A study on controlling carbon deposition reaction over Nickel-based catalysts by employing carbon alloys as catalyst supports

• Project/Area Number: 20560718
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Catalyst/Resource chemical process
• Research Institution: Gunma University
• Principal Investigator: OZAKI Jun-ichi Gunma University, 大学院・工学研究科, 教授 (30214125)
• Co-Investigator(Kenkyū-buntansha): ARAI Masahiko 北海道大学, 大学院・工学研究院, 教授 (60125490) ; KUMAGAI Haruo 北海道大学, 大学院・工学研究院, 助教 (30234511)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2008: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
• Keywords: カーボンアロイ / 担持金属触媒 / 炭素析出 / メタン改質 / 核磁気共鳴

Research Abstract

Influences of N-doping to a nanoshell carbon (NS) and a carbon black(XC) on methane dry reforming reaction (CH_4+CO_2=CO+H_2)were studied. The order of catalytic activity was N-XC>N-NS>XC>NS. However, N-XC showed considerable reactivity for CO_2-gasification. We concluded that the Ni catalyst loaded on AO-treated NS (Ni/N-NS) was the best among the four catalysts.

Research Products

• [Journal Article] Nitrogen-Doped Carbon Materials Prepared by Ammoxidation as Solid Base Catalysts for Knoevenagel Condensation and Transesterification Reactions (2010)
  • Author(s): Naokatsu Kan-nari, Shuhei Okamura, Shin-ichiro Fujita, Jun-ichi Ozaki, Masahiko Arai
  • Journal Title: Advanced Synthesis & Catalysis 352 Pages: 1476-1484
  • Peer Reviewed
• [Journal Article] Enhancement of oxygen reduction activity of nanoshell carbons by introducing nitrogen atoms from metal phthalocyanines (2010)
  • Author(s): Jun-ichi Ozaki, Shin-ichi Tanifuji, Atsuya Furuichi, Katsutoshi Yabutsuka
  • Journal Title: Electrochim. Acta 55 Pages: 1864-1871
  • Peer Reviewed
• [Journal Article] The role of Fe species in the pyrolysis of Fe phthalocyanine and phenolic resin for preparation of carbon-based cathode catalysts (2010)
  • Author(s): Yuta Nabae, Shogo Moriya, Katsuyuki Matsubayashi, Stephen M. Lyth, Michal Malon, Libin Wu, Nazrul M. Islam , Yuka Koshigoe, Shigeki Kuroki, Masa-aki Kakimoto, Seizo Miyata, Jun-ichi Ozaki
  • Journal Title: Carbon 48 Pages: 2613-2624
  • Peer Reviewed
• [Journal Article] Enhanced Catalytic Activity of Carbon Alloy Codoped with Boron and Nitrogen for Oxygen Reduction Reaction (2010)
  • Author(s): Takashi Ikeda, Mauro Boero, Sheng-Feng Huang, Kiyoyuki Terakura, Masaharu Oshima, Jun-ichi Ozaki, Seizo Miyata
  • Journal Title: J.Phys.Chem.C 114 Pages: 8933-8937
  • Peer Reviewed
• [Journal Article] Hydrogen production by steam reforming of acetic acid : Comparison of conventionalsupported metal catalysts and metal-incorporated mesoporous smectite-like catalysts (2010)
  • Author(s): Nobuhiro Iwasa, Toshiyuki Yamane, Masaaki Takei, Jun-ichi Ozaki, Masahiko Arai
  • Journal Title: Int.J.Hydro.Energy 35 Pages: 110-117
  • Peer Reviewed
• [Journal Article] Nitrogen-Doped Carbon Materials Prepared by Ammoxidation as Solid Base Catalysts for Knoevenagel Condensation and Transesterification Reactions (2010)
