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Molecular design and exploitation of spin-polarized molecular wires based on macrocyclic aromatic amines

Research Project

Project/Area Number 20350065
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionKyoto University

Principal Investigator

TANAKA Kazuyoshi  Kyoto University, 工学研究科, 教授 (90155119)

Co-Investigator(Kenkyū-buntansha) ITO Akihiro  京都大学, 大学院・工学研究科, 准教授 (90293901)
FUENO Hiroyuki  京都大学, 大学院・工学研究科, 助教 (30212179)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2010: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2009: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2008: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
Keywords電気・磁気的機能 / スピン偏極分子ワイヤー / 大環状分子 / ラジカル分子 / 芳香族アミン / スピン偏極 / 混合原子価状態 / 大環状有機分子
Research Abstract

Novel molecular wires based on polycyclic aromatic amines were successfully prepared. These molecular wires exhibited strong electron-donating ability, and moreover, when they are oxidized, the generated spin was found to be delocalized over the whole molecular wire. In addition, nitroxide radical centers as a localized spin source were introduced into the newly prepared molecular wires. As a whole, the definite magnetic interaction was observed between the localized spins and the delocalized spin that was generated over molecular wire.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (42 results)

All 2011 2010 2009 2008 Other

All Journal Article (18 results) (of which Peer Reviewed: 18 results) Presentation (22 results) Remarks (2 results)

  • [Journal Article] Spin-Delocalization in Charged States of Para-Phenylene-Linked Dendritic Oligoarylamine2011

    • Author(s)
      A.Ito, D.Sakamaki, Y.Ichikawa, K.Tanaka
    • Journal Title

      Chem.Mater. 23

      Pages: 841-850

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spin-Delocalization in Charged States of Para-Phenylene-Linked Dendritic Oligoarylamine2011

    • Author(s)
      Akihiro Ito, Daisuke Sakamaki, Yusuke Ichikawa, Kazuyoshi Tanaka
    • Journal Title

      Chemistry of Materials

      Volume: 23 Pages: 841-850

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Characterization of N-Anisyl-Substituted Hexaaza[1_6]paracyclophane2010

    • Author(s)
      A.Ito, Y.Yokoyama, R.Aihara, K.Fukui, S.Eguchi, K.Shizu, K.Tanaka
    • Journal Title

      Angew.Chem.Int.Ed. 49

      Pages: 8205-8208

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Para-Phenylene-Bridged Spirobi(triarylamine) Dimer with Four Perpendicularly Linked Redox-Active π Systems2010

    • Author(s)
      A.Ito, K.Hata, K.Kawamoto, Y.Hirao, K.Tanaka, M.Shiro, K.Furukawa, T.Kato
    • Journal Title

      Chem.Eur.J. 16

      Pages: 10866-10878

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Macrocyclic Oligoarylamine-Based Spin System2010

    • Author(s)
      A.Ito, K.Tanaka
    • Journal Title

      Pure Appl.Chem. 82

      Pages: 979-989

    • NAID

      120006653912

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Para-Phenylene-Bridged Spirobi(triarylamine) Dimer with Four Perpendicularly Linked Redox-Active π Systems2010

    • Author(s)
      Akihiro Ito, Kazuhira Hata, Kensuke Kawamoto, Yasukazu Hirao, Kazuyoshi Tanaka, Motoo Shiro, Ko Furukawa, Tatsuhisa Kato
    • Journal Title

      Chemistry European Journal

      Volume: 16 Pages: 10866-10878

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Characterization of N-Anisyl-Substituted Hexaaza[1_6]paracyclophane2010

    • Author(s)
      Akihiro Ito, Yuichiro Yokoyama, Ryosuke Aihara, Koji Fukui, Shoko Eguchi, Katsuyuki Shizu, Kazuyoshi Tanaka
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 49 Pages: 8205-8208

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Macrocyclic Oligoarylamine-Based Spin System2010

