Photocatalytic reactions utilizing the features unique to microreactors

• Project/Area Number: 20510115
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Microdevices/Nanodevices
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: MATSUSHITA Yoshihisa Tokyo Institute of Technology, 大学院・理工学研究科, 助教 (80240753)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000); Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
• Keywords: マイクロリアクター / 光触媒 / ナンバリングアップ / 高付加価値化合物 / 選択的酸化 / 二酸化炭素の資源化

Research Abstract

Microreaction systems specialized photocatalytic reactions have been successfully applied to a wide range of chemical transformations, for instance photocatalytic recycling of carbon dioxide and photocatalytic synthesis of high value added compounds utilizing the features unique to microspace. We have developed a palatalized micro-flow reaction system with immobilized photocatalyst nanoparticles to increase the reaction volume up to 150 times larger than that of single channel microreaction systems.

Research Products

• [Journal Article] Photodimerization of Maleic Anhydride in a Microreactor Without Clogging (2010)
  • Author(s): Tomoaki Horie, Motoshige Sumino, Takumi Tanaka, Yoshihisa Matsushita, Teijiro Ichimura, Jun-ichi Yoshida
  • Journal Title: Org.Process Res.Dev. 14 Pages: 405-410
  • Peer Reviewed
• [Journal Article] Phototdimerization of Maleic Anhydride in a Microreactor Without Clogging (2010)
  • Author(s): Horie, Tomoaki ; Sumino, Motoshige ; Tanaka, Takumi ; Matsushita, Y. ; Ichimura, Teijiro ; Yoshida, Jun-Ichi
  • Journal Title: Organic Process Research & Developmet 14 Pages: 405-410
  • Peer Reviewed
• [Journal Article] Photocatalytic Oxidetion of Aromatic Compounds in Microreactors under Pipe-Flow Conditions (2009)
  • Author(s): Y.Matsushita, M.Iwasawa, T.Suzuki, T.Ichimura
  • Journal Title: Chem.Lett. 38 Pages: 846-847
  • Peer Reviewed
• [Journal Article] Multiphase Photocatalytic Oxidation in a Microreactor (2009)
  • Author(s): Y.Matsushita, M.Iwasawa, T.Suzuki, T.Ichimura
  • Journal Title: Chem.Lett. 38 Pages: 846-847
  • NAID: 10025125361
  • Peer Reviewed
• [Journal Article] Photocatalytic Reactions in Microreactors (2008)
  • Author(s): Y.Matsushita, N.Ohba, S.Kumada, K.Sakeda, T.Suzuki, T.Ichimura
  • Journal Title: Chem.Eng.J. 135S
  • Peer Reviewed
• [Journal Article] N-Alkylation of Amines by Photocatalytic Reaction in a Microreaction System (2008)
  • Author(s): Y.Matsushita, N.Ohba, T.Suzuki, T.Ichimura
  • Journal Title: Catalysis Today 132 Pages: 153-158
  • Peer Reviewed
• [Journal Article] マイクロ流路内の光反応 (2008)
  • Author(s): 松下慶寿
  • Journal Title: 光必学 39 Pages: 93-101
  • NAID: 10024279378
  • Peer Reviewed
• [Journal Article] マイクロ流路内の光反応 (2008)
  • Author(s): 松下慶寿
  • Journal Title: 光化学 39 Pages: 93-101
  • NAID: 10024279378
  • Peer Reviewed
• [Journal Article] Multiphase Photocatalytic Reactions in a Microreaction System (2008)
  • Author(s): Y. Matsushita, Y. Sato, N. Ohba, N. Usami, T. Suzuki, T. Ichimura
  • Journal Title: Micro Total Analysis Systems 2008 2 Pages: 1257-1259
  • Peer Reviewed
• [Presentation] 光触媒を用いた高付加価値化合物合成による光エネルギー変換 (2011)
  • Author(s): 松下慶寿, Salah Eid, 大川原真一, Ahmed Hamza H.Ali
  • Organizer: 電気化学会第78回大会
  • Place of Presentation: 横浜
  • Year and Date: 2011-03-29
• [Presentation] Microreaction System for Highly Selective and Environmentally Benign Photocatalytic Synthesis of Aromatic Aldehydes (2010)
  • Author(s): Yoshihisa Matsushita, Yohei Fukazawa, Shinichi Ookawara, Yoshikazu Kimura
