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Fabrication of environment-responsive interfaces based on bistable metal complexe

Research Project

Project/Area Number 20750106
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionKyoto University

Principal Investigator

FURUKAWA Shuhei  Kyoto University, 物質-細胞統合システム拠点, 特任准教授 (90452276)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywords金属錯体 / 自己組織化 / 環境応答性 / インターフェイス / 配位結合 / 多孔性配位高分子 / センサー / 界面接合 / 電気化学
Research Abstract

The novel research field of crystal interfaces has been developed using the crystal interfaces of porous coordination polymers, in order to fabricate the sophisticated interface device in response to its environment. The key of the research is how the interfaces are linked together. Based on this concept, the connecting crystals of porous coordination polymer themselves, and the immobilizing of the crystals on the oscillation device have been successfully performed, leading to the significant improvement of the sensing ability.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (19 results)

All 2009 2008 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (8 results) Remarks (1 results)

  • [Journal Article] A block PCP crystal: anisotropic hybridization of porous coordination polymers by face-selective epitaxial growth2009

    • Author(s)
      Shuhei Furukawa, Kenji Hirai, Susumu Kitagawa, 他5名
    • Journal Title

      Chem. Commun.

      Pages: 5097-5099

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth Angew.2009

    • Author(s)
      Takaaki Tsuruoka, Shuhei Furukawa, Susumu Kitagawa, 他3名
    • Journal Title

      Chem. Int. Ed. 48

      Pages: 4739-4743

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core-Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship Angew.2009

    • Author(s)
      Shuhei Furukawa, Kenji Hirai, Susumu Kitagawa, 他11名
    • Journal Title

      Chem. Int. Ed. 48

      Pages: 1766-1770

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical reactions at a porphyrin-copper interface2009

    • Author(s)
      N. Thi Minh Hai, Shuhei Furukawa, Steven De Feyter, 他3名
    • Journal Title

      PhysChemChemPhys. 11

      Pages: 5422-5430

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-Leg Molecular Ladders Formed by Hierarchical Self-Assembly of an Organic Radical2009

    • Author(s)
      Nuria Crivillers, Shuhei Furukawa, Steven De Feyter, 他11名
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 6246-6252

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth2009

    • Author(s)
      Shuhei Furukawa, Takaaki Tsuruoka, Susumu Kitagawa, 他3名
    • Journal Title

      Angewandte Chemie International Edition 48

      Pages: 4739-4743

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A block PCP crystal : anisotropic hybridization of porous coordination polymers by face-selective epitaxial growth2009

    • Author(s)
      Shuhei Furukawa, Kenji Hirai, Susumu Kitagawa, 他5名
    • Journal Title

      Chemical Communications

      Pages: 5097-5099

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical reactions at a porphyrin-copper interface2009

    • Author(s)
      Shuhei Furukawa, 他5名
    • Journal Title

      PhysChemChemPhys 11

      Pages: 5422-5430

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-Leg Molecular Ladders Formed by Hierarchical Self-Assembly of an Organic Radical2009

    • Author(s)
      Shuhei Furukawa, 他13名
    • Journal Title

      Journal of Americal Chemical Society 131

      Pages: 6246-6252

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heterogeneously Hybridized Porous Coordination Polymer Crystals : Fabrication of Heterometallic Core-Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship2009

    • Author(s)
      Shuhei Furukawa, Kenji Hirai, Susumu Kitagawa, 他10名
    • Journal Title

      Angewandte Chemie International Edition 48

      Pages: 1766-1770

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 多孔性錯体フレームワークナノロッドの創製と結晶成長メカニズム2009

    • Author(s)
      古川修平、鶴岡孝章、北川進
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎
    • Year and Date
      2009-09-26
    • Related Report
      2009 Final Research Report
  • [Presentation] Hybridization of Fluorescent Porous Coordination Framework Crystals By Epitaxial Growth2009

    • Author(s)
      Shuhei Furukawa, Kenji Hirai, Susumu Kitagawa
    • Organizer
      The XXIV International Conference on Photochemistry (ICP2009)
    • Place of Presentation
      Toledo, Spain
    • Related Report
      2009 Final Research Report
  • [Presentation] ハイブリッド型多孔性錯体フレームワークにおける回転格子緩和2009

    • Author(s)
      古川修平・平井健二・中川啓史・北川進
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Related Report
      2009 Final Research Report
  • [Presentation] Hybridization of heterometal porous coordination polymer crystals, a single crystal film epitaxial growth on a single crystal substrate2008

    • Author(s)
      Shuhei Furukawa, Kenji Hirai, Rie Haruki, Osami Sakata, Susumu Kitagawa
    • Organizer
      1st International Conference on Metal-Organic Frameworks and Open Framework Compounds (MOF 2008)
    • Place of Presentation
      Augsburg, Germany
    • Year and Date
      2008-10-08
    • Related Report
      2009 Final Research Report
  • [Presentation] Hybridization of Heterometal Porous Coordination Polymer Crystals for Fabrication of Core/Shell Type Single Crystals by Near-Matched Epitaxial Crystal Growth2008

    • Author(s)
      Shuhei Furukawa, Kenj Hirai, Keiji Nakagawa, Yohei Takashima, Osami Sakata, Susumu Kitagawa
    • Organizer
      Gordon Research Conferences 2008 (Solid State Chemistry)
    • Place of Presentation
      New London, NH, USA
    • Year and Date
      2008-07-30
    • Related Report
      2009 Final Research Report
  • [Presentation] Hybridization of Heterometal Porous Coordination Polymer Crystals for Fabrication of Core/Shell Type Single Crystals by Near-Matched Epitaxial Crystal Growth2008

    • Author(s)
      Shuhei Furukawa, Kenj Hirai, Keiji Nakagawa, Yohei Takashima, Osami Sakata, Susumu Kitagawa
    • Organizer
      Gordon. Research Conferences 2008 (Solid State Chemistry)
    • Place of Presentation
      New London, NH
    • Year and Date
      2008-07-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] 多孔性金属錯体のエピタキシャル成長による複合化2008

    • Author(s)
      古川修平, 平井健二, 高嶋洋平, 中川啓史, 坂田修身, 北川進
    • Organizer
      第61回コロイドおよび界面化学討論会
    • Place of Presentation
      福岡
    • Related Report
      2009 Final Research Report
  • [Presentation] Fabrication of Hybridized Porous Coordination Framework Crystals

    • Author(s)
      Shuhei Furukawa
    • Organizer
      7th Symposium on Soft Chemistry toward Functional Materials
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://www.icems.kyoto-u.ac.jp/j/pr/2008/12/16-icems-spring8.html

    • Related Report
      2008 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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