Fundamental study of the characterization and reactivity of Group 15 and 16 heteroatom radicals

• Project/Area Number: 20750032
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Organic chemistry
• Research Institution: Kyoto University
• Principal Investigator: NAKAMURA Yasuyuki Kyoto University, 化学研究所, 助教 (30456826)
• Project Period (FY): 2008 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000); Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
• Keywords: 有機元素化学 / カルコゲン / テルル / ラジカル / リビング重合 / 光化学反応 / 有機化学 / 有機ラジカル / ヘテロ元素 / 重合反応

Research Abstract

The radical reactivity of Group 15 and 16 heteroatom compounds was studied. The photoinduced living radical polymerization using organotelluriums was developed based on the efficient radical generation from organotelluriums. The details of the polymerization mediated by organoheteroatoms were investigated.

Research Products

• [Journal Article] Organotellurium-Mediated Controlled/ Living Radical Polymerization Initiated by Direct C-Te Bond Photolysis (2009)
  • Author(s): 山子茂、鵜飼悠、松本篤、中村泰之
  • Journal Title: Journal of the American Chemical Society 131 Pages: 2100-2101
  • Peer Reviewed
• [Journal Article] Organotellurium-mediated Controlled/Living Radical Polymerization Initiated by Direct C-Te Bond Photolysis (2009)
  • Author(s): Yamago, Shigeru ; Ukai, Yuu ; Matsumoto, Atsushi ; Nakamura
  • Journal Title: Journal of the American Chemical Society 131 Pages: 2100-2101
  • Peer Reviewed
• [Presentation] フタルイミドメチルテルリドを用いたリビングラジカル重合とアミノ基末端ポリマーの合成 (2010)
  • Author(s): 堀江慶太、中村泰之、山子茂
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: 横浜市
  • Year and Date: 2010-05-27
• [Presentation] 有機テルル化合物を用いたリビングラジカル重合におけるAIBNの影響の定量分析 (2010)
  • Author(s): 北田有希絵、中村泰之、小林優、Ray Biswajit、山子茂
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: 横浜市
  • Year and Date: 2010-05-27
• [Presentation] フタルイミドメチルテルリドを用いたリビングラジカル重合とアミノ基重合末端ポリマーの合成 (2010)
  • Author(s): 堀江慶太、中村泰之、山子茂
  • Organizer: 日本化学会第91回春季年会
  • Place of Presentation: 東大阪市
  • Year and Date: 2010-03-27
• [Presentation] フタルイミドメチルテルリドを用いたリビングラジカル重合とアミノ基重合末端ポリマーの合成 (2010)
  • Author(s): 堀江慶太、中村泰之、山子茂
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-27
• [Presentation] Organotellurium-mediated Living Radical Polymerization by Direct C-Te Bond Photolysis (2009)
  • Author(s): 中村泰之、鵜飼悠、松本篤、山子茂
  • Organizer: IKCOC-11
  • Place of Presentation: 京都市
  • Year and Date: 2009-11-12
• [Presentation] Organotellurium-mediated Living Radical Polymerization by Direct C-Te Bond Photolysis (2009)
  • Author(s): Nakamura, Yasuyuki; Ukai, Yu; Konishi, Syota; Matsumoto
  • Organizer: IKCOC-11 (11th International Kyoto Conference on New Aspects of Organic Chemistry)
  • Place of Presentation: 京都
  • Year and Date: 2009-11-12
• [Presentation] The Development of Photoinduced Organotellurium- mediated Living Radical Polymerization (2009)
  • Author(s): 中村泰之
  • Organizer: The 1st FAPS Polymer Congress
  • Place of Presentation: 名古屋市
  • Year and Date: 2009-10-22
• [Presentation] The Development of Photoinduced Organotellurium-mediated Living Radical Polymerization (2009)
  • Author(s): Nakamura, Yasuyuki; Ukai, Yu; Matsumoto, Atsushi; Yamago
  • Organizer: The 1st FAPS Polymer Congress
  • Place of Presentation: 愛知
  • Year and Date: 2009-10-22
• [Presentation] 有機テルル化合物を用いた光リビングラジカル重合 (2009)
  • Author(s): 中村泰之、鵜飼悠、松本篤、山子茂
  • Organizer: 特定領域研究「元素相乗系化合物の化学」第5回若手コロキウム
  • Place of Presentation: 高崎市
  • Year and Date: 2009-04-16
• [Presentation] 有機テルル化合物を用いた光リビングラジカル重合 (2009)
  • Author(s): 中村泰之
  • Organizer: 特定領域研究「元素相乗系化合物の化学」第5回若手コロキウム
  • Place of Presentation: 群馬
  • Year and Date: 2009-04-16
• [Presentation] 有機テルル化合物の光活性化による炭素ラジカルの発生 (2009)
  • Author(s): 中村泰之、上田季子、山子茂
  • Organizer: 日本化学会第91回春季年会、
  • Place of Presentation: 舟橋市
  • Year and Date: 2009-03-28
• [Presentation] 有機テルル化合物の光活性化による炭素ラジカルの発生 (2009)
  • Author(s): 中村泰之、上田季子、山子茂
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 船橋(千葉)
  • Year and Date: 2009-03-28
• [Presentation] 有機テルル化合物を用いた光誘起型リビングラジカル重合 (2008)
  • Author(s): 鵜飼悠、松本篤、中村泰之、山子茂
  • Organizer: 第57回高分子討論会
  • Place of Presentation: 大阪市
  • Year and Date: 2008-09-24
• [Presentation] 有機テルル化合物を用いた光誘起型リビングラジカル重合 (2008)
  • Author(s): 鵜飼悠、松本篤、中村泰之、山子茂
  • Organizer: 第57回高分子討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-09-24
• [Presentation] Organotellurium Mediated Living Radical Polymerization by Direct C-Te Bond Photolysis (2008)
  • Author(s): Ukai, Yuu ; Matsumoto, Atsushi ; Nakamura, Yasuyuki ; Yamago, Shigeru
  • Organizer: The Fifth International Symposium on Integrated Synthesis
  • Place of Presentation: 神戸
  • Year and Date: 2008-09-06
• [Presentation] 有機テルル化合物を用いた光誘起型リビングラジカル重合 (2008)
  • Author(s): 鵜飼悠、松本篤、中村泰之、山子茂
  • Organizer: 第57回高分子学会年次大会
  • Place of Presentation: 横浜市
  • Year and Date: 2008-05-28
• [Remarks]
  • URL: http://www.scl.kyoto-u.ac.jp/~yasuyuki/
• [Patent(Industrial Property Rights)] リビングラジカル重合開始剤及びそれを用いるポリマーの製造方法 (2009)
  • Inventor(s): 山子茂、中村泰之、菅生久仁彦
  • Industrial Property Rights Holder: 大塚化学株式会社
  • Industrial Property Number: 2009-059704
  • Filing Date: 2009-03-12