; Shimamoto, T.; Morisaki, Y.; Chujo, Y.
  • Journal Title: Polym.J. Volume: 43 Pages: 358-363
  • NAID: 10028159363
  • Peer Reviewed
• [Journal Article] 1, 4-Dihydro-1, 4-diarsinine-Bridged Dinuclear trans-Dihaloplatinum(II) Complexes : Synthesis and Controlled Pt-Pt Interaction by Halogen Substitution Induced Conformational Change (2010)
  • Author(s): Arita, M., Naka, K., Shimamoto, T., Yumura, T., Nakahashi, A., Morisaki, Y., Chujo, Y.
  • Journal Title: Organometallics 29 Pages: 4992-5003
  • Peer Reviewed
• [Journal Article] Synthesis of poly(vinylene-arsine)s-stabilized silver nanoparticles (2010)
  • Author(s): Naka, K., Nakahashi, A., Bravo, M., Chujo, Y.
  • Journal Title: Appl.Organomet.Chem. 24(8) Pages: 573-575
  • Peer Reviewed
• [Journal Article] Synthesis of poly(vinylene-arsine)s-stabilized silver nanoparticles (2010)
  • Author(s): Naka, K.; Nakahashi, A.; Bravo, M.; Chujo, Y.
  • Journal Title: Applied Organometallic Chemistry Volume: 24 Pages: 573-575
  • Peer Reviewed
• [Journal Article] 1,4-Dihydro-1, 4-diarsinine-Bridged Dinuclear trans-Dihaloplatinum(II)Complexes : Synthesis and Controlled Pt-Pt Interaction by Halogen Substitution Induced Conformational Change (2010)
  • Author(s): Arita, M.; Naka, K.; Shimanioto, T.; Yumura, T.; Nakahashi, A.; Morisaki, Y.; Chujo, Y.
  • Journal Title: Organometallics Volume: 29 Pages: 4992-5003
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of Stereoisomers of 1, 4-Dihydro-1, 4-diarsinines (2009)
  • Author(s): Arita, M., Naka, K., Morisaki, Y., Nakahashi, A., Chujo, Y.
  • Journal Title: Organometallic 28(20) Pages: 6109-6113
  • Peer Reviewed
• [Journal Article] Coordination ability of poly(vinylene-arsine)s towards transition metal ions (2009)
  • Author(s): Nakahashi, A., Bravo, M., Naka, K., Chujo, Y.
  • Journal Title: J.Phys. : Conf.Ser. 184 Pages: 12021-12021
  • Peer Reviewed
• [Journal Article] Effects of Diphenyl Dichalcogenides on the Radical Polymerization of Diethynyl Disulfide Derivative (2009)
  • Author(s): Nakahashi, A., Miyoshi, E., Naka, K., Chujo, Y.
  • Journal Title: J.Inorg.Organomet.Polym.Mater. Pages: 1-12
  • Peer Reviewed
• [Journal Article] Synthesis of Block Copolymers with a Pentasilane Core (2009)
  • Author(s): Morisaki, Y., Otaka, H., Naka, K., Chujo, Y.
  • Journal Title: Macromol.Rapid Comm. 30(11) Pages: 948-953
  • Peer Reviewed
• [Journal Article] Synthesis of Helical Polymers with a Pentasilane Core (2009)
  • Author(s): Morisaki, Y., Otaka, H., Nagai, A., Naka, K., Chujo, Y.
  • Journal Title: Chem.Let. 38(5) Pages: 498-499
  • NAID: 10025122325
  • Peer Reviewed
• [Journal Article] Synthesis of Helical Polymers with a Pentasilane Core (2009)
  • Author(s): Morisaki, Y., Otaka, H., Nagai, A., Naka, K., Chujo, Y.
  • Journal Title: Chemistry Letters 38 Pages: 498-499
  • NAID: 10025122325
  • Peer Reviewed
• [Journal Article] Synthesis of Block Copolymers with a Pentasilane Core (2009)
  • Author(s): Morisaki, Y., Otaka, H., Naka, K., Chujo, Y.
  • Journal Title: Macromolecular Rapid Communications 30 Pages: 948-953
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of Stereoisomers of 1,4-Dihydro-1,4-diarsinines (2009)
  • Author(s): Arita, M., Naka, K., Morisaki, Y., Nakahashi, A., Chujo, Y.
  • Journal Title: Organometallics 28 Pages: 6109-6113
  • Peer Reviewed
• [Journal Article] Coordination ability of poly (vinylene-arsine) s towards transition metal ions (2009)
  • Author(s): Nakahashi, A., Bravo, M., Naka, K., Chujo, Y.
