Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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Research Abstract |
The two objectives of our research are "the development of the methodologies for the electrochemical synthesis of cationic organometal complexes" and "integration the processes into organic reactions". In the three years, we have established the electrochemical methods to synthesize cationic palladium complexes and cationic nickel complexes, which were integrated into electrochemical Wacker-type reactions and coupling reactions. We also found that electrochemically generated cationic nickel complexes are effective catalysts for Michael additions.
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