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Development of terahertz two-dimensional correlation spectroscopy

Research Project

Project/Area Number 20750067
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Analytical chemistry
Research InstitutionThe Institute of Physical and Chemical Research

Principal Investigator

HOSHINA Hiromichi  The Institute of Physical and Chemical Research, テラヘルツイメージング研究チーム, 基幹研究所研究員 (10419004)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywords物理化学 / 分光学 / テラヘルツ / 二次元分光 / ポリマー / 二次元相関分光 / 高分子 / 時間領域分光法
Research Abstract

Two dimensional correlation spectroscopy have been developed in terahertz frequency region. Terahertz pulse train was generated and two dimensional correlation spectra of gas and solid samples were observed. However, correlation spectroscopy was not successful because power of the produced terahertz pulse was not enough and origin of the vibrational peaks was not clear. We explored materials suitable for the two dimensional spectroscopy and found out that poly-hydroxybutylate shows clear vibrational peaks originated in its higher order conformation, which may show clear correlation in two dimensional spectrum.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (6 results)

All 2010 2008

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (2 results)

  • [Journal Article] Higher order conformation of poly(3-hydroxyalkanoate)s studied by terahertz time-domain spectroscopy2010

    • Author(s)
      Hiromichi Hoshina, Yusuke Morisawa, Harumi Sato, Akitsugu Kamiya, Isao Noda, Yukihiro Ozaki, Chiko Otani
    • Journal Title

      Applied Physics Letters 96

      Pages: 101904-101904

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Higher Order Conformation of Poly(3-hydroxyalkanoate)s Studied by Terahertz Time-Domain Spectroscopy2010

    • Author(s)
      Hiromishi Hoshina, et al.
    • Journal Title

      Applied Physics Letters (in press)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Measurement of Precise Pressure Broadening Parameters of Water Vapor with a Terahertz Time Domain Spectrometer2008

    • Author(s)
      Hiromichi Hoshina, Takamasa Seta, Toshiyuki Iwamoto, Yasuko Kasai, Iwao Hosako, Chiko Otani
    • Journal Title

      Journal of Quantitative Spectroscopy and Radiative Transfer 109

      Pages: 2303-2314

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Measurement of Precise Pressure Broadening Parameters of Water Vapor with a Terahertz Time Domain Spectrometer2008

    • Author(s)
      Hiromichi Hoshina
    • Journal Title

      Journal of Quantitative Spectroscopy and Radiative Transfer 109

      Pages: 2303-2314

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] テラヘルツ時間領域分光法によるpoly(3-hydroxybutyrate)の高次構造の研究2010

    • Author(s)
      保科宏道, 森澤勇介, 神谷章嗣, 佐藤春実, 野田勇夫, 尾崎幸洋, 大谷知行
    • Organizer
      応用物理学会
    • Place of Presentation
      東海大学(平塚)
    • Year and Date
      2010-03-17
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Development of Terahertz Time Domain Spectrometer for Gas Phase Spectroscopy2008

    • Author(s)
      Hiromichi Hoshina, Takamasa Seta, Yasuko Kasai, Iwao Hosako, Chiko Otani
    • Organizer
      Federation of Analytical Chemistry and Spectroscopy Societies 2008 (FACSS 2008)
    • Place of Presentation
      Reno, USA
    • Related Report
      2009 Final Research Report 2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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