Electrochemical Synthesis of Cationic Transition-metal Complexes and Application to Organic Syntheses
| Project/Area Number |
20750080
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Okayama University |
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Principal Investigator |
MITSUDO Koichi Okayama University, 大学院・自然科学研究科, 助教 (40379714)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 触媒設計・反応 / 電解錯体合成 / カップリング反応 / カチオン性錯体 / 有機電気化学 / 有機電解 / ホモカップリング / クロスカップリング / Mlchael付加 / Aza-Mlchael付加 / ジイン / ボロン酸 / Michael付加 / Aza-Micheal付加 / 薗頭型カップリング / Wacker反応 |
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| Research Abstract |
The two objectives of our research are "the development of the methodologies for the electrochemical synthesis of cationic organometal complexes" and "integration the processes into organic reactions". In the three years, we have established the electrochemical methods to synthesize cationic palladium complexes and cationic nickel complexes, which were integrated into electrochemical Wacker-type reactions and coupling reactions. We also found that electrochemically generated cationic nickel complexes are effective catalysts for Michael additions.
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Report
(4 results)
Research Products
(72 results)
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[Journal Article] Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates2009
Author(s)
Zhang, Y., Tu, S., Mitsudo, K., Tanaka, H., Shunzo S., Machida, K., Horii, D., Ishimoto, S., Tamamitsu K.
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Journal Title
Tetrahedron Lett. 50
Pages: 6057-6059
Related Report
Peer Reviewed
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[Journal Article] Pd/TEMPO-Catalyzed electrooxidative synthesis of biaryls from arylboronic acids or arylboronic esters2009
Author(s)
Mitsudo, K., Shiraga, T., Kagen, D., Shi, D., Becker, J.Y., Tanaka, H.
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Journal Title
Tetrahedron 65
Pages: 8384-8388
Related Report
Peer Reviewed
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