Synthesis of [60]fullerene-containing interlocked compounds aimed at application into molecular switches

• Project/Area Number: 20550031
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Gunma University
• Principal Investigator: NAKAMURA Yosuke Gunma University, 大学院・工学研究科, 教授 (60261864)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2008: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
• Keywords: フラーレン / ロタキサン / カテナン / ドナー-アクセプター相互作用 / 分子スイッチ / 超分子 / TTF / ナフタレンテトラカルボン酸ジイミド

Research Abstract

[60]Fullerene-containing [2]rotaxanes, consisting of an axle compound bearing an electron-donating 1,5-dialkoxynaphthalene or TTF moiety and a macrocycle containing electron-deficient naphthalenetetracarboxylic diimide moieties, were first successfully synthesized by using the donor-acceptor interaction and fully characterized.

Research Products

• [Journal Article] Exohedral Functionalization of Fullerenes and Supramolecular Chemistry (2011)
  • Author(s): Y.Nakamura, S.-i.Kato
  • Journal Title: Chem.Rec. 11 Pages: 77-94
  • Peer Reviewed
• [Journal Article] Synthesis of [60]fullerene-containing [2]rotaxanes using axle molecules bearing donor moiety (2011)
  • Author(s): Y.Kasai, C.Sakamoto, N.Muroya, S.-i.Kato, Y.Nakamura
  • Journal Title: Tetrahedron Lett. 52 Pages: 623-625
  • Peer Reviewed
• [Journal Article] Synthesis of [60]fullerene-containing [2]rotaxanes using axle molecules bearing donor moiety (2011)
  • Author(s): Yoshinori Kasai
  • Journal Title: Tetrahedron Letters Volume: Vol.52 Pages: 623-625
  • Peer Reviewed
• [Journal Article] Exohedral Functionalization of Fullerenes and Supramolecular Chemistry (2011)
  • Author(s): Yosuke Nakamura
  • Journal Title: Chemical Record Volume: Vol.11(in press)
  • Peer Reviewed
• [Journal Article] Kinetic Study on Huisgen Reaction Catalyzed by Copper(I): Triazol Formation from Water-Soluble Alkyne and Alkyl Azide (2009)
  • Author(s): Y.Kasuga, M.Ito, W.Onoda, Y.Nakamura, S.Inokuma, T.Matsuda, J.Nishimura
  • Journal Title: Heterocycles 78 Pages: 983-997
  • Peer Reviewed
• [Journal Article] Synthesis and Photophysical Properties of N-Arylcarbazolophanes (2009)
  • Author(s): Hideyuki Shimizu
  • Journal Title: Bulletin of the Chemical Society of Japan 82 Pages: 860-869
  • Peer Reviewed
• [Journal Article] Kinetic Study on Huisgen Reaction Catalyzed by Copper(I):Triazol Formation from Water-Soluble Alkyne and Alkyl Azide (2009)
  • Author(s): Yosuke Kasuga
  • Journal Title: Heterocycles 78 Pages: 983-997
  • Peer Reviewed
• [Journal Article] Substituent Effects on Photophysical Properties of N-Thienylcarbazoles (2009)
  • Author(s): Hideyuki Shimizu
  • Journal Title: Heterocycles 78(in press)
  • Peer Reviewed
• [Journal Article] Synthesis and Photophysical Properties of N-Arylcarbazolophanes (2009)
  • Author(s): Hideyuki Shimizu
  • Journal Title: Bulletin of the Chemlical Society of Japan 82(in press)
  • Peer Reviewed
• [Presentation] ドナー部位を有する軸分子を用いたフラーレン系インターロック化合物の合成 (2010)
  • Author(s): 室谷直輝、加藤真一郎、中村洋介
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋大学(名古屋)
  • Year and Date: 2010-09-10
• [Presentation] ドナー部位を有する軸分子を用いたフラーレン系インターロック化合物の合成 (2010)
  • Author(s): 中村洋介
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋大学(名古屋市)
  • Year and Date: 2010-09-10
• [Presentation] フラーレンの官能基化と超分子化学 (2009)
  • Author(s): 中村洋介
  • Organizer: 第37回フラーレン・ナノチューブシンポジウム
  • Place of Presentation: つくば国際会議場(筑波)(依頼講演)
  • Year and Date: 2009-09-01
• [Presentation] フラーレンの官能基化と超分子化学(依頼講演) (2009)
  • Author(s): 中村洋介
  • Organizer: 第37回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: つくば国際会議場(筑波)
  • Year and Date: 2009-09-01
• [Presentation] フラーレン系インターロック化合物の合成と分子スイッチへの展開 (2009)
  • Author(s): 中村洋介
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2009-03-29
• [Book] 電子共役系有機材料の創製・機能開発・応用 (2008)
  • Author(s): 中村洋介、他
  • Publisher: シーエムシー出版