  • Journal Title: J.Phys.: Conf.Ser. 184
  • Peer Reviewed
• [Journal Article] Effects of Diphenyl Dichalcogenides on the Radical Polymerization of Diethynyl Disulfide Derivative (2009)
  • Author(s): A. Nakahashi, E. Miyoshi, K. Naka, Y. Chujo
  • Journal Title: J. Inorg. Organomet. Polym. Mater. 19 Pages: 55-66
  • Peer Reviewed
• [Journal Article] Stoichiometric Complexation of Palladium (II) with 1, 4-Dihydro-1, 4-diar sinine as a Rigid Symmetrical Bidentate Ligand (2008)
  • Author(s): K. Naka, A. Nakahashi, M. Arita, Y. Chujo
  • Journal Title: Organometallics 27 Pages: 1034-1036
  • Peer Reviewed
• [Journal Article] Synthesis of polymers containing group 15 elements via bismetal lation of acetylenic compounds (2008)
  • Author(s): K. Naka
  • Journal Title: Polymer Journal 40 Pages: 1031-1041
  • Peer Reviewed
• [Presentation] ヒ素含有配位子-白金(II)錯体の溶媒蒸気及び温度による固体発光制御 (2011)
  • Author(s): 加藤拓路・中建介
  • Organizer: 第60回高分子学会年次大会
  • Place of Presentation: グランキューブ大阪、大阪
  • Year and Date: 2011-05-26
• [Presentation] ポリ(ビニレンヒ素)-Pd(II)錯体の合成とその触媒機能 (2011)
  • Author(s): 阿部剛士・加藤拓路・中建介
  • Organizer: 第60回高分子学会年次大会
  • Place of Presentation: グランキューブ大阪、大阪
  • Year and Date: 2011-05-26
• [Presentation] ヒ素含有配位子-白金(II)錯体のベイポクロミズムと温度応答性 (2011)
  • Author(s): 加藤拓路・中建介
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学横浜キャンパス、横浜
  • Year and Date: 2011-03-28
• [Presentation] ヒ素含有配位子-白金(II)錯体のベイポクロミズムと温度応答性 (2011)
  • Author(s): 加藤拓路、中建介
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学、横浜
  • Year and Date: 2011-03-28
• [Presentation] ポリ(ビニレンヒ素)-白金(II)錯体の合成とその光学特性 (2011)
  • Author(s): 阿部剛士・中建介
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学横浜キャンパス、横浜
  • Year and Date: 2011-03-26
• [Presentation] ポリ(ビニレンヒ素)-白金(II)錯体の合成とその光学特性 (2011)
  • Author(s): 阿部剛士、中建介
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学、横浜
  • Year and Date: 2011-03-26
• [Presentation] Optical properties of 1, 4-dihydro-1, 4-diarsinine-bridged dihaloplatinum(II) complexes (2010)
  • Author(s): 加藤拓路, 中建介
  • Organizer: Pacifichem 2010
  • Place of Presentation: Convention Center, Honolulu, Hawai, USA
  • Year and Date: 2010-12-19
• [Presentation] Synthesis and properties of organoarsenic polymers via bismetallation of acetylenic compounds (2010)
  • Author(s): 中建介
  • Organizer: Pacifichem 2010
  • Place of Presentation: Convention Center, Honolulu, Hawai, USA.(招待講演)
  • Year and Date: 2010-12-18
• [Presentation] Synthesis and properties of organoarsenic polymers via bisme tallation of acetylenic compounds (2010)
  • Author(s): Naka, K.
  • Organizer: Pacifichem 2010
  • Place of Presentation: ホノルル、ハワイ、アメリカ合衆国(招待講演)
  • Year and Date: 2010-12-18
• [Presentation] Optical properties of 1,4-dihydro-1,4-diarsinine-bridged dihalop latinum(II) complexes (2010)
  • Author(s): Kato, T.; Naka, K.
  • Organizer: Pacifichem 2010
  • Place of Presentation: ホノルル、ハワイ、アメリカ合衆国
  • Year and Date: 2010-12-18
• [Presentation] 1,4-ジヒドロ-1,4-ジアルシニンテトラカルボン酸二酸無水物の合成と低温脱水イミド化重合 (2010)
  • Author(s): 嶋本達男・加藤拓路・中建介・有田学, 森崎泰弘・中條善樹
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学、札幌
  • Year and Date: 2010-09-17
• [Presentation] 1,4-ジヒドロ-1,4-ジアルシニンテトラカルボン酸二無水物の合成と低温脱水イミド化重合 (2010)
  • Author(s): 嶋本達男、加藤拓路、中建介、有田学、森崎泰弘、中條善樹
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学、札幌
  • Year and Date: 2010-09-17
• [Presentation] ヒ素含有配位子-白金錯体の溶媒分子吸脱着による固体発光制御 (2010)
  • Author(s): 加藤拓路・中建介
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学、札幌
  • Year and Date: 2010-09-15
• [Presentation] ヒ素含有二座配位子を用いた遷移金属錯体の合成とその固体発光挙動 (2010)
  • Author(s): 加藤拓路・中建介
  • Organizer: 第56回高分子研究発表会【神戸】
  • Place of Presentation: 兵庫県民会館、神戸
  • Year and Date: 2010-07-16
