Understanding of photochemistry of iridium triscyclometalated complexes by their optical and geometrical isomerizations
| Project/Area Number |
20550056
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Chiba University |
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Principal Investigator |
KARATSU Takashi Chiba University, 大学院・工学研究科, 教授 (70214575)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2008: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
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| Keywords | 機能材料 / 錯体化学 / 発光材料 / 光化学 / イリジウム錯体 / 幾何異性体 / 光学異性体 / 有機エレクトロルミネッセンス |
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| Research Abstract |
Iridium (III) triscyclometalated complexes have attracted much attention as the material for the organic light emitting diode (OLED) because of their high performance of electroluminescence. The complex has a pair of geometrical isomer and optical isomer. To elucidate photochemical geometrical one-way isomerization, experimental and theoretical approaches were applied and successfully we have understood the mechanism.
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Report
(4 results)
Research Products
(108 results)