  • Organizer: 13th Asia Pacific Confederation of Chemical Engineering Congress
  • Place of Presentation: 台北
  • Year and Date: 2010-10-06
• [Presentation] Microreaction System for Highly Selective and Environmentally Benign Photocatalytic Synthesis of Aromatic Aldehydes (2010)
  • Author(s): Yoshihisa Matsushita, Yohei Fukazawa, Shinichi Ookawara, Yoshikazu Kimura
  • Organizer: 13^<th> Asia Pacific Confederation of Chemical Engineering Congress
  • Place of Presentation: 台北
  • Year and Date: 2010-10-06
• [Presentation] 光触媒担持マイクロリアクターを用いた医薬品原料の合成 (2010)
  • Author(s): 松下慶寿、深澤洋平、大川原真一、磯崎輔、鈴木正
  • Organizer: 光化学討論会2010
  • Place of Presentation: 千葉
  • Year and Date: 2010-09-09
• [Presentation] マイクロリアクターを用いた二酸化炭素の光触媒還元反応 (2010)
  • Author(s): 深澤洋平、松下慶寿、大川原真一、磯崎輔、鈴木正
  • Organizer: 光化学討論会2010
  • Place of Presentation: 千葉
  • Year and Date: 2010-09-08
• [Presentation] PHOTOCATALYTIC SYNTHESIS OF HIGH VALUE ADDED COMPOUNDS IN MICROSTRUCTURED DEVICES (2010)
  • Author(s): Yoshihisa Matsushita, Yohei Fukazawa,Tasuku Isozki, Tadashi Suzuki
  • Organizer: IUPAC Photochemistry 2010
  • Place of Presentation: Ferrara, Italy
  • Year and Date: 2010-07-13
• [Presentation] 光触媒担持マイクロリアクターを用いた環境負荷低減型新規合成プロセス (2010)
  • Author(s): 松下慶寿、大川原真一、本間俊介
  • Organizer: 化学とナノ・マイクロシステム研究会
  • Place of Presentation: 東京
  • Year and Date: 2010-06-13
• [Presentation] Highly Selective and Environmentally Benign Photocatalytic Reaction Processes in Microstructured Devices (2010)
  • Author(s): Yoshihisa Matsushita, Yoshiyuki Sekine, Tadashi Suzuki, Teijiro Ichimura
  • Organizer: 11th International Conference on Microreaction Technology
  • Place of Presentation: 京都
  • Year and Date: 2010-03-09
• [Presentation] 環境負荷低減型新規酸化プロセスのためのマイクロ反応デバイス (2010)
  • Author(s): 松下慶寿
  • Organizer: 化学工学会 第75年会
  • Place of Presentation: 鹿児島大学
• [Presentation] Highly Selective and Environmentally Benign Photocatalytic Reaction Processes in Microstructured Devices (2010)
  • Author(s): 松下慶寿
  • Organizer: IMRET11
  • Place of Presentation: 京都
• [Presentation] Environmentally Benign Photochemical Synthesis in Microstructured Devices (2010)
  • Author(s): 松下慶寿
  • Organizer: Nano/Molecular Photochemistry and Nanomaterials for Green Energy Development
  • Place of Presentation: Cairo
• [Presentation] マイクロリアクターを用いた環境負荷低減型新規光反応プロセスの開発 (2009)
  • Author(s): 松下慶寿
  • Organizer: フローマイクロ合成研究会第44回研究会
  • Place of Presentation: 大阪
  • Year and Date: 2009-12-04
• [Presentation] マイクロ反応システム実用化のためのアプローチ (2009)
  • Author(s): 松下慶寿
  • Organizer: 光化学討論会2009
  • Place of Presentation: 桐生
  • Year and Date: 2009-09-18
• [Presentation] 光触媒担持マイクロリアクターによるグリーン合成 (2009)
  • Author(s): 松下慶寿
  • Organizer: 化学工学会 第41回秋季大会
  • Place of Presentation: 広島大学
  • Year and Date: 2009-09-17
• [Presentation] Micro Reaction System for Photochemical Reactions (2009)
  • Author(s): 松下慶寿
  • Organizer: International Conference on Photochemistry
  • Place of Presentation: Toledo
  • Year and Date: 2009-07-22
• [Presentation] マイクロチャネル内の多相流を用いた光反応 (2009)
  • Author(s): 松下 慶寿, 大場 伸子, 宇佐見 直樹, 佐藤 有理子, 鈴木 正, 市村 禎二郎
  • Organizer: 化学工学会第74年会
  • Place of Presentation: 東京
  • Year and Date: 2009-03-20
• [Presentation] 光触媒担持マイクロリアクターを用いた酸化反応 (2009)
  • Author(s): 松下慶寿, 佐藤有理子, 鈴木正, 市村禎二郎
  • Organizer: 第9回GSCシンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2009-03-09
• [Presentation] Photochemical Synthesis in a Microreaction System (2009)
  • Author(s): 松下慶寿
  • Organizer: 2009 AIChE Spring National Meeting
  • Place of Presentation: Tampa
• [Presentation] A Continuous Flow Microreaction System for Photosynthesis (2008)