    • Author(s)
      A.Ito, K.Tanaka
    • Journal Title

      Pure and Applied Chemistry 82

      Pages: 979-989

    • NAID

      120006653912

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polycationic States of Oligoanilines Based on Wurster's Blue2009

    • Author(s)
      A.Ito, D.Sakamaki, H.Ino, A.Taniguchi, Y.Hirao, K.Tanaka, K.Kanemoto, T.Kato
    • Journal Title

      Eur.J.Org.Chem. 2009

      Pages: 4441-4450

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-Spin Polycationic States of An Alternate meta-para-Linked Oligoarylamine Incorporating Two Macrocycles2009

    • Author(s)
      D.Sakamaki, A.Ito, K.Furukawa, T, Kato, K.Tanaka
    • Journal Title

      Chem.Commun. 2009

      Pages: 4524-4526

    • NAID

      120002317415

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electronic Structures of Newly Designed Two-Dimensional High-Spin Organic Polymers2009

    • Author(s)
      A.Ito, H.Ino, K.Tanaka
    • Journal Title

      Polyhedron 28

      Pages: 2080-2086

    • NAID

      120002317416

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-Spin Polycationic States of An Alternate Meta-Para-linked Oligoarylamine Incorporating Two Macrocycles2009

    • Author(s)
      D.Sakamaki, A.Ito, K.Furukawa, T.Kato, K.Tanaka
    • Journal Title

      Chemical Communications 2009

      Pages: 4524-4526

    • NAID

      120002317415

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polycationic States of Oligoanilines Based on Wurster's Blue2009

    • Author(s)
      A.Ito, D.Sakamaki, H.Ino, A.Taniguchi, Y.Hirao, K.Tanaka, K.Kanemoto, T.Kato
    • Journal Title

      European Journal of Organic Chemistry 2009

      Pages: 4441-4450

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic structures of newly designed two-dimensional high-spin organic polymers2009

    • Author(s)
      A. Ito, H. Ino, K. Tanaka
    • Journal Title

      Polyhedron

    • NAID

      120002317416

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Trimacrocyclic Arylamine and its Polycationic States2008

    • Author(s)
      A.Ito, Y.Yamagishi, K.Fukui, S.Inoue, Y.Hirao, K.Furukawa, T.Kato, K.Tanaka
    • Journal Title

      Chem.Commun. 2008

      Pages: 6573-6575

    • NAID

      120001815087

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] An N-Substituted Aza[1_4]metacyclophane Tetracation : A Spin-Quintet Tetraradical with Four para-Phenylenediamine-Based Semi-Quinone Moieties2008

    • Author(s)
      A.Ito, S.Inoue, Y.Hirao, K.Furukawa, T.Kato, K.Tanaka
    • Journal Title

      Chem.Commun. 2008

      Pages: 3242-3244

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] An N-substituted aza[1_4]metacyclophane tetracatlon : spin-quintet tetraradical with four para-phenylenediamine-based semi-qulnone moieties2008

    • Author(s)
      A. Ito, S. Inoue, Y. Hirao, K. Furukawa, T. Kato, K. Tanaka
    • Journal Title

      Chemical Communications 2008

      Pages: 3242-3244

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Trimacrocyclic arylamine and its polycationic states2008

    • Author(s)
      A. Ito, Y. Yamagishi, K. Fukui, S. Inoue, Y. Hirao, K. Furukawa, T. Kato, K. Tanaka
    • Journal Title

      Chemical Communications 2008

      Pages: 6573-6575

    • NAID

      120001815087

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 積層構造を有する芳香族アミンの合成と電子物性2011

    • Author(s)
      酒巻大輔, 伊藤彰浩, 田中一義, 古川貢, 加藤立久
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学横浜キャンパス
    • Year and Date
      2011-03-29
    • Related Report
      2010 Final Research Report
  • [Presentation] 積層構造を有する芳香族アミンの合成と電子状態2011

