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Synthesis and Electro Optical Behavior of Conductive Polymer-Stabilized Metal Coordination Nano-polymers

Research Project

Project/Area Number 20710069
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Nanostructural science
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

YAMADA Mami  Tokyo University of Agriculture and Technology, 大学院・共生科学技術研究院, 特任准教授 (60362026)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2009: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2008: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Keywordsナノ粒子 / 導電性高分子 / 分光電気化学 / 薄膜 / 電気化学 / 有機無機ハイブリッド / 錯体 / プルシアンブルー / pHセンサー / エレクトロクロミック
Research Abstract

A novel hybrid nano-material of a Prussian blue nanoparticle (PB NPs) stabilized by the π-conjugated polymer PEDOT. PEDOT/PB NPs were prepared. PEDOT/PB NPs were effectively protected by the anionic sulfonate groups of PEDOT, and the resulting NPs were water-soluble. PEDOT/PB NPs were fabricated as a film on an ITO electrode which displayed an electrochromic property. PEDOT/PB NPs presented the unique property of multiple-color pH-sensing with redox reaction induced by the interaction between the PB nano-core and the PEDOT-S shell. These findings may lead to variable control of the properties of nanometric metal organic frameworks because of versatile electronic interaction from their surface modification.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (10 results)

All 2010 2009 2008 Other

All Journal Article (2 results) (of which Peer Reviewed: 1 results) Presentation (7 results) Remarks (1 results)

  • [Journal Article] Prussian Blue Nanopartilces Protected by Water-Soluble π-Conjugated Polymer PEDOT-S: Synthesis and Multiple-Color pH-Sensin g with Redox Reaction2009

    • Author(s)
      Mami Yamada, Naoto Ohnishi, Makoto Watanab e, Yasuko Hin
    • Journal Title

      Chemical Communications

      Pages: 7203-7205

    • Related Report
      2009 Final Research Report
  • [Journal Article] Prussian Blue Nanopartilces Protected by Water-Soluble π-Conjugated Polymer PEDOT-S : Synthesis and Multiple-Color pH-Sensing with Redox Reaction2009

    • Author(s)
      Mami Yamada, Naoto Ohnishi, Makoto Watanabe, Yasuko Hino
    • Journal Title

      Chemical Communications

      Pages: 7203-7205

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 集積型金属錯体のナノ粒子材料化-物性と応用2010

    • Author(s)
      山田真実
    • Organizer
      超分子研究会-精密無機化学を基盤とする超分子金属錯体
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2010-01-21
    • Related Report
      2009 Final Research Report
  • [Presentation] 集積型金属錯体のナノ粒子材料化-物性と応用2010

    • Author(s)
      山田真実
    • Organizer
      超分子研究会-精密無機化学を基盤とする超分子金属錯体
    • Place of Presentation
      慶應義塾大学(神奈川)
    • Year and Date
      2010-01-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] 集積型金属錯体のナノ粒子材料化-合成と活2009

    • Author(s)
      山田真実
    • Organizer
      第2回固体材料合成および評価技術の新展開
    • Place of Presentation
      ラフォーレ蔵王(仙台)
    • Year and Date
      2009-09-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] 集積型金属錯体ナノ粒子-新しい有機-無機複合材料としての魅力-2009

    • Author(s)
      山田真実
    • Organizer
      第3回超分子若手懇談会
    • Place of Presentation
      晴海グランドホテル
    • Year and Date
      2009-08-26
    • Related Report
      2009 Final Research Report
  • [Presentation] 集積型金属錯体ナノ粒子-新しい有機-無機複合材料としての魅力-2009

    • Author(s)
      山田真実
    • Organizer
      第3回超分子若手懇談会
    • Place of Presentation
      晴海グランドホテル(東京)
    • Year and Date
      2009-08-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] 集積型金属錯体のナノ粒子材料化-合成と活用2009

    • Author(s)
      山田真実
    • Organizer
      第2回固体材料合成および評価技術の新展開
    • Place of Presentation
      ラフォーレ蔵王
    • Related Report
      2009 Final Research Report
  • [Presentation] 3次元錯体ナノ粒子の合成と機能-複合金属ナノ材料前駆体としての活用2008

    • Author(s)
      山田真実
    • Organizer
      第二回日本化学会東海支部若手研究者フォーラム
    • Place of Presentation
      名古屋大学
    • Year and Date
      2008-12-20
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~m-yamada/frame.htm

    • Related Report
      2009 Final Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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