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A study on defect formation in hydrogen absorbing alloys during hydrogen absorption-desorption cycling

Research Project

Project/Area Number 20560615
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionOsaka University

Principal Investigator

ARAKI Hideki  大阪大学, 工学研究科, 教授 (20202749)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2008: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords格子欠陥 / 陽電子消滅 / 水素吸蔵合金
Research Abstract

Hydrogen absorbing alloys are ingredients essential for switching to clean energy. LaNi_5-based alloys are most frequently used as hydrogen storage materials for electrodes of rechargeable batteries, purification of hydrogen and so on, and it is known that their reversible hydrogen absorbing capacities are decreased by the hydrogen absorption-desorption cycling. In this work we have studied, with positron lifetime spectroscopy, the degradation of LaNi_5-based alloys during the pressure-induced cycling at 248K, and revealed that the decrease in hydrogen absorbing capacity is attributed at least partly to lattice defects formed during hydriding.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (9 results)

All 2009 2008

All Journal Article (9 results) (of which Peer Reviewed: 9 results)

  • [Journal Article] Behavior of vacancy formation and recovery during hydrogenation cycles in LaNi_<4. 93> Sn_<0. 27>2009

    • Author(s)
      Kouji Sakaki, Ryosuke Date, Masataka Mizuno, Hideki Araki, Yumiko Nakamura, Yasuharu Shirai, Robert C. Bowman Jr., Etsuo Akiba
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 477巻 Pages: 205-211

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] The effect of substitutional elements(Al, Co) in LaNi<_4. 5> M_<0. 5> on the lattice defect formation in the initial hydrogenation and dehydrogenation2009

    • Author(s)
      Kouji Sakaki, Etsuo Akiba, Masataka Mizuno, Hideki Araki, Yasuharu Shirai
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 473巻 Pages: 87-93

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] The effect of substitutional elements (Al, Co) in LaNi4.5M0.5 on the lattice defect formation in the initial hydrogenation and dehydrogenation2009

    • Author(s)
      Kouji Sakaki
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 473 Pages: 87-93

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of hydrogen on stability of vacancy in LaNi52009

    • Author(s)
      Masataka Mizuno
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 165

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Behavior of vacancy formation and recovery during hydrogenation cycles in LaNi4.93Sn0.272009

    • Author(s)
      Kouji Sakaki
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 477 Pages: 205-211

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] First-principles study of vacancy formation in LaNi_52008

    • Author(s)
      Masataka Mizuno, Hideki Araki and Yasuharu Shirai
    • Journal Title

      Journal of Physics : Condensed Matter

      Volume: 20巻

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] First-principles study of vacancy formation in LaNi_52008

    • Author(s)
      Masataka Mizuno
    • Journal Title

      Journal of Physics : Condensed Matter 20

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic Structure and Bonding in Amorphous Zr_67Ni_33 and Zr_67Cu_332008

    • Author(s)
      Kazuki Sugita
    • Journal Title

      Advances in Quantum Chemistry 54

      Pages: 161-174

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relationship between Coercivity and Microstructural Changes During DR Treatment in the HDDR-processed Nd-Fe-Co-B Alloy2008

    • Author(s)
      Takeshi Nishiuchi
    • Journal Title

      IEEJ Transactions on Electrical and Electronic Engineering 3

      Pages: 390-393

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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