    • Author(s)
      酒巻大輔, 伊藤彰浩, 田中一義, 古川貢, 加藤立久
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 電子伝導ワイヤー部位と発光部位を有するπ共役有機超分子の合成と物性2011

    • Author(s)
      石川泰嗣, 酒巻大輔, 笛野博之, 伊藤彰浩, 田中一義, 田中彰治, 阿部幸浩, 佐藤万紀, 小松陽子, 和田恭雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and Electronic Properties of a Cage-Like Aromatic Amine2010

    • Author(s)
      D.Sakamaki, A.Ito, K.Furukawa, T.Kato, K.Tanaka
    • Organizer
      The 12th International Conference on Molecule-Based Magnets
    • Place of Presentation
      Beijing, China
    • Year and Date
      2010-10-10
    • Related Report
      2010 Final Research Report
  • [Presentation] Synthesis and Electronic Properties of a Cage-Like Aromatic Amine2010

    • Author(s)
      Daisuke Sakamaki, Akihiro Ito, Ko Furukawa, Tatsuhisa Kato, Kazuyoshi Tanaka
    • Organizer
      The 12th International Conference on Molecule-Based Magnets
    • Place of Presentation
      Peking University, Beijing, China
    • Year and Date
      2010-10-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Vibronic Couplings in High- and Low-Spin States of Phenylene Diamines2010

    • Author(s)
      Naoya Iwahara, Tohru Sato, Kazuyoshi Tanaka
    • Organizer
      The 12th International Conference on Molecule-Based Magnets
    • Place of Presentation
      Peking University, Beijing, China
    • Year and Date
      2010-10-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] ダブルデッカー型トリフェニルアミンの合成と電子物性2010

    • Author(s)
      酒巻大輔, 横山祐一郎, 伊藤彰浩, 田中一義
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2010-09-10
    • Related Report
      2010 Final Research Report
  • [Presentation] ダブルデッカー型トリフェニルアミンの合成と電子物性2010

    • Author(s)
      酒巻大輔, 横山祐一郎, 伊藤彰浩, 田中一義
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋大学 東山キャンパス
    • Year and Date
      2010-09-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Electronic Structures of Spiro-Fused Oligo (triarylamine)s2010

    • Author(s)
      Akihiro Ito, Tanaka Kazuyoshi
    • Organizer
      9th International Symposium on Functional π-Electron Systems
    • Place of Presentation
      Georgia Institute of Technology, Atlanta, Georgia, USA
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Electronic Structures of Spiro-Fused Oligo(triarylamine)s2010

    • Author(s)
      A.Ito, K.Tanaka
    • Organizer
      The 9th International Symposium on Functional π-Electronic Systems
    • Place of Presentation
      Atlanta, USA
    • Year and Date
      2010-05-25
    • Related Report
      2010 Final Research Report
  • [Presentation] Synthesis and Electronic Properties of a Triphenylamine Double-Decker2010

    • Author(s)
      Daisuke Sakamaki, Yuichiro Yokoyama, Akihiro Ito, Kazuyoshi Tanaka
    • Organizer
      9th International Symposium on Functional π-Electron Systems
    • Place of Presentation
      Georgia Institute of Technology, Atlanta, Georgia, USA
    • Year and Date
      2010-05-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and Electronic Properties of a Triphenylamine Double-Decker2010

    • Author(s)
      D.Sakamaki, Y.Yokoyama, A.Ito, K.Tanaka
    • Organizer
      The 9th International Symposium on Functional p-Electronic Systems
    • Place of Presentation
      Atlanta, USA
    • Year and Date
      2010-05-24
    • Related Report
      2010 Final Research Report
  • [Presentation] 多環性大環状芳香族アミンの合成と電子物性2009