  • Author(s): Naokatsu Kan-nari, Shuhei Okamura, Shin-ichiro Fujita, Jun-ichi Ozaki, Masahiko Arai
  • Journal Title: Advanced Synthesis & Catalysis Volume: 352 Pages: 1476-1484
  • Peer Reviewed
• [Journal Article] グニエラ炭のコークス但に及ぼすFe_2O_3およびCaCO_3添加の影響 (2010)
  • Author(s): 神成尚克, 高草木啓太, 尾崎純一, 原田靖之, 安楽大介, 藤本英和
  • Journal Title: 鉄と鋼 Volume: 96 Pages: 249-257
  • Peer Reviewed
• [Journal Article] Hydrogen production by steam reforming of acetic acid : Comparison of conventional supported metal catalysts and metal-incorporated mesoporous smectite-like catalysts (2010)
  • Author(s): N.Iwasa, T.Yamane, M.Takei, J.Ozaki, M.Arai
  • Journal Title: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 35 Pages: 110-117
  • Peer Reviewed
• [Journal Article] Enhancement of oxygen reduction activity of nanoshell carbons by introducing nitrogen atoms from metal phthalocyanines (2010)
  • Author(s): J.Ozaki, S.Tanifuji, A.Furuichi, A.Oya
  • Journal Title: Electrochimica Acta 55 Pages: 1864-1871
  • Peer Reviewed
• [Journal Article] Novel N-Doped Carbon Cathode Catalyst for Polymer Electrolyte Membrane Fuel Cells Formed on Carbon Black (2009)
  • Author(s): Rieko Kobayashi, Jun-ichi Ozaki
  • Journal Title: Chem.Lett. 38 Pages: 396-397
  • NAID: 10025121343
  • Peer Reviewed
• [Journal Article] Electrochemical behavior of carbon nanorod arrays having different grapheme orientations and rystallinity (2009)
  • Author(s): Hironori Orikasa, Takeshi Akahane, Michiyasu Okada, Yu Tong, Jun-ichi Ozaki, Takashi Kyotani
  • Journal Title: J.Mater.Chem. 19 Pages: 4615-4615
  • Peer Reviewed
• [Journal Article] Dispersibility in organic solvents of nanosized silica particles used in semiconductor package substrates (2009)
  • Author(s): Yoshihiro Nakamura, Rieko Kobayashi, Masayoshi Matsui, Jun-ichi Ozaki
  • Journal Title: Chem.Eng.J. 155 Pages: 493-493
  • Peer Reviewed
• [Journal Article] Selective hydrogenation of nitrobenzene to aniline in dense phase carbon dioxide ove Ni/γ-Al_2O_3 : Significance of molecular interactions (2009)
  • Author(s): X.Meng, H.Cheng, Y.Akiyama, Y.Hao, W.Qiao, Y.Yu, F.Zhao, S.Fujita, M.Arai
  • Journal Title: Journal of Catalysis 264 Pages: 1-10
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): R.Srivastava, S.Fujita, M.Arai
  • Journal Title: Progress in Porous Media Research(Nova, New York) Pages: 3-53
• [Presentation] 窒素ドープカーボンナノオニオンの酸素還元特性 (2010)
  • Author(s): 神成尚克,板倉崇仁,尾崎純一
  • Organizer: 第37回炭素材料学会
  • Place of Presentation: 姫路市民会館
  • Year and Date: 2010-12-03
• [Presentation] カーボンアロイNi触媒を用いたメタン乾式改質反応 (2010)
  • Author(s): 高橋卓也,尾崎純一,荒井正彦
  • Organizer: 第37回炭素材料学会
  • Place of Presentation: 姫路市民会館
  • Year and Date: 2010-12-02
• [Presentation] カーボンアロイ担体Ni触媒の活性と炭素析出特性 (2010)
  • Author(s): 高橋海樹,尾崎純一
  • Organizer: 第37回炭素材料学会
  • Place of Presentation: 姫路市民会館
  • Year and Date: 2010-12-02
• [Presentation] 褐炭担持Ni-Mg触媒の炭素析出挙動 (2010)
  • Author(s): 高橋望,宝田恭之,尾崎純一
  • Organizer: 第37回炭素材料学会
  • Place of Presentation: 姫路市民会館