  • Author(s): Y. Matsushita, N. Ohba, M. Iwasawa, Y. Satou, T. Suzuki, T. Ichimura
  • Organizer: The 5th Asian Photochemistry Conference
  • Place of Presentation: Beijing, China
  • Year and Date: 2008-11-02
• [Presentation] マイクロリアクターの特性を用いた光反応 (2008)
  • Author(s): 松下慶寿, 宇佐見直紀, 佐藤有理子, 鈴木 正, 市村 禎二郎
  • Organizer: 化学工学会第40回秋季大会
  • Place of Presentation: 東北大
  • Year and Date: 2008-09-25
• [Presentation] 気液固三相流を用いた光触媒反応 (2008)
  • Author(s): 松下慶寿, 佐藤有理子, 鈴木正, 市村禎二郎
  • Organizer: 第102回触媒討論会
  • Place of Presentation: 名古屋大
  • Year and Date: 2008-09-24
• [Presentation] Microreaction System For Photosynthesis Of High-Value Added Compounds (2008)
  • Author(s): Y. Matsushita, Y. Sato, N. Ohba, N. Usami, T. Suzuki, T. Ichimura
  • Organizer: International Symposium on Micro Chemical Process and Synthesis MiPS2008
  • Place of Presentation: Kyoto
  • Year and Date: 2008-09-13
• [Presentation] マイクロアクターを用いた光反応プロセスの強化 (2008)
  • Author(s): 松下慶寿, 宇佐見直紀, 佐藤有理子, 鈴木 正, 市村禎二郎
  • Organizer: 光化学討論会
  • Place of Presentation: 大阪府立大
  • Year and Date: 2008-09-11
• [Presentation] Microreaction System For Photosynthesis Of High-Value Added Compounds (2008)
  • Author(s): Y. Matsushita, Y. Sato, N. Ohba, N. Usami, T. Suzuki, T. Ichimura
  • Organizer: The 20th International Symposium on Chemical Reaction Engineering
  • Place of Presentation: Kyoto
  • Year and Date: 2008-09-08
• [Presentation] Photoreactions in a Microreaction System (2008)
  • Author(s): Y. Matsushita, N. Ohba, N. Usami, Y. Satou, T. Suzuki, T. Ichimura
  • Organizer: XXII IUPAC Symposium on Photochemistry 2008
  • Place of Presentation: Gothenburg, Sweden
  • Year and Date: 2008-07-29
• [Book] Microchemical Engineering in Practice, ed.by T.R.Dietrich (2009)
  • Author(s): T.Ichimura, Y.Matsushita, K.Sakeda, T.Suzuki
  • Publisher: John Wiley & Sons, Hoboken
• [Patent(Industrial Property Rights)] マイクロ反応装置およびマイクロ流路への気液供給方法 (2010)
  • Inventor(s): 松下慶寿, 他
  • Industrial Property Rights Holder: 東京工業大学、三井造船株式会社
  • Industrial Property Number: 2010-049284
  • Filing Date: 2010-03-05
• [Patent(Industrial Property Rights)] マイクロ流体装置 (2010)
  • Inventor(s): 松下慶寿、大川原真一, 他
  • Industrial Property Rights Holder: 東京工業大学
  • Industrial Property Number: 2010-038019
  • Filing Date: 2010-02-23
• [Patent(Industrial Property Rights)] 芳香族アルデヒド化合物の製造方法 (2010)
  • Inventor(s): 松下慶寿, 他
  • Industrial Property Rights Holder: 東京工業大学、三井造船株式会社、イハラニッケイ化学工業
  • Industrial Property Number: 2010-028091
  • Filing Date: 2010-02-10
• [Patent(Industrial Property Rights)] 共同出願人の要請により秘匿 (2010)
  • Inventor(s): 共同出願人の要請により秘匿
  • Industrial Property Rights Holder: 共同出願人の要請により秘匿
  • Industrial Property Number: 2010-028091
  • Filing Date: 2010-02-10
• [Patent(Industrial Property Rights)] 共同出願人の要請により秘匿 (2010)
  • Inventor(s): 共同出願人の要請により秘匿
  • Industrial Property Rights Holder: 共同出願人の要請により秘匿
  • Industrial Property Number: 2010-030142
  • Filing Date: 2010-02-15
• [Patent(Industrial Property Rights)] 共同出願人の要請により秘匿 (2010)
  • Inventor(s): 共同出願人の要請により秘匿
  • Industrial Property Rights Holder: 共同出願人の要請により秘匿
  • Industrial Property Number: 2010-038019
  • Filing Date: 2010-02-23
• [Patent(Industrial Property Rights)] 共同出願人の要請により秘匿 (2010)
  • Inventor(s): 共同出願人の要請により秘匿
  • Industrial Property Rights Holder: 共同出願人の要請により秘匿
  • Industrial Property Number: 2010-049284
  • Filing Date: 2010-03-05
• [Patent(Industrial Property Rights)] 二酸化炭素の固定化装置およびその方法 (2008)
  • Inventor(s): 松下慶寿, 他
  • Industrial Property Rights Holder: 東京工業大学、三井造船株式会社
  • Filing Date: 2008-07-01