• [Presentation] ヒ素含有環状二座配位子-白金錯体の合成と固体発光挙動 (2010)
  • Author(s): 加藤拓路、中建介
  • Organizer: 第56回高分子研究発表会【神戸】
  • Place of Presentation: 兵庫県民会館、神戸
  • Year and Date: 2010-07-16
• [Presentation] ヒ素含有環状二座配位子-白金錯体の溶媒分子吸着による固体発光制御 (2010)
  • Author(s): 加藤拓路・中建介
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜、横浜
  • Year and Date: 2010-05-27
• [Presentation] 1,4-ジヒドロ-1,4-ジアルシニン酸無水物の低温脱水イミド化重合 (2010)
  • Author(s): 嶋本達男、加藤拓路、中建介、有田学、森崎泰弘、中條善樹
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: 横浜国際会議場、横浜
  • Year and Date: 2010-05-27
• [Presentation] ヒ素含有環状二座配位子-白金錯体の溶媒分子吸着による固体発光制御 (2010)
  • Author(s): 加藤拓路、中建介
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: 横浜国際会議場、横浜
  • Year and Date: 2010-05-27
• [Presentation] 1,4-ジヒドロ-1,4-ジアルシニン酸無水物の低温脱水イミド化重合 (2010)
  • Author(s): 嶋本達男・中建介・有田学・森崎泰弘・中條善樹
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜、横浜
  • Year and Date: 2010-05-26
• [Presentation] ヒ素含有環状二座配位子-白金錯体の固体発光挙動 (2010)
  • Author(s): 加藤拓路・中建介・有田学・森崎泰弘・中條善樹
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学本部キャンパス、大阪
  • Year and Date: 2010-03-28
• [Presentation] ヒ素含有環状二座配位子-白金錯体の固体発光挙動 (2010)
  • Author(s): 加藤拓路, 中建介, 有田学, 森崎泰弘, 中條善樹
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学・大阪
  • Year and Date: 2010-03-28
• [Presentation] 1,4-ジヒドロ-1,4-ジアルシニン酸無水物を用いたヒ素含有ポリイミドの合成 (2009)
  • Author(s): 嶋本達男・中建介・有田学・森崎泰弘・中條善樹
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学黒髪キャンパス、熊本
  • Year and Date: 2009-09-18
• [Presentation] 1,4-ジヒドロ-1,4-ジアルシニン酸無水物を用いたヒ素含有ポリイミドの合成 (2009)
  • Author(s): 嶋本達男, 中建介, 有田学, 森崎泰弘, 中條善樹
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学・熊本
  • Year and Date: 2009-09-18
• [Presentation] ヒ素含有環状二座配位子-白金錯体の合成と光特性 (2009)
  • Author(s): 中建介, 嶋本達男, 加藤拓路, 有田学, 森崎泰弘, 中條善樹, 渡瀬星児, 松川公洋
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学・熊本
  • Year and Date: 2009-09-16
• [Presentation] ジアルシニン酸無水物の合成とその反応性 (2009)
  • Author(s): 嶋本達男・中建介・有田学・森崎泰弘・中條善樹
  • Organizer: 第58回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場、神戸
  • Year and Date: 2009-05-29
• [Presentation] ジアルシニン酸無水物の合成とその反応性 (2009)
  • Author(s): 嶋本達男, 中建介, 有田学, 森崎泰弘, 中條善樹
  • Organizer: 第58回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場・神戸
  • Year and Date: 2009-05-29
• [Presentation] Synthesis of Rigid Organic-Inorganic Hybrid Frameworks for Optical and Biomedical Application (2009)
  • Author(s): 中建介
  • Organizer: U.S.-Japan Joint Workshop on Future Trends in Organic-Inorganic Nanocomposite Hybrid Materials NANO HYBRIDS 2009
  • Place of Presentation: Daicel Chemical Industries, Ltd., Himeji, Japan(招待講演)
  • Year and Date: 2009-05-15
• [Presentation] Synthesis of Rigid Organic-Inorganic Hybrid Framework for Optical and Biomedical Application (2009)
  • Author(s): Naka, K.
  • Organizer: U.S.-Japan Joint Workshop
  • Place of Presentation: 赤穂、兵庫
  • Year and Date: 2009-05-15
• [Presentation] ヒ素含有二座配位子を用いた選択的白金単核および複核錯体の合成機構 (2009)
  • Author(s): 嶋本達男・中建介・有田学・森崎泰弘・中條善樹
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス、千葉
  • Year and Date: 2009-03-27
• [Presentation] Organic-Inorganic Hybrid Polymers Derived from Homocyclic Compounds of Group 15 Elements (2008)
  • Author(s): 中建介
  • Organizer: IUMRS-ICA 2008
  • Place of Presentation: Nagoya Congress Center, Nagoya, Japan(招待講演)
  • Year and Date: 2008-12-09
• [Presentation] Organic-Inorganic Hybrid polymers Derived from Homocyclic Compounds of Group 15 Elements (2008)
  • Author(s): K. Naka, T. Umeyama, A. Nakahashi, M. Arita, Y. Chujo
  • Organizer: IUMRS-ICA 2008
  • Place of Presentation: 名古屋
  • Year and Date: 2008-11-12
• [Book] ヘテロ元素の特徴を活かした新機能材料、有機ヒ素機能材料 (2010)
  • Author(s): 中建介・中條善樹
  • Publisher: シーエムシー出版