    • Author(s)
      相原涼介, 横山祐一郎, 伊藤彰浩, 田中一義
    • Organizer
      第20回基礎有機化学討論会
    • Place of Presentation
      群馬大学工学部桐生キャンパス
    • Year and Date
      2009-09-30
    • Related Report
      2010 Final Research Report
  • [Presentation] 2つの大環状部位を含む芳香族アミンの合成と電子物性2009

    • Author(s)
      酒巻大輔, 伊藤彰浩, 田中一義, 古川貢, 加藤立久
    • Organizer
      第20回基礎有機化学討論会
    • Place of Presentation
      群馬大学工学部桐生キャンパス
    • Year and Date
      2009-09-28
    • Related Report
      2010 Final Research Report
  • [Presentation] スピロ結合したトリフェニルアミンの合成と物性2009

    • Author(s)
      川本健介, 畑一平, 平尾泰一, 伊藤彰浩, 田中一義,
    • Organizer
      第20回基礎有機化学討論会
    • Place of Presentation
      群馬大学工学部桐生キャンパス
    • Year and Date
      2009-09-28
    • Related Report
      2010 Final Research Report
  • [Presentation] Multiradicals of Spiro-Fused Oligoarylamine)s2009

    • Author(s)
      A.Ito, K.Tanaka
    • Organizer
      13th International Symposium of Novel Aromatic Compounds-Satellite Meeting-Diradicals and Multiradicals: Theory and Experiment
    • Place of Presentation
      Namuir, Belgium
    • Year and Date
      2009-07-27
    • Related Report
      2010 Final Research Report
  • [Presentation] Multiradicals of Spiro-Fused Oligo(triarylamine)s2009

    • Author(s)
      A.Ito
    • Organizer
      ISNA-13 Satellite Meeting, Diradicals and Multiradicals : Theory and Experiment
    • Place of Presentation
      Namuir, Belgium
    • Year and Date
      2009-07-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Macrocyclic Oligoarylamine-Based Spin System2009

    • Author(s)
      A.Ito, K.Furukawa, T.Kato, K.Tanaka
    • Organizer
      13th International Symposium of Novel Aromatic Compounds
    • Place of Presentation
      Luxembourg
    • Year and Date
      2009-07-21
    • Related Report
      2010 Final Research Report
  • [Presentation] 多環性大環状アミンの合成2008

    • Author(s)
      相原涼介, 横山祐一郎, 伊藤彰浩, 田中一義
    • Organizer
      第19回基礎有機化学討論会
    • Place of Presentation
      大阪大学コンベンションセンター
    • Year and Date
      2008-10-05
    • Related Report
      2010 Final Research Report
  • [Presentation] 局在スピンを有する芳香族アミンの電子状態に関する研究2008

    • Author(s)
      横山祐一郎, 松永啓吾, 平尾泰一, 伊藤彰浩, 田中一義
    • Organizer
      第19回基礎有機化学討論会
    • Place of Presentation
      大阪大学コンベンションセンター
    • Year and Date
      2008-10-05
    • Related Report
      2010 Final Research Report
  • [Presentation] 大環状芳香族アミンの合成と電子物性2008

    • Author(s)
      酒巻大輔, 山岸祐子, 井上修治, 伊藤彰浩, 田中一義
    • Organizer
      第19回基礎有機化学討論会
    • Place of Presentation
      大阪大学コンベンションセンター(大阪府・吹田市)
    • Year and Date
      2008-10-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] 局在スピンを有する大環状芳香族アミンの合成と電子物性2008

    • Author(s)
      山岸祐子, 井上修治, 平尾泰一, 伊藤彰浩, 田中一義, 古川貢, 加藤立久
    • Organizer
      第19回基礎有機化学討論会
    • Place of Presentation
      大阪大学コンベンションセンター
    • Year and Date
      2008-10-04
    • Related Report
      2010 Final Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.moleng.kyoto-u.ac.jp/~moleng_03/index_J.html

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.moleng.kyoto-u.ac.jp/~moleng_03/research.html

    • Related Report
      2008 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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