  • Year and Date: 2010-12-02
• [Presentation] ナノダイヤモンド熱処理に伴うカーボンナノオニオンの構造形成とその酸素還元活性 (2010)
  • Author(s): 神成尚克,尾崎純一
  • Organizer: 第54回電池討論会
  • Place of Presentation: 愛知県産業労働センター
  • Year and Date: 2010-11-10
• [Presentation] Relation between structure and electrochemical oxygen reduction activity of carbons derived from nanocarbon doped naphthalene pitch (2010)
  • Author(s): Naokatsu Kannari, Manabu Matsumoto, Jun-ichi Ozaki
  • Organizer: The 2nd Japanese-German Symposium on Carbon Materials
  • Place of Presentation: AIST Tokyo Waterfront, Tokyo, Japan
  • Year and Date: 2010-09-21
• [Presentation] カーボン担持Ni触媒を用いたメタン乾式改質反応 (2010)
  • Author(s): 高橋卓也,高橋望,尾崎純一,荒井正彦
  • Organizer: 第19回日本エネルギー学会
  • Place of Presentation: 工学院大学
  • Year and Date: 2010-08-03
• [Presentation] Ni触媒への炭素析出に及ぼす担体の影響 (2010)
  • Author(s): 高橋海樹,高橋望,高草木啓太,武井雅明,尾崎純一
  • Organizer: 第19回日本エネルギー学会
  • Place of Presentation: 工学院大学
  • Year and Date: 2010-08-02
• [Presentation] Ni-Mg/Al_2O_3を用いた豚糞のガス化と炭素析出挙動 (2010)
  • Author(s): 高橋望,高草木啓太,李留云,宝田恭之,松井雅義,尾崎純一
  • Organizer: 第19回日本エネルギー学会
  • Place of Presentation: 工学院大学
  • Year and Date: 2010-08-02
• [Presentation] PREPARETION OF NANOSHELL FROM POLYOXINE COBALT COMPLEX AND ITS ELECTROCATALYTIC ACTIVITY FOR AN OXYGEN REDUCTIONREACTION (2010)
  • Author(s): Naokatsu Kannari, Rieko Kobayashi, Jun-ichi Ozaki
  • Organizer: Carbon2010
  • Place of Presentation: Clemson, South Carolina, USA.
  • Year and Date: 2010-07-13
• [Presentation] PREPARETION OF NANOSHELL FROM POLYOXINE COBALT COMPLEX AND ITS ELECTROCATALYTIC ACTIVITY FOR AN OXYGEN REDUCTION REACTION (2010)
  • Author(s): Naokatsu Kannari, Rieko Kobayashi, Jun-ichi Ozaki
  • Organizer: Carbon2010
  • Place of Presentation: Clemson, South Carolina, USA
  • Year and Date: 2010-07-13
• [Presentation] Ni触媒への炭素析出に及ぼす担体炭素の影響 (2009)
  • Author(s): 高橋望、高草木啓太、尾崎純一
  • Organizer: 第36回 炭素材料学会年会
  • Place of Presentation: 仙台
  • Year and Date: 2009-12-02
• [Presentation] ナノシェル炭素の構造と吸着水素の形態評価 (2009)
  • Author(s): 熊谷治夫, 金松好美, 神成尚克, 腰越悠香, 尾崎純一
  • Organizer: 第36回 炭素材料学会年会
  • Place of Presentation: 仙台
  • Year and Date: 2009-12-02
• [Presentation] 炭素析出効果を有するNi-Mg;/Al_2O_3触媒の調製 (2009)
  • Author(s): 高草木啓太、李留云、宝田恭之、松井雅義、尾崎純一
  • Organizer: 化学工学会米沢大会
  • Place of Presentation: 米沢
  • Year and Date: 2009-08-11
• [Presentation] Ni-Mg;/Al_2O_3触媒のキャラクタリゼーション (2009)
  • Author(s): 高草木啓太、松井雅義、尾崎純一
  • Organizer: 化学工学会米沢大会
  • Place of Presentation: 米沢
  • Year and Date: 2009-08-11
• [Presentation] ナノシェル担持Ni触媒への炭花水素からの炭素析出挙動 (2008)
  • Author(s): 武井雅朗
  • Organizer: 第35回炭素材料学会年会
  • Place of Presentation: つくば
  • Year and Date: 2008-12-05
• [Presentation] ナノシェル構造炭素上に吸蔵した水素の形態評価 (2008)
  • Author(s): 熊谷治夫
  • Organizer: 第35回炭素材料学会年会
  • Place of Presentation: つくば
  • Year and Date: 2008-12-05
• [Patent(Industrial Property Rights)] 触媒及びその製造方法 (2009)
  • Inventor(s): 尾崎純一、松井雅義、高草木啓太、武井雅朗
  • Industrial Property Rights Holder: 群馬大学
  • Industrial Property Number: 2009-095171
  • Filing Date: 2009-04-09